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81.
The effects of peripheral substituents and axial ligands on the electronic structure and properties of iron phthalocyanine, H(16)PcFe, have been investigated using a DFT method. Substitution by electron-withdrawing fluorinated groups alters the ground state of H(16)PcFe and gives rise to large changes in the ionization potentials and electron affinity. For the six-coordinate adducts with acetone, H(2)O, and pyridine, the axial coordination of two weak-field ligands leads to an intermediate-spin ground state, while the strong-field ligands make the system diamagnetic. The electronic configuration of a ligated iron phthalocyanine is determined mainly by the axial ligand-field strength but can also be affected by peripheral substituents. Axial ligands also exert an effect on ionization potentials and electron affinity and can, as observed experimentally, even change the site of oxidation/reduction. 相似文献
82.
Costes JP Novitchi G Shova S Dahan F Donnadieu B Tuchagues JP 《Inorganic chemistry》2004,43(24):7792-7799
The monometallic precursors L1Cu and L2Cu (L1H2 standing for 1,3-bis((3-ethoxysalicylidene)amino) propane and L2H2 standing for 1,2-bis((3-methoxysalicylidene)amino) ethane) react with sodium dicyanamide (dca) (NaN3C2), a mixture of gadolinium nitrate, and sodium dicyanamide to yield heterodinuclear L2CuNa(NCNCN) and L1CuGd(NO3)(NCNCN)2 entities. The structural determination shows that two Cu-Na entities are linked by dca with an original mu1,1 coordination mode, evidenced here for the first time, to yield tetranuclear complexes. Two hydrogen bonds operate between the water molecule coordinated to one of the sodium ions and the free nitrogen atoms of two dca ligands, yielding infinite zigzag chains. The structural determination of the Cu-Gd entities indicates that they are held together by two dca ligands, bridging alternately Cu to Gd and Gd to Gd cations, in the more common mu1,5 mode to yield a one-dimensional (1D) network. The dca ligands are not able to transmit interaction between the magnetically active centers in these chains, which are the unique example of structurally characterized Cu-Gd complexes involving dca ligands. 相似文献
83.
Sergiu Aizicovici Eduard Feireisl Franoise Issard‐Roch 《Mathematical Methods in the Applied Sciences》2001,24(5):277-287
We prove that any global bounded solution of a phase field model tends to a single equilibrium state for large times though the set of equilibria may contain a nontrivial continuum of stationary states. The problem has a partial variational structure, specifically, only the elliptic part of the first equation represents an Euler–Lagrange equation while the second does not. This requires some modifications in comparison with standard methods used to attack this kind of problems. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
84.
Miron Teodor Căproiu Florea Dumitrascu Sergiu Shova Ileana Cornelia Chirită Alexandru Vasile Missir Dana-Mihaela Cioroianu 《Tetrahedron letters》2014
New S-thiocarbamates possessing a 10,11-dihydro-5H-dibenzo[a,d]cycloheptene moiety were obtained unexpectedly in the process of preparing new O-thiocarbamates starting from 5-dibenzosuberol (10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol) and aroyl-isothiocyanates. These compounds were obtained via a benzylic Newman–Kwart rearrangement mechanism. The structures of the new thiocarbamates were confirmed by elemental analysis, IR, and NMR spectroscopy and by X-ray crystallography. 相似文献
85.
Steffen Berger Sergiu P. Albu Felix Schmidt-Stein Helga Hildebrand Patrik Schmuki John S. Hammond Dennis F. Paul Stefan Reichlmaier 《Surface science》2011,605(19-20):L57-L60
High resolution Scanning Auger Electron Spectroscopy (AES) is used to demonstrate the compositional variation across self-organized TiO2 nanotube layers grown in fluoride containing ethylene glycol electrolytes. The analysis results show a distinct fluoride rich layer in between the TiO2 nanotubes and particularly in the triple points of the hexagonally ordered nanotubular arrays. AES analysis further revealed that extended e-beam exposure leads to a decrease in the fluoride signal (electron beam induced decomposition of fluoride species). The proof of the existence of a fluoride rich layer located between the tube walls strongly supports fluoride dissolution as the reason for a transition from a porous to a tubular morphology. 相似文献
86.
Sergiu Sima Julia Cruz-Doblas Martin Cismondi Catinca Secuianu 《Central European Journal of Chemistry》2014,12(9):918-927
The phase behavior of the carbon dioxide + cycloalkane mixtures usually receives low attention, though these systems are important for many industries, e.g. the carbon capture and storage. In this paper calculations results for the carbon dioxide + cyclopentane binary system are presented, based on SRK and PR cubic equations of state with classical van der Waals mixing rules. A single set of binary parameters for each model was proposed to predict the global phase behavior of the system in a wide range of pressure and temperature. Albeit the thermodynamic models used are simple, they are able to represent fairly well the phase behavior of the system analyzed in this paper. 相似文献
87.
Sergiu Shova Vasile Tiron Angelica Vlad Ghenadie Novitchi Dan G. Dumitrescu Madalin Damoc Mirela-Fernanda Zaltariov Maria Cazacu 《应用有机金属化学》2020,34(12):e5957
A di-manganese(III) complex structure was built by an original approach consisting of a two-step procedure. First, the mononuclear complex of the manganese(III) with the Schiff base of the salen-type ligand (H2L) derived from 1,3-bis(3-aminopropyl)tetramethyldisiloxane and 3,5-di-tert-butyl-2-hydroxybenzaldehyde was prepared. The main feature of note is the 12-membered chelate ring formed upon coordination of the Schiff base to central atom, which adopts a distorted N2O4 octahedron environment. In the second step, the acetato co-ligand in this complex is replaced by the carboxylate anion of a dicarboxilic acid, namely adipic acid. This metathesis reaction leads to the formation of dinuclear structure by connecting two manganese centers. The structure, as was determined by X-ray single crystal diffractometry, elemental and spectral analysis, is permethylated dinuclear complex with long aliphatic bridge. Thermal and magnetic properties were studied. In addition, the formation of magnetically induced stripe-ordered domains was highlighted by the magnetic force microscopy (MFM) on films born from diluted solution. 相似文献
88.
