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111.
A simple model has been developed to describe the Zeeman patterns of far-infrared laser magnetic resonance spectra of the monobromomethyl radical CH2Br observed at 447.3 and 671.1μm. A satisfactory agreement between the experimental spectra of the radical and their simulation with this simple model has been achieved. This approach can be used to gain further information about the structure and the spectrum of this interesting radical. 相似文献
112.
With different amounts of KCl added in the PNBA(p- nitro benzoic acid) aqueous solution, the factors affecting the SERS (Surface Enhanced Raman Scattering) are studied systematically on the surface of Copper. The results show that in PNBA aqueous solution the occurrence of SERS effect stongly depends on the existence of Cl-. The amount of KCl added affects not only the emergence and the intensity of SERS effect, but also the adsorption properties such as the adsorption manner,etc. 相似文献
113.
以噻吩为单体,在等离子体环境中聚合成致密的有机膜。利用Rutherford背散射(RB2S)和质子弹性反冲(ERD)、傅里叶红外谱(FTIR)测定了膜的成分和结构;从近红外-可见-紫外光的反射和透射谱,运用传递矩阵方法研究了膜的光学性质;此外,还探讨了24keV的I+离子束的注入对等离子体噻吩聚合膜的掺杂效应。结果表明,注入层内电荷载流子的输运机理可用Mott的可变自由程跳跃(VRH)理论给以解释。
关键词: 相似文献
114.
The electrochemical oxidation of 1, 3-benzenedithiol was investigated in a 0. 100 mol/L tetrabutylammonium perchlorate/acetonitrile electrolyte. The electrochemical techniques used were potential sweep, bulk electrolysis, rotating disc and the potential step method. The combination of the techniques yielded the number of electrons transferred per molecule, the reaction order, the transfer coefficient, the diffusion coefficient and concentration of dithiol anions, the standard heterogeneous rate constant as well as the formal potential and equilibrium constant of the preceeding dissociation reaction. This paper also illustrates the methods for studying the electrode kinetics of reactions which (a) involve a chemical reaction preceeding the electron-transfer process, (b) have insoluble polymer products, and (c) are totally irreversible. 相似文献
115.
从日本冲绳采回枝管藻,用毛细管将成熟多室孢子囊挑出,在试验室条件下培养,可长成孢子体.用光学显微镜和透射电子显微镜观察发现:孢子释放后形成盘状体附着在基质上,念珠状同化丝从盘状体中间分生.同化丝可从中间部位产生分支,多室孢子囊位于部分同化丝的近端部;同化丝大量产生后基部细胞平行排列,中空,形成假薄壁组织,而后孢子体进入伸长生长阶段;在每个盘状体细胞和同化丝细胞中都有多个色素体和线粒体,蛋白核突出于色素体其他部分,类脂体存在于类囊体中;在同化丝的细胞壁上存在缺口;对同化纤毛而言,色素体和线粒体数量少,紧贴细胞膜,质壁分离严重,在细胞壁上存在“通道”. 相似文献
116.
Richard Becker Mladen Prester Ping Hui Lin Mats Johnsson Ivica Zivkovic 《Journal of solid state chemistry》2007,180(3):1051-1059
Two new isostructural cobalt selenite halides Co5(SeO3)4Cl2 and Co5(SeO3)4Br2 have been synthesized. They crystallize in the triclinic system space group P−1 with the following lattice parameters for Co5(SeO3)4Cl2: a=6.4935(8) Å, b=7.7288(8) Å, c=7.7443(10) Å, α=66.051(11)°, β=73.610(11)°, γ=81.268(9)°, and Z=1. The crystal structures were solved from single-crystal X-ray data, R1=3.73 and 4.03 for Co5(SeO3)4Cl2 and Co5(SeO3)4Br2, respectively. The new compounds are isostructural to Ni5(SeO3)4Br2.Magnetic susceptibility measurements on oriented single-crystalline samples show anisotropic response in a broad temperature range. The anisotropic susceptibility is quantitatively interpreted within the zero-field splitting schemes for Co2+ and Ni2+ ions. Sharp low-temperature susceptibility features, at TN=18 and 20 K for Co5(SeO3)4Cl2 and Co5(SeO3)4Br2, respectively, are ascribed to antiferromagnetic ordering in a minority magnetic subsystem. In isostructural Ni5(SeO3)4Br2 magnetically ordered subsystem represents a majority fraction (TN=46 K). Nevertheless, anisotropic susceptibility of Ni5(SeO3)4Br2 is dominated at low temperatures by a minority fraction, subject to single-ion anisotropy effects and increasing population of Sz=0 (singlet) ground state of octahedrally coordinated Ni2+. 相似文献
117.
We report on a new type of Fano effect, named as Andreev-Fano effect, in a hybrid normal-metal/supeeconductor (N/S) interferometer embedded with a quantum dot. Compared with the conventional Fano effect, AndreevFano effect has some new features related to the characteristics of Andreev reflection. In the Iinear response regime, the line shape is the square of the conventional Fano shape, while in the nonlinear transport, a sharp resonant structure is superposed on an expanded interference pattern, which is qualitatively different from the conventional Fano effect. The phase dependence of the hybrid N/S interferometer is also distinguished from those of all-N or all-S interferometers. 相似文献
118.
Zhihui Zhao Hui Dai Xiangmei Wu Haitao Chang Xiaoming Gao Mengjun Liu Pengfei Tu 《Chemistry of Natural Compounds》2007,43(4):374-376
A pectic polysaccharide was isolated from the fruits of Ziziphus jujuba Mill. cv. jinsixiaozao Hort. and its structure was characterized by acid hydrolysis, methylation, and NMR spectroscopies.
The purified fraction Ju-B-7 had a molecular mass of over 2000 kDa. Chemical and spectroscopic analyses indicated that Ju-B-7
is composed mainly of α-1,4-linked D-galactopyranosyluronic acid and 1,2-linked L-rhamnose with a molar ratio of 8.1:1. It can significantly stimulate
spleen cell proliferation in vitro (P<0.01, 10 μmg/mL).
Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 311–312, July–August, 2007. 相似文献
119.
为了实验研究粲偶素ψ'级联衰变过程ψ'→γ'xcJ→γ'γJ/ψ,一个用于正确描述全部末态角分布的产生子是必要的.可以通过分析角分布的关联来确定这一过程的多极展开参数(或者等效的螺旋度振幅),而从中可以知道高阶电磁多极矩和相对论修正的贡献,同时可以检验ψ'是不是ψ'(2S)和ψ'(1D)的混合.介绍了一个能完全描述这一过程的角分布的产生子,同时讨论了测量多极参数的测量方法.这些都可以被用在BESⅢ或者CLEOc的分析当中. 相似文献
120.
基于事前评价过程和自然界生物进化过程的相似性,提出了系统结构、系统结构模式和系统环境模式矩阵的概念,并根据系统结构、系统结构模式与系统环境模式矩阵的适应程度,建立了模式评价决策模型,制定了评价系统的评价分类准则,并对评价系统作了一定的理论分析.将此模型和方法应用于城市生态安全评价中,通过与模糊综合评价法的比较,表明了该评价模型和方法的优越性. 相似文献