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71.
Measurement of filament length generated by an intense femtosecond laser pulse using electromagnetic radiation detection 总被引:4,自引:0,他引:4
We present a new method to measure the length of a filament induced by the propagation of intense femtosecond laser pulses
in air. We used an antenna to detect electromagnetic pulses radiated from multipole moments inside the filament oscillating
at the plasma frequency. The results are compared with the values detected from the backscattered fluorescence induced by
multiphoton ionization of nitrogen molecules excited inside the filament. The values are found to be in good agreement.
Received: 6 November 2002 / Revised version: 27 January 2003 / Published online: 24 April 2003
RID="*"
ID="*"Corresponding author. Fax: +1-418/656-2623, E-mail: shosseini@phy.ulaval.ca 相似文献
72.
Upon crystallisation of two bismonodentate tectons based on two pyridine units, interconnected at the meta position by a tetra- or hexa-ethylene glycol fragment and Ag+ cation, double stranded helical infinite coordination networks were formed and structurally characterised. The cationic double helical architectures obtained may be regarded as analogues of DNA in terms of topology. 相似文献
73.
74.
M. Ghoranneviss A. Shokouhy M. M. Larijani S. H. Haji Hosseini M. Yari A. Anvari M. Gholipur Shahraki A. H. Sari M. R. Hantehzadeh 《Pramana》2007,68(1):135-140
This work presents the results of a low-energy nitrogen ion implantation of AISI 304 type stainless steel (SS) at a moderate
temperature of about 500°C. The nitrogen ions are extracted from a Kauffman-type ion source at an energy of 30 keV, and ion
current density of 100 μA cm−2. Nitrogen ion concentration of 6 × 1017, 8 × 1017 and 1018 ions cm−2, were selected for our study. The X-ray diffraction results show the formation of CrN polycrystalline phase after nitrogen
bombardment and a change of crystallinity due to the change in nitrogen ion concentration. The secondary ion mass spectrometry
(SIMS) results show the formation of CrN phases too. Corrosion test has shown that corrosion resistance is enhanced by increasing
nitrogen ion concentration.
相似文献
75.
Shahla Masoudian Hassan Hosseini Monfared Alireza Aghaei 《Transition Metal Chemistry》2011,36(5):521-530
Various aerogels of silica gel doped with Fe2O3 were prepared by sol–gel method. They were calcined to produce nanoparticle solids. The nanosized mixed oxides were active
in the oxidation of alcohols and produced carbonyl compounds in very good to excellent yields using hydrogen peroxide. 相似文献
76.
A highly efficient synthesis of 2‐arylamino‐2‐imidazolines and 2‐aminobenzimidazoles from aminoimino‐methanesulfonic acid derivatives is described. The method is simple and practical, generating imidazoline and benzimidazoline derivatives in excellent isolated yields. 相似文献
77.
S. Hosseini M. HomaieeA.B. Mohamad M.R. MalekbalaA.A.H. Khadum 《Physica B: Condensed Matter》2011,406(9):1689-1694
Cesium dihydrogen phosphate (CDP) nanoparticles were synthesized using the surfactants cetyltrimethyl ammonium bromide (CTAB), polyoxyethylene-polyoxypropylene (F-68) and (F-68:CTAB) with molar ratio 0.06. The samples conductivity such as CDPCTAB, CDPF-68 and CDP(F-68:CTAB)0.06 was studied by impedance spectroscopy in the frequency range 0.01 Hz to 1 MHz. The Nyquist plots were drawn at different temperatures of 210, 230 and 260 °C, which are defined below transition, phase transition and above transition, respectively. The measured conductivities obey the Arrhenius relation. The influence of surfactants on conductivity are more significant at higher temperature due to grain boundary. The conductivity of CDPCTAB increased slightly with increasing temperature to 260 °C, whereas the conductivity of other samples decreased with increasing temperature over 230 °C. The results indicated that the conductivities increase in the order of CDPCTAB>CDP(F-68:CTAB)0.06>CDPF-68. These are in accordance to the ion exchange capacities of the samples that the surfactant shows a direct influence on the samples proton mobility. It is found that the conductivity of CsH2PO4 is influenced by surfactant type. 相似文献
78.
Hassan Hosseini Monfared Azar Mohajeri Ali Morsali Christoph Janiak 《Monatshefte für Chemie / Chemical Monthly》2009,17(1):1437-1445
Abstract
The Mn(II) dicarboxylate coordination polymers [Mn(μ-terephthalate)(H2O)2] n , [Mn(μ-oxalate)(H2O)2] n , and [Mn(μ-d-(−)-tartrate)] n were prepared in water and characterized by FT-IR spectroscopy and CHN analysis. Particles of the terephthalate catalyst were also synthesized, by reaction of terephthalic acid and MnCl2·4H2O by a sonochemical method. The catalytic potential of these coordination polymers as slow-release sources of catalytically active Mn species was tested in the oxidation of cyclooctene to its epoxide in acetonitrile, using hydrogen peroxide as oxygen source. For the terephthalate species the catalytic activity was found to increase with increasing dielectric constant and dipole moment of the solvent (being highest in acetonitrile), with reaction temperature to a maximum at 60 °C, and with an imidazole co-catalyst (highest activity found for a imidazole-to-catalyst molar ratio of 20:1). Good activity with more than 64% conversion in 24 h was obtained for epoxidation of cyclooctene and cyclohexene, whereas low yields only were obtained from aryl-substituted olefins. Some exo versus endo regioselectivity was found for norbornene. 相似文献79.
Forming partnerships in a virtual factory 总被引:1,自引:0,他引:1
80.
Quantum chemical methods are becoming ever more prevalent for assessing surface interactions of different molecules using cluster models and semi-empirical, ab initio Hartree–Fock and density functional theory (DFT) studies considering the standard potential energy surfaces. Examination of the efficacy of some pyridine derivatives to counter aluminium corrosion in hydrochloric acid using ab initio and semi-empirical quantum chemical deductions and its comparison with the available experimental data forms the basis of this research. It is believed that the inhibition efficiency has lucid correlation with the total energy of inhibitor molecules and highest occupied molecular orbital energy levels calculated by DFT study methods and thus the adsorption energy for the pyridine on Al1, Al5, Al14, Al18 and Al26 clusters are determined to assess the convergence of the results with respect to size of the cluster. Subsequently, Al26 is used for the inhibitor/aluminium cluster interface investigations. Results highlight the reaction between pyridine molecules and appropriately active sites such as corners and steps or kinks and screw dislocations towards which pyridine molecules are attracted as is evident from a three times rise in adsorption energy from (−35) to (−107) kJ mol−1. Therefore, inhibition mechanism is primarily associated with local properties. Interactions take place between the surface defect and the nitrogen group of the pyridine molecule however, the possibility of ion pair formation between protonated pyridine and chloride ion and its influence on the general adsorption of pyridine on aluminium is also examined. The interaction energies of pyridine and aluminium cluster with the natural bond orbital are also reported. 相似文献