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141.
佳木斯地区中草药微量元素的测定 总被引:1,自引:0,他引:1
采用原子吸收分光光度法测定了佳木斯地区产12种中草药的元素含量,为本地区中草药资源的开发和利用提供了有意义的数据。 相似文献
142.
Jia Hui Xu Ting Ting Zhuang Yi Cao Dr. Jing Yang Jing Jia Wen Zheng Ying Wu Dr. Chun Fang Zhou Dr. Li Huang Ying Wang Prof. Dr. Ming Bo Yue Dr. Jian Hua Zhu Prof. Dr. 《化学:亚洲杂志》2007,2(8):996-1006
Copper oxide was incorporated into MCM‐41 by a one‐pot synthesis under acidic conditions to prepare a new mesoporous nitrosamines trap for protection of the environment. The resulting composites were characterized by XRD, N2 adsorption–desorption, and H2 temperature‐programmed reduction techniques, and their adsorption capabilities were assessed in the gaseous adsorption of N‐nitrosopyrrolidine (NPYR). The adsorption isotherms were consistent with the Freundlich equation. The copper salt was deposited onto MCM‐41 during the evaporation stage and was fixed on the host in the calcination process that followed. MCM‐41 was able to capture NPYR in air below 373 K but not at 453 K. Loading of copper oxide on MCM‐41 greatly improved its adsorption capability at elevated temperatures. The influence of the incorporation of copper into MCM‐41 samples and the adsorption behavior of these samples are discussed in detail. 相似文献
143.
144.
Ting Zhang 《Analytica chimica acta》2003,489(2):199-206
A novel inorganic-organic hybrid titania sol-gel nanocomposite film was prepared to fabricate a sensitive tyrosinase biosensor for the amperometric detection of trace phenolic compounds without additional electron mediators. Acetylacetone worked as a complexing ligand to chelate with Ti atom in the synthesis process, and the pH of the titania solution could be adjusted to the value which was optimum for retaining tyrosinase activity and such a membrane was stably attached on to the surface of a glassy carbon electrode (GCE). This titania matrix could supply a good environment for enzyme loading, which resulted in a high sensitivity of 15.78 μA μM−1 cm−2 for monitoring phenols with a detection limit of 1×10−8 M at a signal-to-noise ratio of 3. The TiO2 sol-gel derived biosensor exhibited a fast response less than 10 s and a good stability for more than 2 months. 相似文献
145.
Ying Liu Wenqing Liu Haiyang Li Yong Yang Shuang Cheng 《International journal of quantum chemistry》2007,107(2):396-402
Ab initio molecular orbital and density functional theory (DFT) in conjunction with different basis sets calculations were performed to study the N? H…O and S? H…O blue‐shifted H‐bonds in the HNO…HFSO2 complex. The geometric structures, vibrational frequencies, and interaction energies were calculated by both standard and CP‐corrected methods. Natural bond orbital (NBO) analysis was used to investigate the origin of blue‐shifted H‐bonds, showing that the decrease in the σ*(N? H) and σ*(S? H) is due to the electron density redistribution effect. The structure reorganization effect on the blue‐shifted hydrogen bonds was discussed in detail. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
146.
Kedong Xia Junpo Guo Cuijuan Xuan Ting Huang Zhiping Deng Lingxuan Chen Deli Wang 《中国化学快报》2019,30(1):192-196
Nitrogen doped carbon nanosheets supported molybdenum carbides nanoparticles (MoxC/NCS) have been synthesized by tuning the mass ratio of melamine and ammonia molybdate. The Mo2C/NCS-10 exhibits superior electrocatalytic performance and stability for HER, which was attributed to N-doped carbon nanosheets, small particle size, mesoporous structure, and large electrochemical active surface area. 相似文献
147.
Xiao‐Yan Chen Peng Cheng Shi‐Ping Yan Dai‐Zheng Liao Zong‐Hui Jiang 《无机化学与普通化学杂志》2005,631(15):3104-3107
A novel two‐dimensional cobalt complex, [Co(btrm)2(dca)]ClO4 ( 1 , btrm = 1,2‐bis(1,2,4‐triazole‐1‐yl)methane, dca = dicyanamide), was synthesized and characterized. X‐ray diffraction analyses reveal that the title complex crystallizes in the monoclinic space group C2/m with a = 29.507(13)Å, b = 17.804(8) Å, c = 14.709(7) Å, β = 119.916(7)°, Z = 12, and R1 = 0.0784, wR2 = 0.2041. The cobalt atom involves a six‐coordinated CoN6 environment, with a distorted octahedral coordination. Two btrm ligands connect the CoII atoms with the exodentate nitrogen atoms on the 4‐position of triazole rings to form a sixteen‐membered rhombic grid. The unprecedented double btrm bridges and μ1,5‐dca bridge connect the cobalt atoms to form a two‐dimensional grid‐like layered structure. The spectroscopic and magnetic properties have also been investigated. 相似文献
148.
提出了利用不同取代基烯类单体的电子亲和势来判断其负离子聚合反应活性的方法.采用密度泛函理论的B3LYP/6-31G(d)方法优化了不同取代基烯类单体几何构型,在B3LYP/6-311++G(3df,2p)水平上计算了其电子亲和势.通过电子亲和势计算值与文献报道实验数据比较,表明本文采用的计算方法是比较可靠的.结合不同取代基烯类单体的电子亲和势的计算结果,通过与Q-e关系及取代基常数σ数据进行比较表明,电子亲和势可以用来判断不同单体负离子聚合反应的活性高低. 相似文献
149.
A modified method has been developed to purify retine from pig liver. The crude extract of retine can be separated into five fractions by paper chromatography, each of them having been tested for the effect on the proliferation of protozoal Tetrahymena Pyriformis. One of the fractions, G3, has the strongest effect. The present results show that G3 fraction showed positive reactions toward 2,4-dinitro-phenyl hydrazine, ethylene diamine, and ninhydrin. Other properties of the fraction has also been studied. 相似文献
150.
甲醛与乙醛,甲醚,硝基甲烷相互作用的从头算研究 总被引:1,自引:0,他引:1
用6-31G、全构型优化,研究了甲醛与乙醛、甲醚、硝基甲烷的相互作用。结果表明所有超分子稳定构型都包含2个C—H—O氢键的平面环状结构。H—O距离为0.228~0.264 nm,作用能为—19~—24 kJ/mol,与二聚水的作用能接近。稳定性主要取决于甲基上取代基Y吸电子能力以及环状结构中氢键张力。STO-3G不很适用于研究这类分子的相互作用。 相似文献