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71.
Shinya Harusawa 《Tetrahedron》2004,60(51):11911-11922
A novel measuring method (electroimmunoassay) of 17β-estradiol (E2) in urine or blood was proposed on the basis of a competition between E2 and a labeled E2 against an immobilizing antibody. To evaluate the principle, 3-{4-[17β-hydroxy-1,3,5(10)-estratrien-3-yloxy]butyldisulfanyl}-N-(6,7,9,10,12,13,15,16-octahydro-5,8,11,14,17-pentaoxabenzocyclopentadecen-2-yl) succinamic acid (1) was designed and synthesized as a novel aminobenzo-15-crown-5-containing E2 tethered with disulfide linkage. Two thiol-intermediates 5b and 19c were efficiently synthesized from mercaptosuccinic acid 7 and 4,4′-dithiodibutyric acid 12, respectively. Formations of disulfide linkages from less reactive thiols were examined and 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) could be employed for the formation of an unsymmetrical disulfide 20c from 5b and 19c. Then, removal of TMS- and allyl-protecting groups in 20c successfully afforded the crown ether-containing E21. 相似文献
72.
Morimoto Y Kohyama S Nakai K Matsuo H Karasawa F Kikuchi M 《Photochemistry and photobiology》2003,78(4):372-376
Several studies have shown that UV irradiation may be effective for preventing vascular restenosis or vasopasm. However, the long-term effects of UV light on the physiological properties of vessels such as arterial tension have not been elucidated. We therefore studied the long-term effects of UV using rat carotid arteries treated with UV-B light (wavelength = 313 nm, total energy = 14 mJ/mm2). The animals were sacrificed at 1, 7 and 14 days after UV light exposure, and the carotid arteries were studied by light microscopy and the contractile responses of isolated arterial rings were recorded under isometric tension. UV treatment had induced a substantial loss of smooth muscle cells (SMC) along the entire circumference of the media on days 7 and 14, whereas loss of SMC on day 1 was negligible. Contractile responses of arteries that had been exposed to UV light were significantly reduced on days, 1, 7 and 14. The susceptibility of UV-treated arteries to phenylephrine and prostaglandin F2 alpha was significantly decreased on days 1 and 7, but decreased susceptibility was not seen on day 14. Acetylcholine-induced relaxations were not altered by UV treatment. These results suggest that the long-term effect of UV light is an attenuation of smooth muscle contractility without impairment of endothelial function. 相似文献
73.
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75.
Byungchan Bae Shinya Kawamura Kenji Miyatake Masahiro Watanabe 《Journal of polymer science. Part A, Polymer chemistry》2011,49(17):3863-3873
Random and multiblock sulfonated poly(arylene ether sulfone)s (SPEs) containing various azole groups such as oxadiazole and triazole were synthesized and characterized for fuel cell application. Successful preparation of SPE membranes depended on the structure of azole groups, which affected solubility of precursors and the resulting SPEs. Although oxadiazole groups were incorporated into hydrophobic component, they were found to be hydrophilic to give higher proton conductivity. Introduction of oxadiazole groups into random SPE gave comparable proton conductivity to that of Nafion NRE at >60% relative humidity at 80 °C. Block copolymer structure further increased the proton diffusion coefficient without increasing ion exchange capacity. Hydrolytic and oxidative stability of the SPE membranes was affected by both hydrophilic and hydrophobic components. Oxadiazole groups gave negative impact on hydrolytic and mechanical stability to the SPE membranes. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
76.
Mitsuhisa Narukawa Shinya KoideHideto Miyake Kazumasa Hiramatsu 《Journal of Crystal Growth》2009,311(10):2970-2972
Undoped and Zn-doped GaN nanowires were synthesized by chemical vapor deposition (CVD), and the effects of substrates, catalysts and precursors were studied. A high density of GaN nanowires was obtained. The diameter of GaN nanowires ranged from 20 nm to several hundreds of nm, and their length was about several tens of μm. The growth mechanism of GaN nanowires was discussed using a vapor–liquid–solid (VLS) model. Furthermore, room-temperature cathodoluminescence spectra of undoped and Zn-doped GaN nanowires showed emission peaks at 364 and 420 nm, respectively. 相似文献
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78.
A balanced vertex-coloring of a graph G is a function c from V(G) to {−1,0,1} such that ∑{c(v):v∈V(G)}=0. A subset U of V(G) is called a balanced set if U induces a connected subgraph and ∑{c(v):v∈U}=0. A decomposition V(G)=V1∪?∪Vr is called a balanced decomposition if Vi is a balanced set for 1≤i≤r.In this paper, the balanced decomposition number f(G) of G is introduced; f(G) is the smallest integer s such that for any balanced vertex-coloring c of G, there exists a balanced decomposition V(G)=V1∪?∪Vr with |Vi|≤s for 1≤i≤r. Balanced decomposition numbers of some basic families of graphs such as complete graphs, trees, complete bipartite graphs, cycles, 2-connected graphs are studied. 相似文献
79.
80.
The interaction of gaussian evanescent light with a single dielectric sphere or ordered dielectric spheres in an attenuated total reflection (ATR) geometry was analyzed by the finite-difference time-domain method. Various aspects of this interaction were investigated in terms of spatial visualizations of light intensity, reflectance vs. wavelength characteristics, the transient behavior of reflectances, and so forth. In the case of a single sphere, it was evident that the whispering gallery mode can be excited in ATR geometries, but such excitation cannot be easily confirmed only through the observation of wavelength-scanned ATR spectra. In the case of a closely packed two-dimensional array of dielectric spheres, it was found that an easy axis and also a difficult axis for light propagation exist.This paper was originally presented at the 5th International Conference on NEAR FIELD OPTICS and RELATED TECHNOLOGIES (NFO-5), which was held on December 6–10, 1998 at Coganoi Bay Hotel, Shirahama, Japan, in cooperation with the Japan Society of Applied Phisics and Mombusho Grantin Aid for Scientific Research on Priority Areas “Near-field Nano-optics” Project, sponsored by Japan Society for the Promotion of Science. 相似文献