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101.
Pedro Silva Sofia M. Fonseca Cláudia T. Arranja Hugh D. Burrows Ana M. Urbano Abilio J. F. N. Sobral 《Photochemistry and photobiology》2010,86(5):1147-1153
A new 5,10,15,20-tetra-(phenoxy-3-carbonyl-1-amino-naphthyl)-porphyrin was prepared by an isocyanate condensation reaction and its photophysical properties fully evaluated, both in terms of photostability and singlet oxygen production. It shows considerably enhanced photostability when compared with the parent 5,10,15,20-tetra-(3-hydroxy-phenyl)-porphyrin, with the photodegradation quantum yields for T(NAF)PP and T(OH)PP being 4.65 × 10−4 and 5.19 × 10−3, respectively. Its photodynamic effect in human carcinoma HT-29 cells was evaluated. The new porphyrin showed good properties as a sensitizer in photodynamic therapy with an in vitro cytotoxicity IC50 value of 6.80 μg mL−1 for a 24 h incubation. In addition to the potential of this compound, the synthetic route used provides possibilities of extension to a wide range of new sensitizers. 相似文献
102.
Andromahi Tegou Sofia Papadimitriou Georgios Kokkinidis Sotirios Sotiropoulos 《Journal of Solid State Electrochemistry》2010,14(2):175-184
Platinized nickel and cobalt coatings, Pt(Ni) and Pt(Co), have been prepared on glassy carbon, GC, rotating disc electrode
substrates by a two-step room temperature procedure that involved the electrodeposition of nickel and cobalt layers and their
spontaneous partial replacement by platinum (“transmetalation”) when immersed into a chloroplatinic acid solution. By tuning
the quantity of initially deposited nickel and cobalt, Pt(Ni) and Pt(Co) bimetallic coatings having a 26% atom Ni and 30%
atom Co composition have been prepared. For both materials typical Pt surface electrochemistry was recorded during fast voltammetry
in deaerated acid, pointing to the existence of a continuous Pt skin over a Pt–Ni and Pt–Co core. Oxygen reduction at the
Pt(Ni)/GC and Pt(Co)/GC electrodes was studied by means of steady-state voltammetry at a rotating disc electrode and the construction
of Tafel plots from corresponding voltammetric data. It was found that, when the initial potential of the voltammetric sweep
allowed the formation of a complete Pt oxide monolayer, then oxygen reduction was hindered for low overpotentials at Pt(Ni)
and Pt(Co), compared to pure bulk Pt. On the other hand, when the initial potential was less positive (thus leading to the
formation of a fraction of surface oxide monolayer) the presence of Ni and Co enhanced the kinetics of oxygen reduction. The
former behaviour is attributed to a decrease in oxide reduction ability of Pt in the presence of Ni and Co, while the latter
to an increase in dissociative oxygen chemisorption due to Ni and Co. 相似文献
103.
Sofia Quinodoz Michael A. Thomas Jörn Dunkel Eva-Maria Schötz 《Journal of statistical physics》2011,142(6):1324-1336
The trade-off between traits in life-history strategies has been widely studied for sexual and parthenogenetic organisms,
but relatively little is known about the reproduction strategies of asexual animals. Here, we investigate clonal reproduction
in the freshwater planarian Schmidtea mediterranea, an important model organism for regeneration and stem cell research. We find that these flatworms adopt a randomized reproduction
strategy that comprises both asymmetric binary fission and fragmentation (generation of multiple offspring during a reproduction
cycle). Fragmentation in planarians has primarily been regarded as an abnormal behavior in the past; using a large-scale experimental
approach, we now show that about one third of the reproduction events in S. mediterranea are fragmentations, implying that fragmentation is part of their normal reproductive behavior. Our analysis further suggests
that certain characteristic aspects of the reproduction statistics can be explained in terms of a maximum relative entropy
principle. 相似文献
104.
