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41.
Yuki?KanazawaEmail authorView authors OrcID profile Tetsuya?Yamada Aki?Kido Koji?Fujimoto Kyoko?Takakura Hiroaki?Hayashi Yasutaka?Fushimi Satoshi?Kozawa Koji?Koizumi Makiko?Okuni Naomi?Ueda Kaori?Togashi 《Applied magnetic resonance》2017,48(2):125-134
To visualize the condition of impregnation of polyethylene glycol (PEG) in waterlogged wood, we demonstrated magnetic transfer (MT) magnetic resonance imaging (MRI) through a series of process of PEG impregnation. Three different samples were examined; reference wood, 10 cm cut wood, and 5 cm cut wood. During this study, the upper section sample was kept immersed in water, for the middle and lower sections the concentration of PEG solution was changed at 20 wt% intervals from 20 to 100 wt%. The impregnated periods of each PEG solution concentration were 14 days. Then, MR imaging were performed with/without MT pulse. The MTR value for both 10 cm- and 5 cm-samples were shown to decrease at 20 wt% PEG at peak concentration. When the sample volume was large, e.g., 10 cm-sample, the MTR value decreased to 100 wt% PEG concentration. In contrast, when a sample volume was small, e.g., 5 cm-sample, MTR value decreased to 60 wt% PEG concentration. In conclusion, MTR analysis makes it possible to nondestructively visualize and evaluate the inner condition concerning the PEG impregnation method for waterlogged wood. 相似文献
42.
Recently, the Voice Handicap Index (VHI), developed in the United States, has been highlighted as a means to assess a patient's perceptions of the severity of his or her voice disorder. The VHI is based on a self-administered questionnaire that quantifies the degree of a patient's disability related to his/her voice disorder. The questionnaire was translated into Japanese and applied to Japanese patients with various kinds of disordered voice or dysphonia. The results were analyzed and the usefulness discussed. In this study, 546 patients (281 males and 265 females) were included. Mean VHI scores were 36.2/120 in males and 44.1/120 in females. In the male patients, VHI scores were the highest among teens. However, VHI scores did not vary with age in the female patients. Patients with vocal fold paralysis, functional dysphonia, psychological dysphonia, and spasmodic dysphonia showed relatively high VHI scores, whereas those with laryngeal granuloma and laryngopharyngeal reflux disease showed low scores. In most diseases, functional and physiological scores were higher than emotional scores. In any treated patients, those with vocal nodule, vocal polyp, polypoid vocal fold, and recurrent laryngeal nerve paralysis, VHI scores decreased after therapeutic intervention. These findings suggest that the Japanese VHI is a useful tool for monitoring a patient's psychological status, choosing appropriate treatment, and assessing the therapeutic outcome. 相似文献
43.
Shin-ichi Takekuma Manami Yamamoto Aki Nakagawa Tomohiro Iwata Toshie Minematsu Hideko Takekuma 《Tetrahedron》2012,68(39):8318-8329
Wittig reaction of (E)-3-(3-guaiazulenyl)propenal (11) with (3-guaiazulenylmethyl)triphenylphosphonium bromide (9) in ethanol containing NaOEt at 25 °C for 24 h under argon gives the title new (2E,4E)-1,3-butadiene derivative 4, in 33% isolated yield, which upon treatment with hexafluorophosphoric acid (i.e., 65% HPF6 aqueous solution) in tetrahydrofuran (=THF) at 25 °C for 1 h under aerobic conditions affords a new air (two-electron) oxidation product (E)-ethylene-1,2-bis(3-guaiazulenylmethylium) bis(hexafluorophosphate) (14), quantitatively, and further, zinc-reduction of 14 in trifluoroacetic acid (=CF3COOH) at 0 °C for 1 h under argon reverts 4, quantitatively. Along with the above interesting results, our discovered another preparation method, spectroscopic properties, crystal structure, and electrochemical behavior of 4, which serves as a strong two-electron donor and acceptor, compared with those of the previously reported (E)-1,2-di(3-guaiazulenyl)ethylene (3) are documented in detail. 相似文献
44.
