全文获取类型
收费全文 | 202篇 |
免费 | 33篇 |
专业分类
化学 | 184篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 13篇 |
物理学 | 34篇 |
出版年
2023年 | 4篇 |
2022年 | 9篇 |
2021年 | 9篇 |
2020年 | 10篇 |
2019年 | 13篇 |
2018年 | 13篇 |
2017年 | 8篇 |
2016年 | 19篇 |
2015年 | 20篇 |
2014年 | 15篇 |
2013年 | 16篇 |
2012年 | 30篇 |
2011年 | 23篇 |
2010年 | 7篇 |
2009年 | 6篇 |
2008年 | 9篇 |
2007年 | 2篇 |
2006年 | 6篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 1篇 |
2002年 | 3篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1994年 | 1篇 |
排序方式: 共有235条查询结果,搜索用时 15 毫秒
21.
Takeo Sasaki Takumi Yoneyama Shota Hashimoto Sumie Takemura Yumiko Naka 《Journal of polymer science. Part A, Polymer chemistry》2013,51(18):3873-3880
Photoinduced depolymerization of poly(olefin sulfone)s possessing photobase generators in the side‐chain was investigated. Irradiation with UV light generated base on the side‐chains and induced depolymerization based on proton abstraction on the main‐chain. The effect of the length of the spacer chain, which connects the photobase‐generating moiety to the polymer main chain on the photoinduced depolymerization, also was investigated. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 3873–3880 相似文献
22.
Fused Corrole Dimers Interconvert between Nonaromatic and Aromatic States through Two‐Electron Redox Reactions
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Shota Ooi Dr. Takayuki Tanaka Kyu Hyung Park Sangsu Lee Prof. Dr. Dongho Kim Prof. Dr. Atsuhiro Osuka 《Angewandte Chemie (International ed. in English)》2015,54(10):3107-3111
A singly linked corrole dimer was synthesized by condensation of a dipyrromethane‐1‐carbinol with 1,1,2,2‐tetrapyrroethane. Oxidation of the dimer gave doubly linked corrole dimers 9 and 10 as the first examples of fused corrole dimers involving a meso–meso linkage. Dimers 9 and 10 exhibit characteristic 1H NMR spectra, absorption spectra, excited‐state dynamics, and two‐photon absorption (TPA) values, which indicate the nonaromatic nature of 9 and the aromatic nature of 10 . Interestingly, 9 is fairly stable despite its unusual 2H‐corrole structure, which has been ascribed to the presence of two direct connections between the individual corrole units. 相似文献
23.
High‐performance liquid chromatographic separations of stereoisomers of chiral basic agrochemicals with polysaccharide‐based chiral columns and polar organic mobile phases
下载免费PDF全文
![点击此处可从《Journal of separation science》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Iza Matarashvili Iamze Shvangiradze Lali Chankvetadze Shota Sidamonidze Nino Takaishvili Tivadar Farkas Bezhan Chankvetadze 《Journal of separation science》2015,38(24):4173-4179
The separation of the stereoisomers of 23 chiral basic agrochemicals was studied on six different polysaccharide‐based chiral columns in high‐performance liquid chromatography with various polar organic mobile phases. Along with the successful separation of analyte stereoisomers, emphasis was placed on the effect of the chiral selector and mobile phase composition on the elution order of stereoisomers. The interesting phenomenon of reversal of enantiomer/stereoisomer elution order function of the polysaccharide backbone (cellulose or amylose), type of derivative (carbamate or benzoate), nature, and position of the substituent(s) in the phenylcarbamate moiety (methyl or chloro) and the nature of the mobile phase was observed. For several of the analytes containing two chiral centers all four stereoisomers were resolved with at least one chiral selector/mobile phase combination. 相似文献
24.
Determination methods of halide ions (X(-) = F(-), Cl(-), Br(-) and I(-)) by electrospray ionization mass spectrometry (ESIMS) were developed, where negative ions of the ternary complexes of group-13 elements, nitrilotriacetic acid (NTA), and halides were measured. In particular, these halides were simultaneously determined by measuring [InX(nta)](-), and the limits of detection (LODs) were 1.1 μmol dm(-3) for F(-), 0.32 μmol dm(-3) for Cl(-), 3.8 nmol dm(-3) for Br(-), and 1.6 nmol dm(-3) for I(-), respectively. This approach was extended to the determination of CN(-), where the ternary complex of Cu(II), CN(-) and 4-(2-pyridylazo)resorcinol (PAR), i.e., [(63)Cu(II)(CN)(par)](-) (m/z 302) was measured. The LOD for CN(-) was 20 nmol dm(-3). 相似文献
25.