Miller DJ Öberg H Kaya S Sanchez Casalongue H Friebel D Anniyev T Ogasawara H Bluhm H Pettersson LG Nilsson A 《Physical review letters》2011,107(19):195502
The oxidation of Pt(111) at near-ambient O2 pressures has been followed in situ using x-ray photoelectron spectroscopy (XPS) and ex situ using x-ray absorption spectroscopy (XAS). Polarization-dependent XAS signatures at the O K edge reveal significant temperature- and pressure-dependent changes of the Pt-O interaction. Oxide growth commences via a PtO-like surface oxide that coexists with chemisorbed oxygen, while an ultrathin α-PtO2 trilayer is identified as the precursor to bulk oxidation. These results have important implications for understanding the chemical state of Pt in catalysis. 相似文献
105.
106.
Joint optimization of spare parts ordering and maintenance policies for multiple identical items subject to silent failures 总被引:1,自引:0,他引:1
In this paper the joint maintenance and spare parts ordering problem for more than one identical operating items is studied. The operating items may suffer two types of silent failures: a minor failure, which results in item malfunctioning, and a major failure, which renders the item completely out-of-function. Inspections are periodically held to detect any failures and the inspected items are preventively maintained, repaired or replaced according to their condition. Two ordering policies are investigated to supply the necessary spare parts: a periodic review and a continuous review policy. The expected total maintenance and inventory cost per time unit is derived and the proposed models are optimized for real case data. In addition, the sensitivity of the proposed models is studied through numerical examples and the effect of some key problem characteristics on the optimal decisions is discussed. 相似文献
107.
Infinite dimensional duality and applications 总被引:2,自引:0,他引:2
Patrizia Daniele Sofia Giuffrè Giovanna Idone Antonino Maugeri 《Mathematische Annalen》2007,339(1):221-239
The usual duality theory cannot be applied to infinite dimensional problems because the underlying constraint set mostly has
an empty interior and the constraints are possibly nonlinear. In this paper we present an infinite dimensional nonlinear duality
theory obtained by using new separation theorems based on the notion of quasi-relative interior, which, in all the concrete
problems considered, is nonempty. We apply this theory to solve the until now unsolved problem of finding, in the infinite
dimensional case, the Lagrange multipliers associated to optimization problems or to variational inequalities. As an example,
we find the Lagrange multiplier associated to a general elastic–plastic torsion problem. 相似文献
108.
Ressurreição AS Bordessa A Civera M Belvisi L Gennari C Piarulli U 《The Journal of organic chemistry》2008,73(2):652-660
A practical synthesis of a new bifunctional diketopiperazine (DKP) scaffold 1, formally derived from the cyclization of L-aspartic acid and (S)-2,3-diaminopropionic acid, is reported. DKP-1 bears a carboxylic acid and an amino functionalities in a cis relationship, which have been used to grow peptide sequences. Tetra-, penta-, and hexapeptidomimetic sequences were prepared by solution-phase peptide synthesis (Boc strategy). Conformational analysis of these derivatives was carried out by a combination of 1H NMR spectroscopy, IR spectroscopy, CD spectroscopy, and computer modeling, and reveals the formation of beta-hairpin mimics involving 10-membered and 18-membered H-bonded rings and a reverse turn of the growing peptide chain. 相似文献
109.
110.
We present a fixed‐grid finite element technique for fluid–structure interaction problems involving incompressible viscous flows and thin structures. The flow equations are discretised with isoparametric b‐spline basis functions defined on a logically Cartesian grid. In addition, the previously proposed subdivision‐stabilisation technique is used to ensure inf–sup stability. The beam equations are discretised with b‐splines and the shell equations with subdivision basis functions, both leading to a rotation‐free formulation. The interface conditions between the fluid and the structure are enforced with the Nitsche technique. The resulting coupled system of equations is solved with a Dirichlet–Robin partitioning scheme, and the fluid equations are solved with a pressure–correction method. Auxiliary techniques employed for improving numerical robustness include the level‐set based implicit representation of the structure interface on the fluid grid, a cut‐cell integration algorithm based on marching tetrahedra and the conservative data transfer between the fluid and structure discretisations. A number of verification and validation examples, primarily motivated by animal locomotion in air or water, demonstrate the robustness and efficiency of our approach. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献