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51.
M. L. Occelli S. A. C. Gould J. M. Tsai B. Drake 《Journal of molecular catalysis. A, Chemical》1995,100(1-3):161-166
When vanadyl naphthanate solutions in toluene are used to V-contaminate rectorite pillared with alumina clusters, V migration from the pillared clay microporous structure to the outer surface occurs during the thermal treatments used in catalyst preparation. The presence of V on the clay catalyst surface can be inferred from atomic force microscopy (AFM) images showing a marked decrease in surface roughness resulting from the presence of vanadia. AFM images show what are believed to be islands as well as stacks of vanadia layers on the clay surface. Irrespective of the thermal and hydrothermal treatments used to prepare these catalysts, atomic scale details of V-contaminated clay samples retain the surface parameters characteristic of the silicate layers in smectites. These results suggest that V on the clay surface is present as V=O groups attached to the three basal oxygens of the SiO4 units that form the clay silicate layers. These VO units form an hexagonal arrangement of white spots having next neighbor (dc) and lateral distance (dl) of 5.2 Å and 9.1 Å, respectively. 相似文献
52.
To elucidate the disposition of nicotine in the brain is important because the neuropharmacological effects from nicotine exposure are centrally predominated. The aim of the present study was to develop a rapid and simple method for the simultaneous determination of unbound nicotine and its main metabolite, cotinine, in rat blood and brain tissue. We coupled a multiple sites microdialysis sampling technique with HPLC-UV system to characterize the pharmacokinetics of both nicotine and cotinine. Microdialysis probes were inserted into the jugular vein/right atrium and brain striatum of Sprague-Dawley rats, and nicotine (2 mg/kg, i.v.) was administered via the femoral vein. Dialysates were collected every 10 min and injected directly into a HPLC system. Both nicotine and cotinine were separated by a phenyl-hexyl column (150 mm x 4.6 mm) from dialysates within 12 min. The mobile phase consisted of an acetonitrile-methanol-20 mM monosodium phosphate buffer (55:45:900, v/v/v, pH adjusted to 5.1) with a flow-rate of 1 ml/min. The wavelength of the UV detector was set at 260 nm. The limit of quantification for nicotine and cotinine were 0.25 microg/ml and 0.05 microg/ml, respectively. Intra- and inter-day precision and accuracy of both measurements fell well within the predefined limits of acceptability. The blood and brain concentration-time profile of nicotine and cotinine suggests that nicotine is easily to get into the central nervous system and cotinine exhibits a long retention time and accumulates in blood. 相似文献
53.
The diffusion of 1H in the fast protonic conductor H(UO2PO4) · 4H2O has been investigated as a function of temperature by employing pulsed field gradient NMR measurements. In the light of the present diffusion results and published conductivity observations on the same compound, it is likely that protonic diffusion and conductivity in this material occur by the same mechanism. Possible mechanistic processes for the proton motion in this material which are consistent with the activation energy for protonic diffusion found in this study are briefly discussed. 相似文献
54.
Effect of particle size of activated clay on the adsorption of paraquat from aqueous solution 总被引:4,自引:0,他引:4
This paper describes the effect of particle size on the process of paraquat adsorption from aqueous solution onto an activated clay surface at 25 degrees C and initial pH 11.0. Measurements of the pore properties of the clay adsorbents with three different particle sizes (0.053-0.074 mm, 0.037-0.053 mm, and <0.037 mm) were carried out. The rates and isotherms of adsorption have been also investigated by batch methods under the controlled conditions. From the experimental results obtained, the adsorption process can be well described with the pseudo-second order model and Freundlich model for adsorption kinetics and adsorption isotherm, respectively. In addition, the effect of the particle size of the clay adsorbent on the adsorption kinetics was found to be of considerable significance; namely, the rate constant (k) of paraquat adsorption by the clay adsorbent decreased with increasing particle size. It was concluded that the pore properties (i.e., surface area and total pore volume) and particle size of the clay adsorbent played a significant role in determining adsorption capacity and adsorption rate, respectively. 相似文献
55.
In this study, we developed an analytical method for the enantioseparation of ofloxacin, using capillary electrophoresis with fluorescence detection. The optimum background electrolyte was obtained to be 60 mM hydroxylpropyl‐β‐cyclodextrin (HP‐β‐CD) in 50 mM phosphate buffer at pH 2.30. Under these conditions, the (+) and (‐) ofloxacin were completely separated, with the detection limit of 10 nM when the sample was prepared in deionized water. The linear ranges of levofloxacin in deionized water and untreated urine were 10?7 to 5 × 10?3 M with R2 = 0.9989 and 5 × 10?6to 5 × 10?3 M with R2 = 0.9943, respectively. We also applied this method to investigate the purity of a commercial drug. The results revealed that the ratio between (+)‐ofloxacin and (‐)‐ofloxacin (levofloxacin) was 99.9:0.1, and there is about 93 mg levofloxacin per tablet (200 mg). The concentration of levofloxacin in patient's urine was founded to be 7.9 × 10?4M, and the ratio between the two optical isomers was 99.3:0.7. 相似文献
56.
An approach to analysis of pigment release from microcapsules with size distribution 总被引:2,自引:0,他引:2
Takao Yamamoto Toshiaki Dobashi Miho Kimura Chih Pong Chang 《Colloids and surfaces. B, Biointerfaces》2002,25(4):305-311
We have studied the release curve for microcapsules with size distribution. On the basis of an analogy to the relaxation phenomena with multiple characteristic times, we propose a stretched exponential release curve for the system with size distribution and relate the release curve to the size distribution function of the microcapsule. This method was successfully applied to the transfer of azo-pigments from inner medium of dioctyl phthalate to dispersing medium of methanol through poly(ureaurethane) microcapsule membrane. 相似文献
57.
The determination of lanthanides by Inductively Coupled Plasma Mass Spectrometry (ICP‐MS) is complicated by several spectral overlaps from M+, MO+ or MOH+ ions formed in the ICP. Especially, it is essential to avoid the spectral interferences from lighter lanthanide and Ba polyatomic ions on middle or heavier lanthanides. To tackle this problem, we have developed a mathematical correction method, which reduces all the spectral overlaps from oxide species of Pr, Nd, Ce and Sm over Gd, Tb, Dy and Ho, and Gd, Tb over Yb and Lu. It can also successfully correct the oxide and hydroxide interference of Ba over Eu. The effectiveness of the proposed the mathematical correction scheme is demonstrated for the USGS Standard Rock samples AGV‐1 and G‐2. The results show that the experimental data obtained by applying the mathematical correction scheme for lanthanides is in good agreement with the reported values, using pneumatic and ultrasonic nebulisation methods, for their ICP‐MS analysis. 相似文献
58.
Given a family of Riemann surfaces and a holomorphic vector bundle Beilinson and Schechtman construct a canonical connection on the associated determinant bundle. We prove the conjecture which states that their connection coincides with the Quillen connection. This is done by reducing to the case where
along fibers are invertible. Both connection forms become more accessible in this case.Supported in part by N.S.F. Grant No. DMS-9201022Supported in part by National Science Council of Republic of China Grant No. NSC 82-0208-M-002-125-T, and NSERC of Canada Grant No. OGP 0121883 相似文献
59.
60.