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261.
Ammasai Karthikeyan Packianathan Thomas Muthiah Franc Perdih 《Acta Crystallographica. Section C, Structural Chemistry》2016,72(5):442-450
The coordination chemistry of mixed‐ligand complexes continues to be an active area of research since these compounds have a wide range of applications. Many coordination polymers and metal–organic framworks are emerging as novel functional materials. Aminopyrimidine and its derivatives are flexible ligands with versatile binding and coordination modes which have been proven to be useful in the construction of organic–inorganic hybrid materials and coordination polymers. Thiophenecarboxylic acid, its derivatives and their complexes exhibit pharmacological properties. Cobalt(II) and copper(II) complexes of thiophenecarboxylate have many biological applications, for example, as antifungal and antitumor agents. Two new cobalt(II) and copper(II) complexes incorporating thiophene‐2‐carboxylate (2‐TPC) and 2‐amino‐4,6‐dimethoxypyrimidine (OMP) ligands have been synthesized and characterized by X‐ray diffraction studies, namely (2‐amino‐4,6‐dimethoxypyrimidine‐κN)aquachlorido(thiophene‐2‐carboxylato‐κO)cobalt(II) monohydrate, [Co(C5H3O2S)Cl(C6H9N3O2)(H2O)]·H2O, (I), and catena‐poly[copper(II)‐tetrakis(μ‐thiophene‐2‐carboxylato‐κ2O:O′)‐copper(II)‐(μ‐2‐amino‐4,6‐dimethoxypyrimidine‐κ2N1:N3)], [Cu2(C5H3O2S)4(C6H9N3O2)]n, (II). In (I), the CoII ion has a distorted tetrahedral coordination environment involving one O atom from a monodentate 2‐TPC ligand, one N atom from an OMP ligand, one chloride ligand and one O atom of a water molecule. An additional water molecule is present in the asymmetric unit. The amino group of the coordinated OMP molecule and the coordinated carboxylate O atom of the 2‐TPC ligand form an interligand N—H…O hydrogen bond, generating an S(6) ring motif. The pyrimidine molecules also form a base pair [R22(8) motif] via a pair of N—H…N hydrogen bonds. These interactions, together with O—H…O and O—H…Cl hydrogen bonds and π–π stacking interactions, generate a three‐dimensional supramolecular architecture. The one‐dimensional coordination polymer (II) contains the classical paddle‐wheel [Cu2(CH3COO)4(H2O)2] unit, where each carboxylate group of four 2‐TPC ligands bridges two square‐pyramidally coordinated CuII ions and the apically coordinated OMP ligands bridge the dinuclear copper units. Each dinuclear copper unit has a crystallographic inversion centre, whereas the bridging OMP ligand has crystallographic twofold symmetry. The one‐dimensional polymeric chains self‐assemble via N—H…O, π–π and C—H…π interactions, generating a three‐dimensional supramolecular architecture. 相似文献
262.
M. K. V. Karthikeyan V. Vignesh 《International Journal of Polymer Analysis and Characterization》2016,21(4):296-304
The present work deals with the characterization of banana ribbon, a new natural fiber, and the effect of rope mat and random orientation on the mechanical and thermal properties of banana ribbon-reinforced polyester composites. Of all the fabricated composites, the banana ribbon rope mat composites showed improved mechanical and thermal properties compared to randomly oriented composites and other natural fiber composites. The surface morphologies of fractured mechanical testing samples were studied by scanning electron microscope to probe the fiber–matrix interaction. Furthermore, the mat composites are used to fabricate windshield of four wheelers and mudguard of two wheelers. 相似文献
263.
A. N. Balaji M. K. V. Karthikeyan V. Vignesh 《International Journal of Polymer Analysis and Characterization》2016,21(7):599-605
The present research work aimed to characterize new natural cellulosic kusha fibers extracted from the kusha grass plants. The physical and chemical properties of kusha fibers such as cellulose content (70.58%), lignin (14.35%), wax content (1.52%), ash content (2.46%), moisture content (8.01%), and density (1.1025 g cc?1) were identified. An X-ray diffraction of kusha fibers confirms the presence of cellulose with a crystalline index of 55.4%. Fourier transform infrared spectroscopy analysis was carried out to establish the certainty of using them as reinforcement fiber. Thermogravimetric analysis ensures thermal stability up to 357°C which is within the polymerization process temperature. 相似文献
264.
V. Vignesh M. K. V. Karthikeyan 《International Journal of Polymer Analysis and Characterization》2016,21(6):504-512
Natural fibers are one of the good alternative sources for replacing synthetic fiber and reinforcing polymer matrices because of their eco-friendly nature. This investigation deals with the extraction and characterization of new natural fiber from Indian mallow plant stem. The physico-chemical, thermal, and mechanical properties of Indian mallow fibers (IMFs) were reported and compared with other natural fibers for the first time. Cellulose (78.22%), wax (0.47%), density (1.33 g/cm³), and tensile strength (979.83 MPa) were recognized in IMFs. Fourier transform-infrared spectroscopy, X-ray diffraction, and thermo-gravimetric analysis confirmed that IMFs are rich in cellulose content and thermally stable with a crystallinity index of 72%. 相似文献
265.
