全文获取类型
收费全文 | 1490篇 |
免费 | 71篇 |
国内免费 | 32篇 |
专业分类
化学 | 1120篇 |
晶体学 | 3篇 |
力学 | 90篇 |
数学 | 168篇 |
物理学 | 212篇 |
出版年
2024年 | 3篇 |
2023年 | 7篇 |
2022年 | 34篇 |
2021年 | 48篇 |
2020年 | 94篇 |
2019年 | 79篇 |
2018年 | 107篇 |
2017年 | 71篇 |
2016年 | 137篇 |
2015年 | 97篇 |
2014年 | 115篇 |
2013年 | 203篇 |
2012年 | 125篇 |
2011年 | 127篇 |
2010年 | 82篇 |
2009年 | 64篇 |
2008年 | 57篇 |
2007年 | 36篇 |
2006年 | 21篇 |
2005年 | 18篇 |
2004年 | 12篇 |
2003年 | 21篇 |
2002年 | 11篇 |
2001年 | 5篇 |
2000年 | 4篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1976年 | 2篇 |
排序方式: 共有1593条查询结果,搜索用时 0 毫秒
61.
Dr. Tana Koudelakova Dr. Radka Chaloupkova Dr. Jan Brezovsky Dr. Zbynek Prokop Dr. Eva Sebestova Dr. Martin Hesseler Dr. Morteza Khabiri Maryia Plevaka Daryna Kulik Dr. Ivana Kuta Smatanova Dr. Pavlina Rezacova Dr. Rudiger Ettrich Prof. Uwe T. Bornscheuer Prof. Jiri Damborsky 《Angewandte Chemie (International ed. in English)》2013,52(7):1959-1963
62.
Abbas Ghasempour Ardakani Mehdi Hosseini Ali Reza Bahrampour Seyed Mohammad Mahdavi 《Optics Communications》2012,285(7):1900-1904
We propose that spectral intensity of superconductor based random lasers can be made tunable by changing temperature. The two fluid model and wavelength dependent dispersion formula have been employed to describe the optical response of the superconducting materials. Random laser characteristics have been calculated using the one dimensional FDTD method. Our simulation results reveal that the emission spectrum can be manipulated through the ambient temperature of the system. It is observed that transition from metal phase to pure superconducting phase leads to the enhancement of the laser emission. Furthermore, spatial distribution of the fields in one dimensional disordered media is very sensitive to the system temperature. 相似文献
63.
A template-free seeded short-time in situ hydrothermal treatment was carried out in a brass autoclave to synthesize crystalline mordenite (MOR) membranes on alumina-silicate disk supports with micro-scale pores. According to XRD analysis, MOR was the only zeolitic material present in the membrane layers on the supports. SEM examination of the membranes showed three different layers of the membrane thickness: (i) support sub-layer, (ii) mix penetrated mid-layer, the MOR crystals filling the pores among the support (about 4–5 μm), and (iii) MOR top-layer (about 4–5 μm). The crystalline bonds between MOR crystals of the membrane top-layer and the crystals of the support were clearly observed within the mid-layer. The continuous top-layer of zeolitic membrane was formed by many large and well-shaped crystals. The seeding treatment significantly enhanced the formation of MOR crystals onto the surface of the supports. EDAX analysis showed a Si/Al ratio of 6.8 for the MOR layer of the membrane. Due to their hydrophilic natures, the polycrystalline MOR membranes were found to be selective for continuous dehydration of different EtOH–water mixtures through an adsorption–diffusion–desorption mechanism. Both total permeation flux and separation factor of the membrane were found to increase by increasing temperature and water concentration of feed. The continuity and high crystallinity of the membrane top-layer led to the fairly high dehydration of EtOH. It was found that there was no pinhole within the layer and the morphology of the membrane was almost defect-free. 相似文献
64.
Let G be a 2k-edge-connected graph with and let for every . A spanning subgraph F of G is called an L-factor, if for every . In this article, we show that if for every , then G has a k-edge-connected L-factor. We also show that if and for every , then G has a k-edge-connected L-factor. 相似文献
65.
66.
In this paper, we investigate the complete moment convergence for dependent linear processes with random coefficients to form 相似文献
67.
Sahra Balilehvand Seyed Majid Hashemianzadeh SeyedehSaleheh Razavi Hedayat Karimi 《Adsorption》2012,18(1):13-22
A combination of ab initio quantum mechanical (QM) calculations and canonical Monte Carlo (CMC) simulations are employed to
investigate possible usage of single-walled silicon nanotubes (SWSiNTs) as a novel media for hydrogen and methane adsorption
as well as their separation from each other. By fitting the force field, a Morse potential model is selected as an efficient
potential to describe the binding energies between both hydrogen-SiNTs and methane-SiNTs obtained from ab initio calculations.
Then CMC simulations are performed to evaluate the adsorption and separation behaviors of H2 and CH4 on the three different sizes of SiNTs including (5, 5), (7, 7), and (9, 9) SiNTs at ambient temperatures and pressures from
1 up to 10 MPa. As a comparison, the adsorption and separation of H2 and CH4 on the (8, 8) CNTs which are isodiameter with (5, 5) SiNTs are also simulated. Results are indicative of remarkable enhancement
of H2 and CH4 adsorption capacity on the SiNTs compared to the CNTs, which arise from stronger van der Waals (VDW) attractions. In the
case of methane adsorption on SiNTs, the stored volumetric energy exceeds the goal of the US Freedom CAR Partnership by 2010,
which can not be achieved by methane compression at such low pressures. Moreover, simulation results indicate that SiNTs preferentially
adsorb methane relative to hydrogen in their equimolar mixture, which results in efficient separation of these gases from
each other at 293 K. 相似文献
68.
69.
70.
Seyed Abolghasem Kahani Mohammad Sabeti Mohammad Taghi Yosefi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):1584-1590
Abstract The oxidation of thiocyanate to polythiocyanic acid by peroxydisulfate was carried out in an aqueous solution at room temperature. The primary step is the decomposition of peroxydisulfate into sulfate-free radicals. At room temperature in the presence of peroxydisulfate as a oxidizing agent, HSCN polymerizes to (HSCN)n. The oxidation of thiocyanate in an aqueous solution is often complicated, but here we obtained the polythiocyanic acid as a major product. The products were characterized by elemental analysis, IR, UV- visible, H-NMR spectroscopy, and X-ray powder diffraction. 相似文献