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121.
Mohamed Mohd Hilmi Othman Mohd Hafiz Dzarfan Hubadillah Siti Khadijah Rahman Mukhlis A. Jaafar Juhana Ismail Ahmad Fauzi 《Journal of Solid State Electrochemistry》2019,23(7):2195-2203
Journal of Solid State Electrochemistry - In this study, the effects of two fuel types, i.e., hydrogen and methane on the electrochemical performance of the co-extruded triple layer hollow fiber,... 相似文献
122.
Dr. Jinquan Wang Justin Chua Zhi En Dr. Siti Nurhanna Riduan Dr. Yugen Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(12):2581-2585
Nitrogen-linked hexaazatrinaphthylene polymer ( N2-HATN ) as organic cathode material with low HOMO–LOMO gap was synthesized and was observed to possess reversible high capacity and unexpected long-term cycling stability. The pre-treated N2-HATN and pRGO combination demonstrated good structure compatibility and the resultant cathode exhibited a constant increment of capacity during the redox cycles. The initial capacity at 0.05 A g−1 was 406 mA h−1 g−1, and increased to 630 mA h−1 g−1 after 70 cycles. At 0.5 A g−1 discharging rate, the capacity increased from an initial value of 186 mA h−1 g−1 to 588 mA h−1 g−1 after 1600 cycles. The pseudocapacitance-type behavior is postulated to be attributed to the structure compatibility between the active material and pRGO. 相似文献
123.
Dr. Zhenghai Yang Dr. Bing-Jian Sun Dr. Chao He Dr. Siti Fatimah Prof. Dr. Agnes H. H. Chang Prof. Dr. Ralf I. Kaiser 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(10):e202103999
The hitherto elusive monobridged Ge(μ-H)GeH (X1A′) molecule was prepared in the gas phase by bimolecular reaction of atomic germanium with germane (GeH4). Electronic structure calculations revealed that this reaction commenced on the triplet surface with the formation of a van der Waals complex, followed by insertion of germanium into a germanium-hydrogen bond over a submerged barrier to form the triplet digermanylidene intermediate (HGeGeH3); the latter underwent intersystem crossing from the triplet to the singlet surface. On the singlet surface, HGeGeH3 predominantly isomerized through two successive hydrogen shifts prior to unimolecular decomposition to Ge(μ-H)GeH isomer, which is in equilibrium with the vinylidene-type (H2GeGe) and dibridged (Ge(μ-H2)Ge) isomers. This reaction leads to the formation of cyclic dinuclear germanium molecules, which do not exist on the isovalent C2H2 surface, thus deepening our understanding of the role of nonadiabatic reaction dynamics in preparing nonclassical, hydrogen-bridged isomers carrying main group XIV elements. 相似文献
124.
N.H. Shamsudin Suhaidi Shafie Mohd Zainal Abidin Ab Kadir Fauzan Ahmad Amir Reza Sadrolhosseini Yusran Sulaiman Abdul Halim Abdullah Siti Amaniah Mohd Chachuli 《Surface and interface analysis : SIA》2022,54(2):109-116
The multiple sizing of silver nanoparticles (AgNPs) were synthesized from the miscible compound of ethylene glycol (EG), polyvinylpyrrolidone (PVP) and silver nitrate (AgNO3) via the solvothermal method. During the synthesis, the PVP-AgNO3 was contemplated as a paramount parameter. Using the simple method of solvothermal, the sizing of AgNPs was easily controlled in accord with the augmentation of PVP-AgNO3 at secured and moderate temperature. In regards to the sizing of AgNPs, the presence of minimum agglomeration, the absorption capability and chemical structures were highlighted through a series of verification includes ultraviolet–visible (UV–Vis) spectroscopy, Fourier-transform infrared (FTIR) spectroscopy and transmission electron microscopy (TEM) analysis. The effectiveness of the synthesized AgNPs was further investigated and compared with the commercial AgNPs by incorporating the AgNPs into titanium dioxide (TiO2) semiconductor film-based dye-sensitized solar cells (DSSCs). Results signified that the spherical AgNPs with produced sizing within the range of 19.6 to 45.2 nm were greatly impacting by tunable quantities of PVP-AgNO3, which was validated in the forms of linear equations. A larger size promotes a slower nucleation rate that conduces agglomeration. In opposition to this, the smallest size of AgNPs develops a faster formation rate of Ag ions into AgNPs, inducing the deterrent of agglomeration in light of notable particle dispersion. The power conversion efficiency (PCE) contributed by the incorporation of synthesized AgNPs into TiO2 is also 41.2% higher than that of the commercial AgNPs-TiO2. This is because the synthesized AgNPs provides less agglomeration which led to a better surface plasmonic effect towards the nanoparticles. 相似文献
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126.