Ghenadie Novitchi Victor Ciornea Jean-Pierre Costes Aurelian Gulea Olga N. Kazheva Sergiu Shova Vladimir B. Arion 《Polyhedron》2010
A 1D heterometallic Cr2/Ag2 polymer formulated as {[Ag(μ-H2O)Ag(nta)Cr(μ-OH)(μ-AcO,O′)Cr(nta)]·H2O}n (1) (H3nta = nitrilotriacetic acid) has been prepared and structurally characterized. {Cr(μ-OH)(μ-OAc)Cr} dimeric units containing two different bridging ligands, hydroxo and acetate groups are coordinated to six Ag atoms forming the 1D network. The temperature dependence of magnetic susceptibility for 1 which was fitted with an isotropic Hamiltonian including biquadratic exchange parameters, yielded antiferromagnetic interaction parameters (J = −8.5(1), j = −0.50(7) cm−1 g = 2.0). 相似文献
89.
Alexandru-Constantin Stoica Madalin Damoc Corneliu Cojocaru Alina Nicolescu Sergiu Shova Mihaela Dascalu Maria Cazacu 《Molecules (Basel, Switzerland)》2022,27(23)
The specific features of the siloxane bond unify the compounds based on it into a class with its own chemistry and unique combinations of chemical and physical properties. An illustration of their chemical peculiarity is the behavior of 1,3-bis(2-aminoethylaminomethyl)tetramethyldisiloxane (AEAMDS) in the reaction with carbonyl compounds and metal salts, by which we obtain the metal complexes of the corresponding Schiff bases formed in situ. Depending on the reaction conditions, the fragmentation of this compound takes place at the siloxane bond, but, in most cases, it is in the organic moieties in the β position with respect to the silicon atom. The main compounds that were formed based on the moieties resulting from the splitting of this diamine were isolated and characterized from a structural point of view. Depending on the presence or not of the metal salt in the reaction mixture, these are metal complexes with organic ligands (either dangling or not dangling silanol tails), or organic compounds. Through theoretical calculations, electrons that appear in the structure of the siloxane bond in different contexts and that lead to such fragmentations have been assessed. 相似文献
90.
The copper(II)-gadolinium(III) and copper(II)-terbium(III) complexes studied in this report derive from disymmetric trianionic ligands abbreviated H3Li (i = 4-6). These ligands are obtained through reaction of different aldehydes with "half-units" having an amide function, the latter resulting from the monocondensation of different diamines with phenyl 2-hydroxy-3-methoxybenzoate. Upon deprotonation, the Li ligands (i = 4-10) possess an inner N2O2 coordination site with one amido, one imine, and two phenoxo functions, an outer O2O2 or O2O coordination site, and an amido oxygen atom positioned out of these two sites. The trianionic character of such ligands yields original anionic complexes in the presence of copper(II) or nickel(II) ions, with a 1/1 L/M stoichiometry. The crystal and molecular structures of four complexes, two 3d (1, 5) and two 3d-4f (12, 13) complexes, have been determined. Complex 1 crystallizes in the monoclinic space group C2/c: a = 27.528(2) A, b = 7.0944(7) A, c = 22.914(2) A, beta = 92.130(6) degrees , V = 4471.9(7) A(3), Z = 8 for C(21.5)H(27)CuKN(2)O(6.5). Complex 5 crystallizes in the monoclinic space group P2(1)/n (No. 14): a = 11.0760(9) A, b = 21.454(2) A, c = 15.336(1) A, beta = 101.474(1) degrees , V = 3571.5(5) A(3), Z = 4. Complex 12 crystallizes in the triclinic space group P (No. 2): a = 8.682(2) A, b = 11.848(2) A, c = 11.928(2) A, alpha = 81.77(3) degrees , beta = 89.17(3) degrees , gamma = 85.49(3) degrees , V = 1210.6(4) A(3), Z = 2 for C20H22CuN5O11Tb. Complex 13 belongs to the monoclinic space group C2/c: a = 25.475(5)A, b = 12.934(3)A, c = 15.023(3) A, beta = 91.06(3) degrees , V = 4949.02A3, Z = 8 for C21H25CuN4O12Tb. The structural determinations confirm that the dinuclear entities involved in 12 and 13 are disposed in a head-to-tail arrangement to give tetranuclear complexes in which the copper and lanthanide ions are positioned at the vertexes of a rectangle. In the [Cu-Gd]2 species, there are two different ferromagnetic Cu-Gd interactions. The stronger one is supported by the double phenoxo bridge (CuO2Gd) while the weaker one corresponds to the single amido bridge (Cu-N-C-O-Gd). Replacement of gadolinium ions with anisotropic terbium ions yields tetranuclear entities showing slow relaxation of magnetization and magnetization hysteresis. Detailed relaxation and hysteresis loop studies establish single-molecule magnet (SMM) behavior which is influenced by weak intermolecular interactions. 相似文献