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51.
A. P.L. Siqueira I. A. Esquef M. G. da Silva L. C.M. Miranda H. Vargas 《The European physical journal. Special topics》2008,153(1):431-433
In this paper we describe a new, simple and fast
photothermal method for characterizing simultaneously the thermal
diffusivity and thermal effusivity. The improved PTGA essentially combines a
photoacoustic cell and a thermal wave pyroelectric cell enclosed in a single
compact gas analyzer. The photo- acoustic cell is kept filled with nitrogen
and sealed. The pyroelectric cell is also filled with nitrogen and after
some warm up time, the nitrogen is exchanged to the gas of interest. It is
shown that the analysis of the transient and saturation signals of both
photoacoustic and pyroelectric cells are capable of measuring the thermal
properties with an accuracy of 5%. The measurements were performed for
hydrocarbons as ethane and propane, which are combustible gases. Knowing
thermal diffusivity and effusivity, others important properties can be
determinate: the thermal conductivity and the volumetric thermal capacity. 相似文献
52.
Vertical structure and biomass are key characteristics of the forest random medium. This paper calculates the power and interferometric synthetic aperture radar (InSAR) sensitivity to tree height and vegetation density as it manifests in extinction, using a homogeneous, random-volume model of the forest medium, and accounting for speckle and thermal noise. Tree height and extinction are both related to biomass within the context of this simple model. Signal and noise calculations show that InSAR coherence and phase are more sensitive than radar power to structure and biomass to 10% variations in structure parameters over a wide range of medium to high density forests. For example, for extinctions of 0.2 db m-1 and other parameters as noted in the text, the sensitivity of InSAR coherence to 10% changes in tree height exceeds observation errors for trees shorter than about 37 m, as opposed to 14 m for radar power. InSAR phase sensitivity to 10% structural and associated biomass changes exceeds observation errors for all tree heights. Only for the very lowest densities, for extinctions less than 0.15 db m-1, does radar power sensitivity to density exceed that of InSAR; even at low densities, InSAR sensitivity to tree height outperforms that of radar power in these calculations. 相似文献
53.
The results of electron spin resonance (ESR) and electron nuclear double resonance (ENDOR) studies of a self-trapped hole (VK center) in SrF2 are reported. The g-factor and hyperfine interaction constants were determined for the flourine nuclei forming the center and for those in the nearest three different sites. The values of hyperfine interaction constants are intermediate to the known values for CaF2 and BaF2. 相似文献
54.
55.
2,3-Aziridino-γ-lactones are versatile synthons for the preparation of polysubstituted α- or β-amino acids. With the intention of preparing α,α-disubstituted α- or β-amino acids, regioselective electrophilic substitution of aziridino-γ-lactones at C2 was realized using two different methods. In the first, the anion was generated at C2 with LDA in the presence of the electrophilic agent. In the second method, the anion was trapped with TMS. Subsequent treatment of the C2 silylated product with a fluoride ion source regenerated the anion, which then reacted in situ with various electrophiles. Intramolecular aziridine opening of the C2 benzyl derivative prepared by the first method allowed access to a novel furan derivative, a direct precursor of an α,α-disubstituted β-amino acid. 相似文献
56.
Fernandes DC Regasini LO Vellosa JC Pauletti PM Castro-Gamboa I Bolzani VS Oliveira OM Silva DH 《Chemical & pharmaceutical bulletin》2008,56(5):723-726
Two new flavone glucosides, nitensosides A and B (1, 2), together with four known compounds, sorbifolin (3), sorbifolin 6-O-beta-glucopyranoside (4), pedalitin (5), and pedalitin 6-O-beta-glucopyranoside (6) were isolated from Pterogyne nitens. Their structures were elucidated from 1D and 2D NMR analysis, as well as by high resolution mass spectrometry. All the isolated flavones were evaluated for their myeloperoxidase (MPO) inhibitory activity. The most active compound, pedalitin, exhibited IC50 value of 3.75 nM on MPO. Additionally, the radical-scavenging capacity of flavones 1-6 was evaluated towards ABTS and DPPH radicals and compared to standard compounds quercetin and Trolox. 相似文献
57.