Fatin Nor Arissa Azhar Mohd Faisal Taha Siti Musliha Mat Ghani Muhammad Syafiq Hazwan Ruslan Noor Mona Md Yunus 《Molecules (Basel, Switzerland)》2022,27(6)
This paper investigated the solubility of carbon dioxide (CO2) in an aqueous solution of monoethanolamine (MEA) and 1-butyl-3-methylimidazolium dibutylphosphate ((BMIM)(DBP)) ionic liquid (IL) hybrid solvents. Aqueous solutions of MEA-(BMIM)(DBP) hybrid solvents containing different concentrations of (BMIM)(DBP) were prepared to exploit the amine’s reactive nature, combined with the IL’s non-volatile nature for CO2 absorption. Response surface methodology (RSM) based on central composite design (CCD) was used to design the CO2 solubility experiments and to investigate the effects of three independent factors on the solubility of CO2 in the aqueous MEA-(BMIM)(DBP) hybrid solvent. The three independent factors were the concentration of (BMIM)(DBP) (0–20 wt.%), temperature (30 °C–60 °C) and pressure of CO2 (2–30 bar). The experimental data were fitted to a quadratic model with a coefficient of determination (R2) value of 0.9791. The accuracy of the developed model was confirmed through additional experiments where the experimental values were found to be within the 95% confidence interval. From the RSM-generated model, the optimum conditions for CO2 absorption in aqueous 30 wt% MEA-(BMIM)(DBP) were 20 wt% of (BMIM)(DBP), a temperature of 41.1 °C and a pressure of 30 bar. 相似文献
127.
Siti Nor Syairah Anis M. I. Nurhezreen K. Sudesh A. A. Amirul 《Applied biochemistry and biotechnology》2012,167(3):524-535
A simple, efficient and economical method for the recovery of P(3HB-co-3HHx) was developed using various chemicals and parameters. The initial content of P(3HB-co-3HHx) in bacterial cells was 50?C60?wt%, whereas the monomer composition of 3HHx used in this experiments was 3?C5?mol%. It was found that sodium hydroxide (NaOH) was the most effective chemical for the recovery of biodegradable polymer. High polyhydroxyalkanoate purity and recovery yield both in the range of 80?C90?wt% were obtained when 10?C30?mg/ml of cells were incubated in NaOH at the concentration of 0.1?M for 60?C180?min at 30?°C and polished using 20?% (v/v) of ethanol. 相似文献
128.
N-4-(bromobutanoyl)-N'-(o-, m- and p-tolyl)thioureas 3a, 3b and 3c respectively, were synthesized by the reaction of 4-bromobutanoylisothiocyanate with p-, m- and o-toludine. The products were characterized by IR, and NMR spectroscopic techniques. The two carbonoylthiourea isomers N-(4-bromobutanoyl)-N'-(3-methylphenyl)thiourea(3b) and N-(4-bromobutanoyl)-N'-(4-methylphenyl)thiourea(3c) were obtained in crystalline form by recrystallization from DMSO. Xray crystallographic studies showed that both compounds 3b and 3c crystallize in triclinic system with space group of P1. The molecules adopt trans-cis configuration with respect to the positions of 4-bromobutanoyl and tolyl groups respectively, against the thiono C=S bond across their C–N bonds. The configuration is attributed by the intrahydrogen bond between the carbonyl oxygen and amide hydrogen atoms. Both crystal structures are stabilized by N–H···S intermolecular hydrogen bonds to form dimers and arranged along the b axis. 相似文献
129.
Mardis Mardiansyah Takada Noriharu Machmudah Siti Wahyudiono Sasaki Koichi Kanda Hideki Goto Motonobu 《Research on Chemical Intermediates》2016,42(5):4581-4590
Research on Chemical Intermediates - Nickel nanoparticles with various structures were synthesized by a pulsed laser ablation process in liquid CO2 at 17 °C and 5.2 MPa. A... 相似文献
130.
Fauzia Izzati Mega Ferdina Warsito Asep Bayu Anggia Prasetyoputri Akhirta Atikana Linda Sukmarini Siti Irma Rahmawati Masteria Yunovilsa Putra 《Molecules (Basel, Switzerland)》2021,26(7)
Marine invertebrates have been reported to be an excellent resource of many novel bioactive compounds. Studies reported that Indonesia has remarkable yet underexplored marine natural products, with a high chemical diversity and a broad spectrum of biological activities. This review discusses recent updates on the exploration of marine natural products from Indonesian marine invertebrates (i.e., sponges, tunicates, and soft corals) throughout 2007–2020. This paper summarizes the structural diversity and biological function of the bioactive compounds isolated from Indonesian marine invertebrates as antimicrobial, antifungal, anticancer, and antiviral, while also presenting the opportunity for further investigation of novel compounds derived from Indonesian marine invertebrates. 相似文献