全文获取类型
收费全文 | 6912篇 |
免费 | 983篇 |
国内免费 | 1027篇 |
专业分类
化学 | 5745篇 |
晶体学 | 117篇 |
力学 | 269篇 |
综合类 | 104篇 |
数学 | 667篇 |
物理学 | 2020篇 |
出版年
2024年 | 18篇 |
2023年 | 125篇 |
2022年 | 308篇 |
2021年 | 291篇 |
2020年 | 294篇 |
2019年 | 339篇 |
2018年 | 271篇 |
2017年 | 284篇 |
2016年 | 394篇 |
2015年 | 382篇 |
2014年 | 444篇 |
2013年 | 523篇 |
2012年 | 629篇 |
2011年 | 676篇 |
2010年 | 478篇 |
2009年 | 485篇 |
2008年 | 504篇 |
2007年 | 435篇 |
2006年 | 328篇 |
2005年 | 305篇 |
2004年 | 267篇 |
2003年 | 185篇 |
2002年 | 192篇 |
2001年 | 144篇 |
2000年 | 115篇 |
1999年 | 89篇 |
1998年 | 57篇 |
1997年 | 41篇 |
1996年 | 56篇 |
1995年 | 48篇 |
1994年 | 36篇 |
1993年 | 23篇 |
1992年 | 18篇 |
1991年 | 26篇 |
1990年 | 18篇 |
1989年 | 19篇 |
1988年 | 9篇 |
1987年 | 13篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1984年 | 2篇 |
1983年 | 8篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 6篇 |
1977年 | 2篇 |
1975年 | 3篇 |
1973年 | 2篇 |
1935年 | 1篇 |
排序方式: 共有8922条查询结果,搜索用时 15 毫秒
41.
Triterpenoid Constituents of Huperzia miyoshiana 总被引:1,自引:0,他引:1
Thirteen triterpenoids, including three new ones, miyoshianois A (1), B (2) and C (3), were isolated from Huperzia miyoshiana. The structures of these new compounds were established as 3-O-dihydroferuloyltohogenol (1), 16-oxo-3β,21β-dihydrox-y-serrat-14-en-24-ferulate (2) and 16-oxo-3a, 21β-dihydroxy-serrat-14-en-24-ferulate (3), respectively, on the basis of their spectroscopic analysis. 相似文献
42.
有机化合物电子光谱中的助色基及其作用机理探讨(Ⅰ) 总被引:1,自引:1,他引:0
本文就电子光谱中助色基的作用进行了讨论 ,认为不能一概地认为助色基能使与之相连的生色基最大吸收波长统统发生红移 ,而应具体问题具体分析 :对于n→π 来说 ,一方面助色基的p轨道和生色基的最低π 反键空轨道相互作用 ,使π 反键轨道能量上升 ,另一方面助色基的p轨道和生色基的n轨道正交 ,n轨道能量基本保持不变 ,因此n→π 跃迁能增加 ,吸收波长发生蓝移。对于π→π 跃迁来说 ,助色基的p轨道和生色基的最高π成键轨道相互作用生成的新的最高π成键轨道 ,能量虽然有所升高 ,但升高的程度与π 反键轨道升高的程度相比 ,在一些化合物中π轨道升高程度较大 ,因而π→π 跃迁能减小 ,吸收波长发生红移 ;在另一些化合物中π轨道升高程度较小 ,因而π→π 跃迁能增加 ,吸收波长发生蓝移。 相似文献
43.
LI Na ZHAO Degang & YANG Hui State Key Laboratory on Integrated Optoelectronics Institute of Semiconductors Chinese Academy of Sciences Beijing China 《中国科学G辑(英文版)》2004,47(6):694-701
Because of their large band-gap, large high-field electron velocity, large breakdownfield, and large thermal conductivity, GaN and its heterojunction with AlGaN and InGaNhave foreseeable potential in the applications of high-power/temperature electronics, andoptoelectronic devices operative in UV and visible wavelength. Polarization inducedelectric field can reach the magnitude of ~MV/cm[1,2]. For AlGaN/GaN based FETs theconcentration of sheet carrier induced by polarization in the cha… 相似文献
44.
