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排序方式: 共有134条查询结果,搜索用时 31 毫秒
21.
In this paper, the mathematical expressions and the particularities of the joint fractional Fourier transform correlator (JFRTC) are detailedly analyzed. In a JFRTC, the distance between the two fractional correlation peaks can be adjusted flexibly by shifting the fractional orders. However, the intensity of the fractional correlation peaks decreases rapidly as the first fractional order p1 drops. The former property is very useful in a practical recognition system, but the latter one seriously reduces the recognition sensitivity of a JFRTC. For this reason, phase masks should be added at the input plane of the JFRTC to enhance the intensities of the fractional correlation peaks and effectively overcome the default. Compared with the existing JFRTC with single phase modulation, a JFRTC with double phase modulation is suggested to more flexibly improve the performance of a JFRTC. 相似文献
22.
Shiyang Qin Guobin Xin Yuanfeng Wang Jing Qiao Wenfang Zhang Duoqi Xu Zizhen Xu Yongtao Liu Ying Zhang Jianghai Lu 《Journal of mass spectrometry : JMS》2019,54(8):704-715
Flunitrazepam (FNZ) is a potent hypnotic, sedative, and amnestic drug used to treat severe insomnia. In our recent study, FNZ metabolic profiles were investigated carefully. Six authentic human urine samples were purified using solid phase extraction (SPE) without enzymatic hydrolysis, and urine extracts were then analyzed by liquid chromatography‐Q exactive‐HF hybrid quadrupole‐Orbitrap‐mass spectrometry (LC‐QE‐HF‐MS), using the full scan positive ion mode and targeted MS/MS (ddms2) technique to make accurate mass measurements. There were 25 metabolites, including 13 phase I and 12 phase II metabolites, which were detected and tentatively identified by LC‐QE‐HF‐MS. In addition, nine previously unreported phase II glucuronide conjugates and four phase I metabolites are reported here for the first time. Eight metabolic pathways, including N‐reduction and O‐reduction, N‐glucuronidation, O‐glucuronidation, mono‐hydroxylation and di‐hydroxylation, demethylation, acetylation, and combinations, were implicated in this work, and 2‐O‐reduction together with dihydroxylation were two novel metabolic pathways for FNZ that were identified tentatively. Although 7‐amino FNZ is widely considered to be the primary metabolite, a previously unreported metabolites (M12) can also serve as a potential biomarker for FNZ misuse. 相似文献
23.
使用二维多群辐射扩散流体力学程序LARED-S,模拟研究靶丸支撑膜在惯性约束聚变氘氘(DD)气体靶内爆过程中的扰动演化过程及其对内爆性能的影响.二维模拟表明:靶丸支撑膜显著降低DD气体靶内爆的中子产额,二维模拟产额为一维结果的55.2%.内爆性能下降的主要物理机制是支撑膜使靶壳生成大幅度的尖钉深入DD气体区,使烧蚀层与DD气体之间物质界面处的电子热传导漏失功率显著增大,导致DD核反应速率显著降低,中子反应速率峰值时刻(bang-time时刻)提前.相比一维理想内爆的模拟结果,支撑膜引入的扰动显著降低bang-time时刻DD气体压强与内爆动能转化为DD气体内能的效率,壳层剩余动能相应大幅增加. 相似文献
24.
25.
Fault estimation for rotary steerable drilling tool systems with strong vibrations and unknown terms
Liu Shiyang Gao Ming Sheng Li Niu Yichun Wang Yuechao Zhou Donghua 《Nonlinear dynamics》2023,111(10):9161-9175
Nonlinear Dynamics - In this paper, the problem of gyro fault estimation is studied for the dynamic point-the-bit rotary steerable drilling tool system (DPRSDTS), and it is essentially the fault... 相似文献
26.
Optical Review - Fringe projection profilometry is widely used for the 3D measurement of real-world objects; however, quickly obtaining high-precision 3D measurements is an issue that needs to be... 相似文献
27.
Liu J Bai S Jin Q Zhong H Li C Yang Q 《Langmuir : the ACS journal of surfaces and colloids》2012,28(25):9788-9796
The highly ordered mesoporous silicas with elaborately controlled microenvironment were synthesized via covalent incorporation of long-chain polymers (M(w) = 2000 g mol(-1)) bearing specific hydrophilic/hydrophobic balance. The microenvironment (hydrophilicity/hydrophobicity) of the mesoporous silicas was quantitatively determined by gas adsorption experiments and investigated by lysozyme (LYZ) adsorption. The relative activity of lipase from Pseudomonas cepacia (PCL) encapsulated in the mesoporous silica with moderate hydrophobic microenvironment (hereafter denoted as MHM) reaches up to 281% compared with the free PCL, notably higher than that of PCL accommodated in the mesoporous silicas with hydrophilic or strong hydrophobic microenvironment (20.7-26.2% relative to the free PCL). Moreover, PCL entrapped in the nanochannels with MHM affords the highest initial rate in the kinetic resolution of (R,S)-1-phenylethanol relative to other immobilized PCL. The above results suggest that the MHM could render the active center of PCL entirely exposed to the substrates without interrupting its native conformation in the "interfacial activation". In addition, the nanochannels with MHM could markedly improve the thermal stability of PCL (preserving nearly 60% of the initial activity after the incubation at 70 °C for 2 h) and facilitate the recycling of the immobilized PCL in both aqueous and organic media. Our work demonstrates that the subtle modulation of the microenvironment of mesoporous silicas for enzyme immobilization designates a very promising strategy to fabricate the highly active and stable heterogeneous biocatalysts for industrial application. 相似文献
28.