da Silva MA Oliveira AP Sannomiya M Sano PT Varanda EA Vilegas W dos Santos LC 《Chemical & pharmaceutical bulletin》2007,55(11):1635-1639
A new acylated flavonoid, 6,4'-dimethoxyquercetin-3-O-beta-D-6'[3,4,5-trihydroxy (E)-cinnamoyl]glucopyranoside, and a naphthopyranone dimer, named eriocauline, together with 2 other known flavonoids, 6-methoxyapigenin-7-O-beta-D-glucopyranoside and 6-methoxyapigenin-7-O-beta-D-allopyranoside, have been isolated from the capitulae of Eriocaulon ligulatum. The compounds were identified using spectroscopic methods (HR-ESI-MS, and 1-D and 2-D NMR). The methanol extract exhibited mutagenic activity in the Salmonella/microsome assay, in strains TA100, TA97a and TA102 and for dichloromethane extract tested in strain TA98. 相似文献
58.
Thermodynamics, structure, and dynamics of an ionic liquid based on a quaternary ammonium salt with ether side chain, namely, N-ethyl-N,N-dimethyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide, MOENM2E TFSI, are investigated by molecular dynamics (MD) simulations. Average density and configurational energy of simulated MOENM2E TFSI are interpreted with models that take into account empirical ionic volumes. A throughout comparison of the equilibrium structure of MOENM2E TFSI with previous results for the more common ionic liquids based on imidazolium cations is provided. Several time correlation functions are used to reveal the microscopic dynamics of MOENM2E TFSI. Structural relaxation is discussed by the calculation of simultaneous space-time correlation functions. Temperature effects on transport coefficients (diffusion, conductivity, and viscosity) are investigated. The ratio between the actual conductivity and the estimate from ionic diffusion by the Nernst-Einstein equation indicates that correlated motion of neighboring ions in MOENM2E TFSI is similar to imidazolium ionic liquids. In line with experiment, Walden plot of conductivity and viscosity indicates that simulated MOENM2E TFSI should be classified as a poor ionic liquid. 相似文献
59.
[reaction: see text] A new approach for the synthesis of (+/-)-indatraline, which is a 3-phenyl-1-indanamine that displays several biological activities, is described. The strategy features as the key step a diastereoselective ring contraction of a 1,2-dihydronaphthalene promoted by PhI(OTs)OH, to construct the indan ring system. The oxidative rearrangement of other 1,2-dihydronaphthalenes was also investigated, generalizing this method to obtain indans. 相似文献
60.
Farias WR Lima PC Rodrigues NV Siqueira RC Amorim RM Pereira MG Assreuy AM 《Natural product communications》2011,6(6):863-866
Sulfated polysaccharides (SP) of brown algae (Phaeophyta) are composed mainly of alpha- L-fucose, being classified as fucans, with recognized role in inflammation but not in nociception, which was already described for SP obtained from red algae. Here the SP of the brown marine alga S. schroederi (named Ss-SP) was isolated and assayed for the antinociceptive effect. Ss-SP was isolated by DEAE-cellulose, analyzed by agarose gel electrophoresis and evaluated in nociception models (Formalin, Hot plate, Von Frey) using Swiss mice (20-25g). Anion exchange chromatography provided four major fractions being F1 (Ss-SP) that of highest metachromatic activity and sugar content. Ss-SP inhibited both phases of the formalin test. In the first phase the paw licking (55.2 +/- 8.07s) was reduced by 45% (30.5 +/- 6.51s) and 40% (32.85 +/- 8.66s) at 0.1 and 1 mg/kg, respectively. In the second phase, Ss-SP was also inhibitory about 39%, but only at 1 mg/kg (83.0 +/- 15.70s) compared to formalin (136.8 +/- 10.27s). This inhibitory effect suggests a mixed mechanism similar to morphine, which was not confirmed in the hot plate test, a model of pain associated with central neurotransmission. However, Ss-SP reduced the animal reaction in response to stimulation withVon Frey filament at the 2nd and 3rd h (20.8 +/- 6.86% versus carrageenan: 47.9 +/- 5.83%; 33.3 +/- 7.71% versus carrageenan: 62.5 +/- 9.83%). Accordingly, the paw edema induced by carrageenan (0.08 +/- 0.01g) was potently reduced in 45.35% by Ss-SP pre-treatment (0.02 +/- 0.003g), corroborating the anti-inflammatory activity demonstrated for brown seaweed polysaccharides. In conclusion our data revealed for the first time the antinociceptive effect of Ss-SP which could be used as a new source of analgesic substances. 相似文献