Arichi N Inase A Eto S Mizukoshi T Yamamoto J Iwai S 《Organic & biomolecular chemistry》2012,10(11):2318-2325
The (6-4) photoproduct is one of the major damaged bases produced by ultraviolet light in DNA. This lesion is known to be alkali-labile, and strand breaks occur at its sites when UV-irradiated DNA is treated with hot alkali. We have analyzed the product obtained by the alkali treatment of a dinucleoside monophosphate containing the (6-4) photoproduct, by HPLC, NMR spectroscopy, and mass spectrometry. We previously found that the N3-C4 bond of the 5' component was hydrolyzed by a mild alkali treatment, and the present study revealed that the following reaction was the hydrolysis of the glycosidic bond at the 3' component. The sugar moiety of this component was lost, even when a 3'-flanking nucleotide was not present. Glycosidic bond hydrolysis was also observed for a dimer and a trimer containing 5-methyl-2-pyrimidinone, which was used as an analog of the 3' component of the (6-4) photoproduct, and its mechanism was elucidated. Finally, the alkali treatment of a tetramer, d(GT(6-4)TC), yielded 2'-deoxycytidine 5'-monophosphate, while 2'-deoxyguanosine 3'-monophosphate was not detected. This result demonstrated the hydrolysis of the glycosidic bond at the 3' component of the (6-4) photoproduct and the subsequent strand break by β-elimination. It was also shown that the glycosidic bond at the 3' component of the Dewar valence isomer was more alkali-labile than that of the (6-4) photoproduct. 相似文献
45.
Seki M Tsuruta O Aoyama Y Soejima A Shimada H Nonaka H 《Chemical & pharmaceutical bulletin》2012,60(4):488-498
In investigating potent sodium (Na(+)) channel blockers for the treatment of ischemic stroke, we synthesized a novel series of 3-amino-1-(5-indanyloxy)-2-propanol derivatives and evaluated their inhibitory effects on neuronal Na(+) channels. The 3-amino-1-(5-indanyloxy)-2-propanol derivatives exhibited potent blocking activity for Na(+) channels and a significantly low affinity for dopamine D(2) receptors, which demonstrates a minimal clinical risk for extrapyramidal side effects. In particular, compound 4b, a 3-amino-1-(5-indanyloxy)-2-propanol derivative bearing a benzimidazole moiety, showed desirable neuroprotective activity in a rat transient middle cerebral artery occlusion model. Furthermore, compound 4b displayed a high binding affinity for neurotoxin receptor site 2 of the Na(+) channels, which suggests that 4b would act as a use-dependent Na(+) channel blocker in sustained depolarization during ischemic stroke. 相似文献
46.
This paper introduces a new concept: a binary sequence of order (k,r), which is an extension of a binary sequence of order k and a Markov dependent sequence. The probability functions of the sooner and later waiting time random variables are derived in the binary sequence of order (k,r). The probability generating functions of the sooner and later waiting time distributions are also obtained. Extensions of these results to binary sequence of order (g,h) are also presented. 相似文献
47.
48.
Sigeo Aki 《Annals of the Institute of Statistical Mathematics》1985,37(1):205-224
Summary This paper considers discrete distributions of orderk based on a binary sequence which is defined as an extension of independent trials with a constant success probability and
is more practical than the independent trials. Some results on calculation of probabilities and characteristics of the distributions
are obtained as well as their formal expressions. Examples and an application are also given.
The Institute of Statistical Mathematics 相似文献
49.
Let Z
0, Z
1,...,Z
n
be a sequence of Markov dependent trials with state space Ω = {F
1,...,F
λ, S
1,...,S
ν}, where we regard F
1,...,F
λ as failures and S
1,...,S
ν as successes. In this paper, we study the joint distribution of the numbers of S
i
-runs of lengths k
ij
(i = 1,2,...,ν, j = 1,2,...,r
i
) based on four different enumeration schemes. We present formulae for the evaluation of the probability generating functions
and the higher order moments of this distribution. In addition, when the underlying sequence is i.i.d. trials, the conditional
distribution of the same run statistics, given the numbers of success and failure is investigated. We give further insights
into the multivariate run-related problems arising from a sequence of the multistate trials. Besides, our results have potential
applications to problems of various research areas and will come to prominence in the future.
This research was partially supported by the ISM Cooperative Research Program (2004-ISM·CRP-2007). 相似文献
50.
Sigeo Aki 《Annals of the Institute of Statistical Mathematics》1986,38(1):1-21
Summary It is proved that the martingale term of the empirical distribution function converges weakly to a Gaussian process inD[0, 1]. Some statistics for goodness-of-fit tests based on the martingale term of the empirical distribution function are
proposed. Asymptotic distributions of these statistics under the null hypothesis are given. The approximate Bahadur efficiencies
of the statistics to the Kolmogorov-Smirnov statistic and to the Cramér-von Mises statistic are also calculated.
The Institute of Statistical Mathematics 相似文献