Shao Z Li H Zhang S Li J Dai Z Mo Y Bae YJ Kim MS 《The Journal of chemical physics》2012,136(6):064308
The energy levels of CH(3)Cl(+)X?(2)E showing strong spin-vibronic coupling effect (Jahn-Teller effect) have been measured up to 3500 cm(-1) above the ground vibrational state using one-photon zero-kinetic energy photoelectron and mass-analyzed threshold ionization spectroscopic method. Theoretical calculations have been also performed to calculate the spin-vibronic energy levels using a diabatic model and ab initio adiabatic potential energy surfaces (PESs). In the theoretical calculations the diabatic potential energy surfaces are expanded by the Taylor expansions up to the fourth-order including the multimode vibronic interactions. The calculated spin-orbit energy splitting (224.6 cm(-1)) for the ground vibrational state is in good agreement with the experimental data (219 ± 3 cm(-1)), which indicates that the Jahn-Teller and the spin-orbit coupling have been properly described in the theoretical model near the zero-point energy level. Based on the assignments predicted by the theoretical calculations, the experimentally measured energy levels were fitted to those from the diabatic model by optimizing the main spectroscopic parameters. The PESs from the ab initio calculations at the level of CASPT2/vq(t)z were thus compared with those calculated from the experimentally determined spectroscopic parameters. The theoretical diagonal elements in the diabatic potential matrix are in good agreement with those determined using the experimental data, however, the theoretical off-diagonal elements appreciably deviate from those determined using the experimental data for geometric points far away from the conical intersections. It is also concluded that the JT effect in CH(3)Cl(+) mainly arises from the linear coupling and the mode coupling between the CH(3) deform (υ(5)) and CH(3) rock (υ(6)) vibrations. The mode couplings between the symmetric C-Cl stretching vibration υ(3) with υ(5) and υ(6) are also important to understand the spin-vibronic structure of the molecule. 相似文献
29.
李志超 赵航 龚韬 李欣 杨冬 蒋小华 郑坚 刘永刚 刘耀远 陈朝鑫 李三伟 李琦 潘凯强 郭亮 理玉龙 徐涛 彭晓世 吴畅书 张桦森 郝亮 蓝可 陈耀桦 郑春阳 古培俊 王峰 蔡洪波 郑无敌 邹士阳 杨家敏 江少恩 张保汉 朱少平 丁永坤 《强激光与粒子束》2020,32(9):092004-1-092004-14
当前,激光惯性约束聚变在越来越接近点火的极端能量密度条件下,实验与模拟的偏离逐渐增大,一个关键原因是缺乏对黑腔等离子体状态及其影响黑腔能量学和内爆对称性的细致研究和判断。光学汤姆逊散射主动式、诊断精确、参数完备的优点,使之成为激光惯性约束聚变黑腔等离子体状态参数精密诊断的标准方法。中国面向激光惯性约束聚变研究的光学汤姆逊散射实验技术的发展与神光系列激光装置的建设和在其上开展的物理实验紧密相关。近年来,四倍频汤姆逊散射实验技术在神光III原型和100 kJ激光装置上相继建立,部分实验结果不仅加深了对激光惯性约束聚变靶物理的认识,还反映了实验条件对汤姆逊散射诊断的影响,促进了实验技术的精密化发展。在未来,还需要进一步发展多支路汤姆逊散射、五倍频汤姆逊散射和超热相干汤姆逊散射等新技术,面向点火黑腔条件,大幅提升激光等离子体状态参数的诊断精度,开展新物理机制的探索和研究,在激光惯性约束聚变和其他高能量密度物理科学领域发挥更重要的作用。 相似文献
30.
SOI(Silicon-on-Insulator)技术被认为是21世纪的硅集成电路技术,近年来,国际上出现了一种引人注目的SOI制备新技术-智能剥离(Smartcut)技术,它的出现为解决SOI技术中质量与价格的矛盾带来了新的希望,将会有力地堆动SOI技术的进一步发展,文章简要回顾了目前存在的几种SOI制备技术,并结合我们的工作重点介绍了智能剥离这种有竞争力的SOI制备新技术。 相似文献