In this paper, the authors establish the LP-mapping properties of certain classes of Marcinkiewicz integral operators along surfaces with rough kernels. The results in this paper essentially extend as well as improve previously known results. 相似文献
In the age of information globalization, research on the mechanism of propagation will help mitigate the bad influence of rumors. Based on the classical rumor propagation model, this paper further analyzes the internal mechanism of the stochastic rumor propagation model incorporating media coverage with white noise. We investigate the existence of a unique global positive solution to the model and study the dynamic properties of the solutions around the rumor-free and local equilibrium points of the deterministic model. Furthermore, we establish sufficient conditions for the existence of traversal static distribution in the model. Numerical simulation shows that the role of media coverage is crucial to reduce the rumor propagation scale. The larger the coverage rate is, the smaller the rumor propagation scale is. 相似文献
First-order hyperbolic partial differential equations with two internal variables have been used to model biological and epidemiological problems with two physiological structures, such as chronological age and infection age in epidemic models, age and another physiological character (maturation, size, stage) in population models, and cell-age and molecular content (cyclin content, maturity level, plasmid copies, telomere length) in cell population models. In this paper, we study nonlinear double physiologically structured population models with two internal variables by applying integrated semigroup theory and non-densely defined operators. We consider first a semilinear model and then a nonlinear model, use the method of characteristic lines to find the resolvent of the infinitesimal generator and the variation of constant formula, apply Krasnoselskii’s fixed point theorem to obtain the existence of a steady state, and study the stability of the steady state by estimating the essential growth bound of the semigroup. Finally, we generalize the techniques to investigate a nonlinear age-size structured model with size-dependent growth rate.
Magnetoresistance material Sr2FeMoO6 with double perovskite structure was synthesized by microwave sintering method using SrCO3, Fe2O3 and MoO3 as raw materials, with MnO2 for microwave absorber. The phase structure, magnetic and electrical transport properties were investigated by X-ray powder diffraction (XRD) and vibrating-sample magnetometer. XRD analysis shows that the as-synthesized sample is Sr2FeMoO6 with tetragonal crystal structure and I4/mmm space group. The unit cell parameters are a=0.5587 nm, c=0.7894 nm, volume=0.2464 nm3. The calculated grain size of the sample is 31.62 nm, which is obtained by the Scherrer formula using the diffraction data. Magnetism testing results show that the sample Sr2FeMoO6 is ferromagnetic with the magnetic transition temperature of about 380 K. Under 1.0 T magnetic field, the saturation and spontaneous magnetization of Sr2FeMoO6 is 1.25 μB/f.u. and 1.00 μB/f.u. at room temperature. The magnetoresistance ratio of the sample is 28%. Electrical transport properties testing results indicate that the sample exhibits typical semiconductor behavior. The conductive mechanism of Sr2FeMoO6 is highly dependent on temperature: within the temperature range of 100–300 K, the mechanism is attributed to the small polaron variable-range hopping model; while it is ascribed to the adiabatic small polaron model within the temperature range of 80–100 K. 相似文献
Porous metal-organic frameworks (MOFs) are highly ordered crystalline materials prepared by the self-assembly of metal ions with organic linkers to yield low density network structures of diverse topology. MOFs have attracted considerable attention over the last decade due to their facile preparation, tunable pore metrics and the ease of functionalisation of their internal surfaces, such that designer frameworks with exceptional properties for application in gas-storage, separation of small molecules, heterogeneous catalysis and drug delivery are becoming commonplace. For any material to find practical utility however, there is a need for processing and formulation into application-specific configurations. One way to do this is to prepare composite materials where the MOF is supported on a planar substrate or some other shaped body through interaction with functional groups at the support interface. This is a rapidly developing research area, and this review provides an overview of the diverse MOF composite materials prepared up to now, organised by interface type. The importance of the interface is explored within each section and while the overall emphasis is on applications of the composites, coatings and MOF-based devices, the most widely-used and successful synthetic strategies for composite formation are also presented. (183 references). 相似文献
