A self-consistent field procedure for stationary states using an algebraic approach and the maximum entropy formalism

A stationary state of maximal entropy is derived as a solution of a variational procedure. Generators of a continuous group are used as the constraints. The self-consistent hamiltonian is linear in these generators so that the solution of the self-consistency problem is replaced by a solution of an algebraic equation. The familiar Hartree-Fock procedure is a special case.     

A Comparison of the Molecular Dynamics of Fluorescent Probes in Curved Lipid Vesicles and Planar Multibilayers

The dynamic behaviour of the probe molecules DPH and TMA-DPH embedded in small unilamellar vesicles and planar multibilayers of POPC has been studied by time-resolved fluorescence depolarization techniques. The molecular dynamics of the probe molecules was analysed in terms of the rotational diffusion model. It is found that analysis of the time-dependent fluorescence anisotropy from the vesicle system yields two distinct, though statistically equivalent solutions. On the other hand the measurements on planar multibilayers can be interpreted unequivocally. It is shown that the order parameters of the probe molecules are higher in the multibilayers than in the vesicles. A reconstruction of the orientational distribution function reveals that the TMA-DPH molecules have a more pronounced tendency to lie with their long axes parallel to the bilayer surface in the curved vesicles than in the planar multibilayers. An intriguing finding is that the reorientational motion of the probes is considerably slower in the multibilayer samples than in the vesicles. These differences are attributed to the curvature and higher hydration of the bilayers in the vesicle systems.     

Relative MilnorK-theory

LetR be a commutative, semi-local ring,I ₁, ...,I _s ideals. In this paper, we define therelative Milnor K-groups of (R;I ₁, ...,I _s ),K _p ^M (R;I ₁, ...,I _s ), and show that these groups have many of the properties of the usual MilnorK-groups of a field. In particular, assuming a weak condition on the ideals, we show thatK _p ^M (R;I ₁, ...,I _s ) is isomorphic to the weightp portion of the relative QuillenK-groupK _p (R;I ₁, ...,I _s ), after inverting (p–1)!. We also define the relative group homology of GL _n (R;I ₁, ...,I _s ), and show thatK _p ^M (R;I ₁, ...,I _s ) is isomorphic toH _p (GL_p(R;I ₁, ...,I _s ))/Im(H _p (GL _p–1 (R;I ₁, ...,I _s ))). Finally, we consider a generalization to the relative setting of Kato's conjecture asserting that the Galois symbol gives an isomorphism fromK _p ^M (F)/l ^v to , and show that this relative version of Kato's conjecture implies the Quillen-Lichtenbaum conjectures asserting the Chern class:

Estimates and regularization for solutions of some ill-posed problems of elliptic and parabolic type

In this paper, we examine, in a systematic fashion, some ill-posed problems arising in the theory of heat conduction. In abstract terms, letH be a Hilbert space andA: D (A)?H→H be an unbounded normal operator, we consider the boundary value problemü(t)=Au(t), 0<t<∞,u(0)=u ₀∈D(A), \(\mathop {\lim }\limits_{t \to 0} \left\| {u\left( t \right)} \right\| = 0\) . The problem of recoveringu ₀ whenu(T) is known for someT>0 is not well-posed. Suppose we are given approximationsx ₁,x ₂,…,x _N tou(T ₁),…,u(T _N) with 0<T, <…<T _N and positive weightsP _i,i=1,…,n, \(\sum\limits_{i = 1}^N {P_i = 1} \) such that \(Q_2 \left( {u_0 } \right) = \sum\limits_{i = 1}^N {P_i } \left\| {u\left( {T_i } \right) - x_i } \right\|^2 \leqslant \varepsilon ^2 \) . If ‖u _t(0)‖≤E for some a priori constantE, we construct a regularized solution ν(t) such that \(Q\left( {\nu \left( 0 \right)} \right) \leqslant \varepsilon ^2 \) while \(\left\| {u\left( 0 \right) - \nu \left( 0 \right)} \right\| = 0\left( {ln \left( {E/\varepsilon } \right)} \right)^{ - 1} \) and \(\left\| {u\left( t \right) - \nu \left( t \right)} \right\| = 0\left( {\varepsilon ^{\beta \left( t \right)} } \right)\) where 0<β(t)<1 and the constant in the order symbol depends uponE. The function β(t) is larger thant/m whent _k andk is the largest integer such that \((\sum\limits_{k = 1}^N {P_i (T_i )} )< (\sum\limits_{k = 1}^N {P_i (T_i )} = m\) , which β(t)=t/m on [T _k, m] and β(t)=1 on [m, ∞). Similar results are obtained if the measurement is made in the maximum norm, i.e.,Q _∞(u ₀)=max{‖u(T _i)?x _i‖, 1≤i≤N}.