Spectrophotometric determination of titanium(IV) was accomplished with o-carboxyphenylfluorone (OCPF) in the presence of hexadecyltrimethyl ammonium chloride (HTAC) under strongly acidic media. In the determination of titanium(IV), Beer's law was obeyed in the range of 24-340 ng mL−1 with an effective molar absorption coefficient (at 530 nm) and relative standard deviation of 2.24 × 105 dm3 mol−1 cm−1 and 0.64% (n = 8), respectively. The severe interference of iron ions was easily eliminated by the addition of ethylenediaminetetraacetic acid (EDTA); the effects of other foreign substances were low. Equilibrium and kinetic studies under analytical conditions were investigated to quantitatively evaluate the reaction mechanism. The obtained orange complex is considered to be Ti(OCPF)4. Its stability log Kf and rate constant Kobs are 16.88 and 1.65 × 10−2 s−1, respectively. It is suggested that the color of the complex is related to the species of OCPF in the solution. 相似文献
26.
Shota Sato 《Journal of Mathematical Analysis and Applications》2011,380(2):632-641
We investigate the initial-boundary value problem
27.
Hayashi M Sasano Y Nagasawa S Shibuya M Iwabuchi Y 《Chemical & pharmaceutical bulletin》2011,59(12):1570-1573
A highly active organocatalyst for alcohol oxidation has been developed. 9-Azanoradamantane N-oxyl (Nor-AZADO 4), constituting an unhindered, stable nitroxyl radical, exhibits superior catalytic activity to 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and AZADOs in the oxidation of alcohols to their corresponding carbonyl compounds. 相似文献
28.
Shota Gugushvili Frank van der Meulen Peter Spreij 《Statistical Inference for Stochastic Processes》2018,21(1):53-79
Given a sample from a discretely observed compound Poisson process, we consider non-parametric estimation of the density \(f_0\) of its jump sizes, as well as of its intensity \(\lambda _0.\) We take a Bayesian approach to the problem and specify the prior on \(f_0\) as the Dirichlet location mixture of normal densities. An independent prior for \(\lambda _0\) is assumed to be compactly supported and to possess a positive density with respect to the Lebesgue measure. We show that under suitable assumptions the posterior contracts around the pair \((\lambda _0,\,f_0)\) at essentially (up to a logarithmic factor) the \(\sqrt{n\Delta }\)-rate, where n is the number of observations and \(\Delta \) is the mesh size at which the process is sampled. The emphasis is on high frequency data, \(\Delta \rightarrow 0,\) but the obtained results are also valid for fixed \(\Delta .\) In either case we assume that \(n\Delta \rightarrow \infty .\) Our main result implies existence of Bayesian point estimates converging (in the frequentist sense, in probability) to \((\lambda _0,\,f_0)\) at the same rate. We also discuss a practical implementation of our approach. The computational problem is dealt with by inclusion of auxiliary variables and we develop a Markov chain Monte Carlo algorithm that samples from the joint distribution of the unknown parameters in the mixture density and the introduced auxiliary variables. Numerical examples illustrate the feasibility of this approach. 相似文献
29.
David Natroshvili Shota Zazashvili 《Journal of Computational and Applied Mathematics》2010,234(6):1622-1630
The theory of elasticity of hemitropic materials has recently been the object of rigorous mathematical analysis. In particular, the potential method and the theory of pseudodifferential equations have been used in studying the solvability in various function spaces of the main boundary value and transmission problems, in smooth and in Lipschitz domains. The main features and results of this boundary integral equations approach are briefly reviewed here. 相似文献
30.
Junko Hirota Dr. Kazuteru Usui Dr. Yasufumi Fuchi Masaomi Sakuma Shota Matsumoto Ryusuke Hagihara Prof. Dr. Satoru Karasawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(65):14943-14952
Water-soluble donor–acceptor-type fluorophore 15Nap-Cl having two trifluoromethyl groups and a Cl group on a 1,5-aminonaphthyridine framework was prepared. Fluorophore 15Nap-Cl showed strong solvatochromic fluorescence, and, as the solvent polarity increased, a bathochromic shift was observed accompanied by an increase in the fluorescence quantum yield. In addition, in the presence of amines such as ethylamine, diethylamine, and aniline, further considerable bathochromic shifts in the fluorescence were observed. Density functional calculations identified the source of the fluorescence behavior as exciplex formation between 15-Nap-Cl and the corresponding amine. The fluorescence behavior was exploited to fabricate a sensor that can identify various primary, secondary, and tertiary amines. 相似文献