A rapid and sensitive sorbent extraction hydride generation-flow injection analysis atomic absorption spectrometric (HG-FIAS-AAS) method is described for the determination of As(III) and As(V) based upon online preconcentration on a microcolumn packed with activated alumina. In the present procedure these arsenicals are complexed with quinolin-8-ol-5-sulphonic acid from neutral solutions in the flow injection system and adsorbed on the column. The preconcentrated species are eluted with 10% HCl, mixed with 0.5% sodium borohydride and carried to the HG-FIAS cell with a carrier gas flow rate of 75 ml min(-1). The retention efficiency is found to be better than 98% with sensitivity enhancement of 12 and 10 for As(III) and As(V), respectively, for a 20 s preconcentration period. The respective detection limits are 0.05 and 2 ng ml(-1) for As(III) and As(V). The throughput of the samples is found to be 60 h(-1), with a loading time of 20 s. The method has been applied to sea water samples. 相似文献
266.
Karthikeyan S Potisek SL Piermattei A Sijbesma RP 《Journal of the American Chemical Society》2008,130(45):14968-14969
The ultrasound-induced scission of silver carbene coordination complexes with polytetrahydrofuran-functionalized N-heterocyclic carbene ligands is reported. In solution, scission is very efficient, with complete conversion within 10 min when the polymers have a molecular weight of 6.7 kDa. The mechanochemical origin of the scission is supported by the molecular weight dependence of the scission rate and by the low reactivity of the silver complex with low molecular weight ligands. The mechanochemical process at room temperature is much faster than thermal scission at 60 degreesC, which has a conversion of 30% in 18 h. 相似文献
267.
The Silver Sulfide (Ag2S) nanostructures were synthesized via the facile co-precipitation method. Thorough study and analysis were carried out to reveal and compare the structural, optical, functional, and morphological characteristics of as-synthesized samples annealed at various temperatures. The XRD analysis characterized the structural properties of Ag2S nanoparticles, which unveiled the excellent crystallinity and monoclinic structure. The as-synthesized samples show an average crystallite size of 52 nm–41.7 nm. The modes of vibration and peak position of metal sulfides in Ag2S nanoparticles were investigated through the FTIR technique. The optical attributes of prepared samples were scrutinized using UV–Vis analysis, which portrays the cut-off wavelength in the range of 1192–1223 nm for non-annealed and annealed Ag2S nanoparticles, alongside the optical band gap is about 0.86 eV–0.96 eV. This work elucidates a novel approach to synthesis and scrutinises the characteristics of Ag2S nanoparticles by subjecting them to distinct annealing temperatures precisely, as-prepared, 200 °C and 400 °C. 相似文献
268.
Shanmugasundaram Veerabahu Bajorath Jürgen Christoffersen Ralph E. Petke James D. Howe W. Jeffrey Johnson Mark A. Agrafiotis Dimitris K. Lee Pil Kuhn Leslie A. Goodwin Jay T. Holloway M. Katharine Doman Thompson N. Walters W. Patrick Schreyer Suzanne Medina-Franco José L. Martinez-Mayorga Karina Restifo Linda L. 《Journal of computer-aided molecular design》2022,36(9):623-638
Journal of Computer-Aided Molecular Design - In May 2022, JCAMD published a Special Issue in honor of Gerald (Gerry) Maggiora, whose scientific leadership over many decades advanced the fields of... 相似文献
269.
We investigated various two-dimensional (2D) and three-dimensional (3D) structures of H (+)(H 2O) 8, using density functional theory (DFT), Moller-Plesset second-order perturbation theory (MP2), and coupled cluster theory with single, double, and perturbative triple excitations (CCSD(T)). The 3D structure is more stable than the 2D structure at all levels of theory on the Born-Oppenheimer surface. With the zero-point energy (ZPE) correction, the predicted structure varies depending on the level of theory. The DFT employing Becke's three parameters with Lee-Yang-Parr functionals (B3LYP) favors the 2D structure. At the complete basis set (CBS) limit, the MP2 calculation favors the 3D structure by 0.29 kcal/mol, and the CCSD(T) calculation favors the 3D structure by 0.27 kcal/mol. It is thus expected that both 2D and 3D structures are nearly isoenergetic near 0 K. At 100 K, all the calculations show that the 2D structure is much more stable in free binding energy than the 3D structure. The DFT and MP2 vibrational spectra of the 2D structure are consistent with the experimental spectra. First-principles Car-Parrinello molecular dynamics (CPMD) simulations show that the 2D Zundel-type vibrational spectra are in good agreement with the experiment. 相似文献
270.
Penumaka Nagababu Mynam Shilpa Sirasani Satyanarayana Jeevigunta Naveena Lavanya Latha Kilampalli Shivaramasastri Karthikeyan Medisetti Rajesh 《Transition Metal Chemistry》2008,33(8):1027-1033
Four asymmetric cobalt(III) complexes, [Co(bpy)2(aip)]3+, [Co(bpy)2(pyip)]3+, [Co(phen)2(aip)]3+, and [Co(phen)2(pyip)]3+ (bpy = 2,2,bipyridine, phen = 1,10-phenathroline), (pyip = 2-(1-pyrenyl)-1H-imidazo[4,5-f][phen], (aip = 2-(9-anthryl)-1H-imidazo[4,5,-f][phen],
have been synthesized and characterized. Their interaction with calf thymus DNA (CT-DNA) was investigated by physico-chemical
methods and photocleavage. The size and shape of the ligands have a marked effect on the DNA-binding affinity of the complexes.
Irradiation of pBR322 DNA with these novel cobalt(III) complexes results in nicking of the plasmid DNA. Toxicity and induced
cell death investigations revealed that the complexes of pyip had higher toxicity than those of aip.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献