全文获取类型
收费全文 | 462篇 |
免费 | 22篇 |
国内免费 | 7篇 |
专业分类
化学 | 287篇 |
晶体学 | 3篇 |
力学 | 28篇 |
数学 | 115篇 |
物理学 | 58篇 |
出版年
2023年 | 3篇 |
2022年 | 6篇 |
2021年 | 13篇 |
2020年 | 17篇 |
2019年 | 15篇 |
2018年 | 22篇 |
2017年 | 17篇 |
2016年 | 20篇 |
2015年 | 26篇 |
2014年 | 40篇 |
2013年 | 65篇 |
2012年 | 40篇 |
2011年 | 32篇 |
2010年 | 35篇 |
2009年 | 15篇 |
2008年 | 20篇 |
2007年 | 13篇 |
2006年 | 12篇 |
2005年 | 18篇 |
2004年 | 11篇 |
2003年 | 15篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 7篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1994年 | 6篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1983年 | 1篇 |
1979年 | 3篇 |
排序方式: 共有491条查询结果,搜索用时 562 毫秒
81.
Siamak Yassemi 《Czechoslovak Mathematical Journal》1997,47(4):585-592
It is shown that for any Artinian modules M, M
is the greatest integer i such that
(M
) 0. 相似文献
82.
This paper introduces four different modes of multiple-injection CZE (MICZE). The validity of these MICZE models was evaluated by the experimental data. Prior to the application of MICZE, the electrophoretic conditions are developed in the single-injection mode by adjusting different experimental parameters such as pH, type and concentration of buffer additives and temperature. Based on the migration time difference (Deltatmig) between the analyte and the internal standard or injection marker, one or more MICZE modes can be employed. The injection marker is added to the sample to compensate for injection-volume fluctuations. The inter-plug distance is regulated by applying an electrical field over the capillary for a short period of time between each injection. After the final injection, the separation is completed by electrophoresis for a time period corresponding to that in the single-injection mode. 相似文献
83.
Maryam Ataeefard Siamak Moradian Mojtaba Mirabedini Morteza Ebrahimi Saeed Asiaban 《Plasma Chemistry and Plasma Processing》2008,28(3):377-390
The surface of a LDPE was modified by Ar, O2, N2, CO2 gaseous plasma. The changes in surface morphology and surface wettability were investigated using AFM and SEM. The surface
chemical changes of LDPE were also characterized by FTIR-ATR. The SEM and AFM results demonstrated variable changes in surface
roughness for different types of plasma gas used, the changes being more for the Ar and N2 plasma treatments. Considering the nature of the LDPE film, XRD studies were carried out to determine changes in the percentage
crystalinity. The results showed that all low pressure O2, Ar, N2, CO2 gas plasmas improved the wettability of LDPE films. Contact angles decreased significantly depending on the discharge powers
and exposure times. Surface morphology was also found to vary with plasma discharge powers, exposure times, and the type of
gas being used. Ar and N2 gas plasmas in general produced more superior results. 相似文献
84.
By calculating the energies of neutral and different ionic forms (M2+, M+, M, M-, and M2-) of 32 elements (using B3LYP/6-311++G** level of theory) and taking energy (E) to be a Morse-like function of the number of electrons (N), the electrophilicity values (omega) are calculated for these atoms. The obtained electrophilicities show a good linearity with some commonly used electronegativity scales such as Pauling and Allred-Rochow. Using these electrophilicities, the ionicities of some diatomic molecules are calculated, which are in good agreement with the experimental data. Therefore, these electrophilicities are introduced as a new scale for atomic electronegativity, chi(omega)0. The same procedure is also performed for some simple polyatomic molecules. It is shown that the new scale successfully obeys Sanderson's electronegativity equalization principle and for those molecules which have the same number of atoms, the ratio of the change in electronegativity during the formation of a molecule from its elements to the molecular electronegativity (Delta chi/chi omega) is the same. 相似文献
85.
Let be a commutative Noetherian local ring and let be an ideal of R. We give some inequalities between the Bass numbers of an R–module and those of its local cohomology modules with respect to . As an application of these inequalities, we recover results of Delfino-Marley and Kawasaki by showing that for a minimax
R-module M and for any non-negative integer i, the Bass numbers of the ith local cohomology module are finite if one of the following holds:
S. Yassemi was supported by a grant from IPM No. 85130214. 相似文献
(a) | , |
(b) | is a principal ideal. |
86.
(13)C chemical shieldings and (14)N and (2)H electric field gradient (EFG) tensors of L-alanylglycine (L-alagly) dipeptide were calculated at RHF/6-31 + + G** and B3LYP/6-31 + + G** levels of theory respectively. For these calculations a crystal structure of this dipeptide obtained from X-ray crystallography was used. Atomic coordinates of different clusters containing several L-alagly molecules were used as input files for calculations. These clusters consist of central and surrounding L-alagly molecules, the latter forming short, strong, hydrogen bonds with the central molecule. Since the calculations did not converge for these clusters, the surrounding L-alagly molecules were replaced by glycine molecules. In order to improve the accuracy of calculated chemical shifts and nuclear quadrupole coupling constants (NQCCs), different geometry-optimization strategies were applied for hydrogen nuclei. Agreement between calculated and experimental data confirms that our optimized coordinates for hydrogen nuclei are more accurate than those obtained by X-ray diffraction. 相似文献
87.
Masoud Bakhshi Hamid Arab Mohammad K. Amini 《Journal of the Iranian Chemical Society》2016,13(9):1673-1681
Several sample preparation methods were evaluated for determination of free carbon in boron carbide powders by quantitative X-ray diffraction method, including ultrasonication, wet ball milling and dry ball milling–wet mixing. Quantitation was based on measuring the integral peak area ratio of the diffraction lines of graphite (002) to boron carbide (012) in samples spiked with pure graphite. The dry milling–wet mixing method provided the best precision and accuracy in all the measurements as well as in determination of free carbon in a boron carbide reference material. There was a linear relationship between the integral peak area ratios and graphite added to boron carbide samples which were purified from their free carbon content. The method provided a low detection limit of 0.05 wt% free carbon. 相似文献
88.
89.
90.
A convenient synthesis of 5‐alkylthio‐3,4‐diarylisoxazoles by palladium‐catalyzed coupling reactions
Roozbeh Eskandari Latifeh Navidpour Mohsen Amini Abbas Shafiee Hamed Shafaroodi Abbas Shafiee 《Journal of heterocyclic chemistry》2007,44(2):449-453