KF-Al2O3催化合成2-甲基-1-苄基苯并咪唑 总被引:1,自引:0,他引:1
苯并咪唑类杂环化合物具有杀菌、消炎、抗癌、抗氧化的活性,广泛用于食品的防虫和防腐,用于动、植物病毒的防治,人体疾病和肿瘤的防治[1-3],本文用KF Al2O3作催化剂,用DMF为溶剂,利用2 甲基苯并咪唑与苄基溴反应合成2 甲基 1 苄基苯并咪唑的新型方法,考察了诸因素对产率的影响,找出了最佳的反应条件。合成路线如下:1 实验部分1 1 仪器与试剂Brurer AM 500超导核磁共振波谱仪(溶剂CDCl3);CarloErbal1106型元素分析仪,NicoletIm pact410型红外光谱仪,KBr压片,HP1100型和Finnigan FTMS 2000型质谱仪(以上均由华东理工大学分析… 相似文献
45.
QiaoHongYAO FuYouLI LuSHAN ChunHuiHUANG DongDongYIN 《中国化学快报》2003,14(11):1185-1188
A new photoresponsive D-π-A dye, mPS, has been designed and synthesized.Compared to the parent dye PS, IPCE values in the region from 400 nm to 560 nm was greatly improved upon changing the attaching group from the p- position to the o- position of the π-conjugation bridge. A solar cell based on mPS generated a remarkably high overall yield η of 5.4% under irradiation of 80.0 mW cm^-2 white light from a Xe lamp, Compared with PS, the overall yield η increased by 64%. 相似文献
46.
Na SUN 《数学学报(英文版)》2007,23(10):1909-1914
In this paper, we introduce an operator Hμ(z) on L^∞(△) and obtain some of its properties. Some applications of this operator to the extremal problem of quasiconformal mappings are given. In particular, a sufficient condition for a point r in the universal Teichmfiller space T(△) to be a Strebel point is obtained. 相似文献
47.
Zhao‐Peng Deng Shan Gao Li‐Hua Huo Hui Zhao 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(5):m225-m227
In the title complex, [Mn(SO4)(C3H7NO)(H2O)2]n, each MnII ion has a distorted octahedral geometry formed by three O atoms of three different sulfate groups, one O atom of a dimethylformamide ligand and two water molecules. The sulfate groups act as tridentate bridging ligands connecting the MnII ions into a two‐dimensional layer structure which can be regraded as a 4.82 network. 相似文献
48.
采用均相沉积法制备了不同Er3+离子浓度掺杂的Y2O3纳米晶, 应用XRD,SEM和PL光谱对该体系材料进行了表征.在Y2O3:Er3+纳米材料体系中, 观察和研究了Stokes及anti-Stokes PL谱强度与Er3+离子摩尔浓度变化的关系, 当Er3+离子浓度为2.0mol%时, anti-Stokes PL强度最强.粉末X
关键词:
氧化钇纳米晶
anti-Stokes PL
双光子吸收 相似文献
49.
Tumor cells transduced with herpes simplex virus thymidine kinase gene have been intensively applied to the field of positron emission tomography via imaging of its substrate. As a pilot synthesis approach, a facile preparation of 5‐[125I] iodoarabinosyl uridine starting from commercially available uridine is reported herein. 相似文献
50.
Amphiphilic biodegradable block copolymers [poly(sebacic anhydride)–poly(ethylene glycol)–poly(sebacic anhydride)] were synthesized by the melt polycondensation of poly(ethylene glycol) and sebacic anhydride prepolymers. The chemical structure, crystalline nature, and phase behavior of the resulting copolymers were characterized with 1H NMR, Fourier transform infrared, gel permeation chromatography, and differential scanning calorimetry. Microphase separation of the copolymers occurred, and the crystallinity of the poly(sebacic anhydride) (PSA) blocks diminished when the sebacic anhydride unit content in the copolymer was only 21.6%. 1H NMR spectra carried out in CDCl3 and D2O were used to demonstrate the existence of hydrophobic PSA domains as the core of the micelle. In aqueous media, the copolymers formed micelles after precipitation from water‐miscible solvents. The effects on the micelle sizes due to the micelle preparation conditions, such as the organic phase, dropping rate of the polymer organic solution into the aqueous phase, and copolymer concentrations in the organic phase, were studied. There was an increase in the micelle size as the molecular weight of the PSA block was increased. The diameters of the copolymer micelles were also found to increase as the concentration of the copolymer dissolved in the organic phase was increased, and the dependence of the micelle diameters on the concentration of the copolymer varied with the copolymer composition. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1271–1278, 2006 相似文献