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71.
    
A new approach to the chemo‐mechanical detection of trace amounts of nitroaromatics, even in the presence of high concentrations of background materials, is presented. The detection scheme is based on the plasticization of an aminopropyl silane layer that is harnessed to a silicon beam following its reaction with nitroaromatic systems. The reaction‐induced plasticization attenuates the temperature induced bending of the polymer‐beam sandwich, offering a simple and very sensitive tool for the detection of nitroaromatic systems. Using this approach, it was possible to detect a sample of 100 pg TNT even in the presence of a ~109 fold excess of a background material such as acetonitrile. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 2124–2130  相似文献   
72.
    
The asymmetric roughening of silicon microcantilevers using different vapor stain‐etching conditions is studied with the aim of optimizing face selective coating of microcantilevers by polymers through simple dipping. The effect of roughening is studied by following the time‐dependent guest‐induced bending of silicone microcantilevers coated with a poly‐4‐vinylpyridine sensing layer. A correlation between the surface roughness of the microcantilevers and their time‐dependent guest‐induced bending is gained from combining high resolution scanning electron microscopy studies of the surface of the microcantilevers as well as their cross‐sections with time‐dependent guest‐induced microcantilever bending. The purpose of the present work is to lay the foundations for a small and relatively simple gas‐phase sensing tool based on a microcantilever platform capable of offering wide range sensing capabilities. © 2013 Wiley Periodicals, 2014 , 52, 141–146  相似文献   
73.
    
It is shown that for m = 2d ? 1, 2d, 2d + 1, and d ≥ 1, the set {1, 2,…, 2m + 2}, ? {2,k} can be partitioned into differences d,d + 1,…,d + m ? 1 whenever (m,k) ≡ (0,0), (1,d + 1), (2, 1), (3,d) (mod (4,2)) and (d,m,k) ≠ (1,1,3), (2,3,7) (where (x,y) ≡ (u,ν) mod (m,n) iff xu (mod m) and yν (mod n)). It is also shown that if m ≥ 2d ? 1 and m ? [2d + 2, 8d ? 5], then the set {1, 2, …, 2m + 1} ? {k} can be partitioned into differences d,d + 1,…,d + m ? 1 whenever (m,k) ≡ (0, 1), (1,d), (2,0), (3,d + 1) mod (4,2). Finally, for d = 4 we obtain a complete result for when {1,…,2m + 1} ? {k} can be partitioned into differences 4,5,…,m + 3. © 2004 Wiley Periodicals, Inc.  相似文献   
74.
We show that the non-separable Banach space SL∞ is primary. This is achieved by directly solving the infinite-dimensional factorization problem in SL∞. In particular, we bypass Bourgain’s localization method.  相似文献   
75.
    
We present a new experimental approach, in which anion photodetachment spectroscopy is recorded with electrons of fixed kinetic energy. This approach circumvents some shortcomings of the zero electron kinetic energy method. Our method is based on a modified magnetic bottle photoelectron spectrometer (MBPES). A tunable laser is used to detach electrons from mass selected anions, drifting collinearly with the 40 cm MBPES drift tube. To avoid Doppler broadening, a low voltage pulse removes the velocity component of anions from the detached electrons. Spectra are recorded by collecting the wavelength dependence of electron-signal at a predetermined TOF window, corresponding to a specific electron-kinetic energy. We call this approach PEACE, denoting photoelectron action spectroscopy at constant kinetic energy. Our best resolution is 0.65 meV for 1.5 meV electrons. We present a PEACE spectrum of HgCl(-) together with the corresponding simulated theoretical spectrum. The method is similar in resolution and data collection rates to the slow electron velocity map imaging technique recently introduced by Neumark and co-workers.  相似文献   
76.
77.
Previous gas-phase dissociation experiments of protein-protein complexes have resulted in product ion distributions that are asymmetric by charge and mass, providing limited insight into the chemical nature of subunit organization and interaction. In these experiments, a symmetric charge distribution results from an "energy sudden" collision of protein-protein complexes with a surface, indicating that it may be possible to probe the suboligomeric structure of noncovalent complexes in the gas phase. It is proposed that energy sudden surface activation of cytochrome C homodimers results in dissociation without significant unfolding of one of the monomeric subunits. Previously proposed mechanisms for the dissociation of protein-protein complexes are discussed in the context of these results. These experiments demonstrate the potential to preserve the structural details of subunit interaction within a protein-protein complex and help elucidate the asymmetric nature of macromolecular dissociation in the gas phase.  相似文献   
78.
This work describes ratiometric photoacoustic chemical sensing of pH, and describes how these measurements can be applied as a ratiometric biomedical imaging modality to image pH in intact biological tissue.  相似文献   
79.
Rare earth doping is the key strategy to increase the Curie temperature (T(C)) of the ferromagnetic semiconductor EuO. The interplay between doping and charge carrier density (n), and the limit of the T(C) increase, however, are yet to be understood. We report measurements of n and T(C) of Gd-doped EuO over a wide range of doping levels. The results show a direct correlation between n and T(C), with both exhibiting a maximum at high doping. On average, less than 35% of the dopants act as donors, raising the question about the limit to increasing T(C).  相似文献   
80.
本文采用Sn自熔剂法,制备Mg掺杂Sn基单晶笼合物Ba8Ga16-XMgXSn30(0 X 1.5),并对其结构及电传输性能进行研究.结果表明所制备化合物为具有空间群Iˉ43m的VIII型单晶笼合物,随Mg掺杂量的增加,对应化合物的熔点略有升高,晶格常数减小,掺杂样品中填充原子Ba的实际含量低于理想值8.0,其在十二面体空洞中的占有率约为0.93(Mg的名义含量X=1.5时).所有样品均表现为n型传导,Mg的掺入对材料的能带结构有一定影响,Mg掺杂后,样品的载流子浓度降低,Seebeck系数的绝对值、电阻率增加,Mg的名义含量X=1.5时,样品的功率因子在430 K附近取得最大值1.26×10-3W·m-1·K-2.  相似文献   
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