The magnetic properties and electronic structures of ferromagnetic nanowires (FM=Fe, Co and Ni) encapsulated inside a zigzag (12,0) boron nitride nanotube (BNNT) are investigated by first-principle calculations. The relaxed geometry structures of FM/BNNT systems have only slightly changed. Formation energy analysis shows that the combining processes of Co/BNNT and Ni/BNNT systems are exothermic, and therefore the Co and Ni nanowires can be encapsulated into a semiconducting zigzag (12,0) BNNT and form stable hybrid structures. The charges are transferred from ferromagnetic nanowires to more electronegative BNNTs, and the formed FM–N bonds have covalent bond characteristics. The magnetic moments of FM/BNNT systems are smaller than those of the freestanding ferromagnetic nanowires, especially for the atoms on the outermost shell of the nanowires. The stable FM/BNNT systems exhibit higher magnetic moments, which can be useful for a wide variety of next-generation nanoelectronic device components. 相似文献
Six Al(1%wtSi)/Zr multilayers are deposited on Si substrates by using the direct-current magnetron sputtering system, and annealed from 100?°C to 500?°C temperature in a vacuum furnace for 1?h. To evaluate the thermal stability of Al(1%wtSi)/Zr multilayers, the multilayers were characterized by grazing incidence X-ray reflectance, X-ray diffraction, X-ray emission spectroscopy, and near-normal incident extreme ultraviolet (EUV) reflection. The symmetric and asymmetric interlayer models are used to present the interfacial structure before and after 300?°C. The Al(1%wtSi)/Zr multilayer annealed up to 200?°C maintains the initial symmetric multilayer structure, and keeps almost the similar EUV reflectivity as the nonannealed sample. From 300?°C, interdiffusion is much greater at the Zr/Al interface compared with the Al/Zr interface. And the interfacial phases of Al-Zr alloy transform from amorphous to polycrystalline, which induces the deterioration of multilayer structure and the decrease of EUV reflectivity. However, up to 500?°C, the polycrystalline Al-Zr compound does not destroy the multilayer completely. 相似文献
The interaction of aconitine with bovine serum albumin (BSA) and effect of atropine sulphate and glycyrrhizic acid on binding constant, binding sites, and conformation were studied in an aqueous buffer solution (pH 7.40) by ultraviolet absorption and fluorescence spectroscopy. The study results show that aconitine quenched the endogenous fluorescence of BSA via a dynamic quenching procedure. Predominant intermolecular forces between aconitine and BSA were hydrophobic interactions, which stabilized the complex of aconitine–BSA. The distance between the donor and acceptor was 2.62 nm. The conformation of BSA was investigated by synchronous fluorescence techniques, indicating that the microenvironment around tryptophan (Trp) residues was changed. Furthermore, with the addition of atropine sulphate or glycyrrhizic acid, binding constant and the number of binding sites of aconitine to BSA were decreased, and the conformation had no change, which provide an important theoretical support for aconitine detoxification by atropine sulphate and glycyrrhizic acid. 相似文献
Alkane C-H bond activation by various catalysts and enzymes has attracted considerable attention recently, but many issues are still unanswered. The conversion of ethane to ethanol and ethene by bare [Fe(III)═O](+) has been explored using density functional theory and coupled-cluster method comprehensively. Two possible reaction mechanisms are available for the entire reaction, the direct H-abstraction mechanism and the concerted mechanism. First, in the direct H-abstraction mechanism, a direct H-abstraction is encountered in the initial step, going through a collinear transition state C···H···O-Fe and then leading to the generation of an intermediate Fe-OH bound to the alkyl radical weakly. The final product of the direct H-abstraction mechanism is ethanol, which is produced by the hydroxyl group back transfer to the carbon radical. Second, in the concerted reaction mechanism, the H-abstraction process is characterized via overcoming four/five-centered transition states (6/4)TSH_c5 or (4)TSH_c4. The second step of the concerted mechanism can lead to either product ethanol or ethene. Moreover, the major product ethene can be obtained through two different pathways, the one-step pathway and the stepwise pathway. It is the first report that the former pathway starting from (6/4)IM_c to the product can be better described as a proton-coupled electron transfer (PCET). It plays an important role in the product ethene generation according to the CCSD(T) results. The spin-orbital coupling (SOC) calculations demonstrate that the title reaction should proceed via a two-state reactivity (TSR) pattern and that the spin-forbidden transition could slightly lower the rate-determining energy barrier height. This thorough theoretical study, especially the explicit electronic structure analysis, may provide important clues for understanding and studying the C-H bond activation promoted by iron-based artificial catalysts. 相似文献