激光间接驱动惯性约束聚变二维总体程序——LARED集成程序

介绍了辐射流体力学程序LARED集成程序的物理背景、模型方程、数值方法和数值算例。该程序主要应用于激光间接驱动惯性约束聚变的二维整体模拟,兼顾激光直接驱动、辐射驱动靶丸内爆过程和流体不稳定性等物理过程的数值模拟。通过与实验数据、一维辐射流体力学程序进行比对,验证了程序的可靠性。该程序实现了多群输运建模下NIF点火靶的全过程数值模拟,并已应用于惯性约束聚变的物理研究。     

Acid controlled diastereoselectivity in asymmetric aldol reaction of cycloketones with aldehydes using enamine-based organocatalysts

The example of syn-aldol reaction of cyclohexanone to aldehyde was demonstrated based on chiral diamine organocatalysts and it was realized either by increasing the molecular size of acid additives or by introducing a hydrogen-bond donor into acid additives.     

Enabling High-Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte

Lithium metal is an ideal electrode material for future rechargeable lithium metal batteries. However, the widespread deployment of metallic lithium anode is significantly hindered by its dendritic growth and low Coulombic efficiency, especially in ester solvents. Herein, by rationally manipulating the electrolyte solvation structure with a high donor number solvent, enhancement of the solubility of lithium nitrate in an ester-based electrolyte is successfully demonstrated, which enables high-voltage lithium metal batteries. Remarkably, the electrolyte with a high concentration of LiNO₃ additive presents an excellent Coulombic efficiency up to 98.8 % during stable galvanostatic lithium plating/stripping cycles. A full-cell lithium metal battery with a lithium nickel manganese cobalt oxide cathode exhibits a stable cycling performance showing limited capacity decay. This approach provides an effective electrolyte manipulation strategy to develop high-voltage lithium metal batteries.     

Forecasting bifurcations of multi-degree-of-freedom nonlinear systems with parametric resonance

The location of bifurcation points and bifurcation diagrams is important for the understanding of a nonlinear system with parametric resonance. This paper presents a model-less method to predict bifurcations of slightly damped multi-degree-of-freedom nonlinear systems with parametric resonance using transient recovery data in the pre-bifurcation regime. This method is based on the observation that the envelope amplitude of a decaying response in the pre-bifurcation regime recovers more slowly to the equilibrium as the system becomes closer to the bifurcation. Data obtained from both simulations and experiments are used to forecast the location of the bifurcation point and the bifurcation diagram. Forecasting results demonstrate that the method can be used to predict the bifurcation accurately under a set of specific assumptions.     

梁在纯弯曲作用下的脆性断裂

脆性梁在纯弯曲断裂时会产生多个碎片, 其断裂过程直接影响弯曲波的产生和传播, 以及产生碎片的平均尺度. 采用内聚力断裂模型对脆性梁的弯曲断裂过程进行有限元数值模拟, 再现了断裂中的裂纹扩展过程, 分析了脆性梁断裂后断裂面弯矩与裂纹张开角之间的规律. 数值结果表明: (1)在一个广泛的材料参数和加载应变率条件下, 断裂面弯矩与裂纹张开角之间均呈相似的单调衰减规律; (2)断裂过程中弯矩做功与断裂面的表面能一致; (3)在纯弯矩作用下, 裂纹前端总是存在压应力区域, 使得断裂末期应力状态较为复杂, 断裂不再是纯弯曲状态.     

太阳光下高光催化活性Pr-N-P三元掺杂锐钛矿TiO2纳米片

利用溶胶-凝胶和溶剂热联合技术制备了Pr-N-P三元掺杂锐钛矿TiO₂（PrNPTO）纳米片,并采用X射线衍射、透射电镜、N₂吸附、X射线光电子能谱、UV-vis吸收谱和光致荧光光谱分析技术对其进行了表征.当Pr掺杂量为1.75wt%,焙烧温度为550℃时,制得的PrNPTO在可见和紫外光下光催化降解亚甲基蓝（MB）活性最佳.在模拟太阳光照射下,PrNPTO也表现出优越的光催化降解4-氯酚性能（k_app=3.90×10^-2min^-1）,优于未掺杂、单掺杂和双掺杂TiO₂样品,其光活性是P25TiO₂的3.33倍（k_app=1.17×10^-2min^-1）.PrNPTO光活性的提高归因于Pr-N-P三元掺杂增强了紫外和可见光吸收,降低了光生载流子复合,增加了表面羟基以及改善了表面织构特性.在模拟太阳光照射下,PrNPTO光催化效率高且光催化性能稳定,适合于环境净化领域的实际应用.     

聚酰亚胺碳分子筛气体分离膜的研究进展

聚酰亚胺碳分子筛膜由于具有较高的热稳定性、耐化学性、气体渗透性和选择性,而受到广泛关注。根据近年来聚酰亚胺碳分子筛膜在气体分离方面的研究现状,详细介绍了填充改性、对前驱体进行预处理和聚酰亚胺单体改性的研究成果,并展望了聚酰亚胺碳分子筛分离膜的发展趋势,以期为未来高效分离膜的研发提供参考。     

Investigations of kinetics and mechanism of chloropinnoite in boric acid aqueous solution at 303 K by Raman spectroscopy

Raman spectroscopy of dissolution and transformation of chloropinnoite in 4.5% (wt.%) boric acid aqueous solution at 303 K has been recorded. The Raman spectra of kinetics process have been obtained. The phase transformation product is 2MgO.3B2O3.15H2O (kurnakovite). The main polyborate anions and their interaction in aqueous solution have been proposed according to the Raman spectrum. Some assignments were tentatively given and the relations between the existing forms of polyborate anions and the crystallizing solid phases have been gained. A mechanism of dissolution and crystallization reactions and the formation condition of kurnakovite in Qinghai-Tibet plateau were proposed and discussed.