酞菁染料的金属化和溴化与光物理影响的研究

以α位 (2 ,4 二特戊基 )苯氧基邻苯二腈作为环合前体 ,制备了多种金属酞菁 ,产物经元素分析、紫外、红外、核磁氢谱等分析手段进行表征 .并选择了部分酞菁进行溴化 ,其中着重研究了不同中心金属以及溴化对染料Q带吸收的影响 .结果表明 ,酞菁染料的金属化对于其Q带吸收影响很大 ,多数染料金属化后会出现蓝移 ,而选择合适的条件进行溴化 ,可以使得金属酞菁的Q带吸收出现一定程度的红移 ,其中部分溴化金属酞菁的吸收波长与光信息产业中使用的近红外激光器很接近 ,具有潜在的实用价值     

α-和β-四烷氧取代酞菁的合成及性能研究

利用 3 烷氧取代邻苯二腈和 4 烷氧取代邻苯二腈与相应的金属盐反应制备了两大系列 (α 和 β )四烷氧取代酞菁 .讨论了温度对中间体烷氧取代邻苯二腈合成的影响 ,探讨了酞菁的两种环合方法 ,并对 β 烷氧酞菁的环合历程进行了初步的考察 .研究了不同取代位置和酞菁的最大吸收波长之间的关系 ,结果表明 ,α 取代烷氧取代酞菁导致λmax红移值较大 ,而相应 β位取代情况下红移值较小 ,说明给电子基团在α位对酞菁骨架的π共轭结构微扰作用比 β位大 .同时研究了溶解度及热失重与酞菁结构的关系     

Magnetorefractive effect in granular alloys with tunneling magnetoresistance

The magnetorefractive effect and optical reflectivity are studied in granular Co-Al-O, Co-Si-O, and Co-Ti-O metal-insulator alloys exhibiting tunneling magnetoresistance for compositions close to the percolation threshold. The dependences of these effects on frequency, angle of incidence, and light polarization were measured. The experimental data obtained suggest that the major MRE mechanism in these systems is spin-dependent tunneling at optical frequencies.     

低温储罐自增压特性的实验研究

LNG是一种易燃易爆的低温气体,通常采用无损储存。由于外界漏热,储罐内压力会不断上升,此升压速率对无损储存的安全有着重要的影响。文中建立了低温储罐自增压以及温度分层实验装置,对罐内的温度分层及此时的升压过程进行了实验研究。     

CO在Pu(100)表面吸附的研究

采用密度泛函理论(DFT)研究了CO分子在Pu (100)面上的吸附. 计算结果表明：CO在Pu (100)表面的C端吸附比O端吸附更为有利，属于强化学吸附. CO吸附态的稳定性为穴位倾斜>穴位垂直>桥位>顶位. CO分子与表面Pu原子的相互作用主要源于CO分子的杂化轨道和Pu原子的杂化轨道的贡献. 穴位倾斜吸附的CO分子的离解能垒较小(0.280eV)，表明在较低温度下，CO分子在Pu (100)表面会发生离解吸附，离解的C，O原子将占据能量最低的穴位.     

Dual-dressed four-wave mixing and dressed six-wave mixing in a five-level atomic system

We study the co-existing four-wave mixing (FWM) process with two dressing fields and the six-wave mixing (SWM) process with one dressing field in a five-level system with carefully arranged laser beams. We also show two kinds of doubly dressing mechanisms in the FWM process. FWM and SWM signals propagatingalong the same direction compete with each other. With the properly controlled dressing fields, the FWM signals can be suppressed, while the SWM signals have been enhanced.     

A novel magnetic fluid based on starch-coated magnetite nanoparticles functionalized with homing peptide

Preparation and characterization in vitro and in vivo of a novel magnetic fluid based on starch-coated magnetite nanoparticles functionalized with homing peptide is reported in this paper. Precursory magnetic fluids stabilized with starch were prepared, in a polymeric starch matrix, by controlled chemical coprecipitation of magnetite phase from aqueous solutions. The average hydrodynamic diameter of starch-coated iron oxide nanoparticles (SIONs) was 46 nm. As a homing peptide, A54 is the most effective peptide specific to the human hepatocellular carcinoma cell line BEL-7402. Final magnetic fluids were obtained through chemical coupling of homing peptide labeled with 5-carboxyl-fluorescein (FAM-A54) and SIONs. Magnetic measurements showed the saturation magnetization value of SIONs amounted to 45 emu/g and the FAM-A54-coupled SIONs showed a good magnetic response in magnetic field. The results of experiments in vitro and in vivo showed that SIONs were endowed with specific affinity to corresponding tumor cells after coupling with FAM-A54 and the FAM-A54-coupled SIONs could be accumulated in the tumor tissue with more efficiency than individual magnetic targeting or biomolecular targeting. This novel magnetic fluid with dual function has great potential applications in diagnostics and therapeutics of human tumor such as drug targeting, magnetic hyperthermia, and magnetic resonance imaging.     

聚变装置中真空室上涡流的分析

本文研究了聚变装置真空室上的涡流问题,将真空室上的涡流看作面电流密度并定义一矢势的法向分量来描述它。详细地叙述了求解真空室上感应涡流的计算方法,对HTU托卡马克实验装置真空室上涡流的大小、分布形式及衰减情况进行了分析。