全文获取类型
收费全文 | 595篇 |
免费 | 18篇 |
国内免费 | 6篇 |
专业分类
化学 | 401篇 |
晶体学 | 2篇 |
力学 | 27篇 |
数学 | 105篇 |
物理学 | 84篇 |
出版年
2018年 | 6篇 |
2017年 | 16篇 |
2016年 | 16篇 |
2015年 | 13篇 |
2014年 | 16篇 |
2013年 | 27篇 |
2012年 | 26篇 |
2011年 | 37篇 |
2010年 | 18篇 |
2009年 | 21篇 |
2008年 | 11篇 |
2007年 | 21篇 |
2006年 | 15篇 |
2005年 | 12篇 |
2004年 | 14篇 |
2003年 | 10篇 |
2002年 | 7篇 |
2001年 | 8篇 |
2000年 | 10篇 |
1999年 | 6篇 |
1998年 | 10篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1985年 | 8篇 |
1939年 | 6篇 |
1938年 | 10篇 |
1937年 | 10篇 |
1934年 | 10篇 |
1932年 | 9篇 |
1931年 | 7篇 |
1930年 | 6篇 |
1929年 | 9篇 |
1928年 | 7篇 |
1927年 | 9篇 |
1926年 | 11篇 |
1925年 | 5篇 |
1923年 | 7篇 |
1922年 | 6篇 |
1920年 | 5篇 |
1919年 | 6篇 |
1916年 | 8篇 |
1914年 | 5篇 |
1913年 | 7篇 |
1912年 | 7篇 |
1911年 | 6篇 |
1910年 | 5篇 |
1909年 | 8篇 |
1908年 | 9篇 |
排序方式: 共有619条查询结果,搜索用时 15 毫秒
21.
22.
23.
24.
Łukasz Woźniak Krystian Marszałek Sylwia Skąpska Renata Jędrzejczak 《Chromatographia》2017,80(10):1527-1533
Triterpenic acids are a group of secondary plant metabolites which are part of the cuticular waxes covering fruits, leaves, and flowers. To date, quantitative analysis of these compounds has often been conducted using high-performance liquid chromatography coupled with spectrophotometric detection or mass spectrometry; however, these methods have some major drawbacks. This paper reports a new method of analysis implementing derivatization with 9-anthryldiazomethane and fluorescence detection. The method consists of the extraction of analytes from a matrix, purification with anion exchanging SPE columns, and an optional step of the alkaline hydrolysis of triterpenic acid esters. The paper also describes a fast and easy method for the synthesis of the derivatization agent. The detection limits of the method presented are approximately 100-fold lower than in a similar method using ultraviolet spectrophotometry as the mode of detection. The recovery and repeatability of the method are at satisfactory levels. 相似文献
25.
Robert Łysek Ewa Woźny Marek Chmielewski 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):327-340
Chiral formates derived from propane-1,2-diol, 1,2- O -isopropylidene- f - D -xylo- and f - D -gluco-furanoses were subjected to treatment with cyclopentadienyl [tris(trimethylsilylmethyl)] titanium (IV). A mixture of the corresponding ( E )- and ( Z )- g -silylvinyl ethers were obtained with predominance of the former. It was found that in contrast to ( Z )-vinyl ethers, which give g -lactams with chlorosulfonyl isocyanate, the ( E )-vinyl ethers gave unstable cycloadducts which undergo rapid elimination reaction leading to ( E )- f , g -unsaturated amides. 相似文献
26.
Zal U’yun Wan Mahmood Mei Wo Yii 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(3):1727-1732
The purpose of this study was to estimate the sedimentation rate in the Sungai Linggi estuary using the constant initial concentration of unsupported or excess 210Pb model and verified with 137Cs method. Five sediment cores were collected on 25 January 2011 using gravity corer with the inner tube of 50 cm length and 7.5 cm diameter. The total 210Pb activities in the sediment cores profile at all sampling stations were varied and upper than those obtained for supported 210Pb i.e. 226Ra, indicated disequilibrium among 210Pb and its grandparents in the 238U decay series. Meanwhile, the lower 137Cs activities were observed at all sampling stations due to no significant sources of 137Cs releases were transferred into Malaysian marine. The estimation of sedimentation rate indicated the agreement of 210Pb and 137Cs method with a general presence of deep mixing in the Sungai Linggi estuary. Therefore, the apparent sedimentation rates calculated from 210Pb profiles generally reflect the true value with the range from 0.70 to 1.97 cmyr?1. High sedimentation rate was observed at some sampling stations which are located in river channel, estuary and closer to mainland. This suggested that land-use development, agriculture activities, channelization etc. introduced a large amount of sediment loaded into those areas. 相似文献
27.
亚波长直径微纳光纤强倏逝场传输的光学特性,使其对周围介质折射率的变化具有极高的灵敏度.本文提出一种基于微纳尺度光纤布拉格光栅(MNFBG)的折射率传感器,结合微纳光纤倏逝场传输和光纤布拉格光栅(FBG)强波长选择的特性来实现高精度折射率传感,对其制备可行性进行了讨论.论文中对MNFBG折射率传感机理进行了深入的理论分析,并使用OptiGrating软件进行了数值模拟,模拟数据显示MNFBG折射率测量的灵敏度随着光纤半径的减小而增加,其中光纤半径为400 nm的MNFBG灵敏度可达到993 nm/RIU,相比于包层蚀刻的FBG灵敏度增加了170倍,说明MNFBG对发展微型化、高灵敏度折射率传感器具有良好的应用前景.
关键词:
微纳光纤
光纤布拉格光栅
折射率传感 相似文献
28.
The lowest variational upper bounds to the lowest 2S state of ?7.478044 au and to the lowest 2P state of ?7.410097 au of the lithium atom are obtained. 相似文献
29.
Volume Contents
Contents of Volume 60 (2000) 相似文献30.
M. Wołoszyn D. Stauffer K. Kułakowski 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,57(3):331-335
We investigate the network model of community by Watts, Dodds and Newman (D.J. Watts et al., Science 296, 1302 (2002)) as a hierarchy of groups, each of 5 individuals. A homophily parameter
α controls the probability proportional to exp (-αx) of selection of neighbours
against distance x. The network nodes are endowed with spin-like variables si = ± 1,
with Ising interaction J > 0. The Glauber dynamics is used to investigate the
order-disorder transition. The transition temperature Tc is close to 3.8 for
α < 0.0 and it falls down to zero above this value. The result provides a mathematical
illustration of the social ability to a collective action via weak ties, as discussed
by Granovetter in 1973. 相似文献