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171.
Mirela‐Fernanda Zaltariov Maria Cazacu Sergiu Shova Angelica Vlad Iuliana Stoica Elena Hamciuc 《Journal of polymer science. Part A, Polymer chemistry》2012,50(18):3775-3787
Bis[N‐(4‐carboxyphenyl)phtalimidyl]dimethylsilane prepared by the reaction between bis(3,4‐dicarboxyphenyl)dimethylsilane anhydride and p‐aminobenzoic acid has been used to built three novel hydrogen‐bonded supramolecular polymers as a result of cocrystallization with pyridine derivatives: 4,4′‐bipyridyl ( SP1 ), 1,2‐bis(4‐pyridyl)ethylene ( SP2 ), and 4,4′‐azopyridine ( SP3 ). The structures of the dianhydride, diacid, and derived supramolecular polymers were investigated by Fourier transform infrared (FTIR) and proton magnetic resonance (1H NMR) spectroscopy. Self‐assembling was proved by the presence of the IR absorption bands around 1900 and 2400 cm?1 specific for hydrogen bond. The association constant values were estimated by using FTIR spectroscopy in solid state. According to X‐ray diffraction study, the bis(3,4‐dicarboxyphenyl)dimethylsilane anhydride ( 1 ) has an isolated molecular structure. Bis[N‐(4‐carboxyphenyl)phtalimidyl]dimethylsilane ( 2 ) molecules are associated in the crystal structure via dimeric O? H … O hydrogen bonds resulting in the wavy 1D supramolecular chain. The main packing motif for SP1 and SP3 is represented by wavy chain formed by alternating sequences of 4,4′‐bipyridyl or 4,4′‐azopyridine and bis[N(4‐carboxyphenyl)phtalimidyl]dimethylsilane molecules linked by O? H … N hydrogen bonds. Thermal behavior was studied by differential scanning calorimetry and thermogravimetric analysis. The ability for the structuration in film was emphasized by atomic force microscopy. The molecular transport ability of the reversible associations was estimated by dynamic water vapor sorption (DVS) analysis. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
172.
Does the Sign of the Cu–Gd Magnetic Interaction Depend on the Number of Atoms in the Bridge?
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Dr. Jean‐Pierre Costes Dr. Carine Duhayon Dr. Sonia Mallet‐Ladeira Prof. Sergiu Shova Dr. Laure Vendier 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(6):2171-2180
Several theoretical investigations with CASSCF methods confirm that the magnetic behavior of Cu–Gd complexes can only be reproduced if the 5d Gd orbitals are included in the active space. These orbitals, expected to be unoccupied, do present a low spin density, which is mainly due to a spin polarization effect. This theory is strengthened by the experimental results reported herein. We demonstrate that Cu–Gd complexes characterized by Cu–Gd interactions through single‐oxygen and three‐atom bridges consisting of oxygen, carbon, and nitrogen atoms, present weak ferromagnetic exchange interactions, whereas complexes with bridges made of two atoms, such as the nitrogen–oxygen oximato bridge, are subject to weak antiferromagnetic exchange interactions. Therefore, a bridge with an odd number of atoms induces a weak ferromagnetic exchange interaction, whereas a bridge with an even number of atoms supports a weak antiferromagnetic exchange interaction, as observed in pure organic compounds and also, as in this case, in metal–organic compounds with an active spin polarization effect. 相似文献
173.
174.
The main goal of this work is to perform a nonholonomic deformation (Fedosov type) quantization of fractional Lagrange–Finsler
geometries. The constructions are provided for a fractional almost K?hler model encoding equivalently all data for fractional
Euler–Lagrange equations with Caputo fractional derivative. 相似文献
175.
We present a new, fully anisotropic, criterion for formation of trapped surfaces in vacuum. More precisely we provide local conditions on null data, concentrated in a neighborhood of a short null geodesic segment (possibly flat in all other directions) whose future development contains a trapped surface. This extends considerably the previous result of Christodoulou (Monographs in Mathematics. European Mathematical Society, Switzerland, 2009) which required instead a uniform condition along all null geodesic generators. To obtain our result we combine Christodoulou’s mechanism for the formation of a trapped surface with a new deformation process which takes place along incoming null hypersurfaces. 相似文献
176.
177.
Note on the topological degree of the subdifferential of a lower semi-continuous convex function 总被引:3,自引:0,他引:3
Sergiu Aizicovici Yuqing Chen 《Proceedings of the American Mathematical Society》1998,126(10):2905-2908
The purpose of the present paper is to prove that the topological degree of the subdifferential of a coercive lower semi-continuous function on a sufficiently large ball in a reflexive Banach space is equal to one.
178.
EPR study of the low temperature ferroelectric phase transition in Cu doped Rb2ZnCl4 single crystals
Mariana Stefan Sergiu V. Nistor Dirk SchoemakerIoan Ursu 《Solid State Communications》2003,127(11):695-698
Temperature dependent EPR measurements on copper doped Rb2ZnCl4 single crystals allowed us to evidence and study the P21cn↔C1c1 structural phase transition that takes place in this compound at 74.6 K. From the two types of Cu2+ centers localized at different anionic sites, called Cu2+(I) and Cu2+(II), which are formed in this compound, only the Cu2+(II) centers exhibit observable changes in their EPR spectra, attributable to the symmetry lowering. The observed changes have been related to the soft-mode responsible for the structural phase transition. 相似文献
179.
We show that the Dirac operator on a spin manifold does not admit L2 eigenspinors provided the metric has a certain asymptotic behaviour and is a warped product near infinity. These conditions on the metric are fulfilled in particular if the manifold is complete and carries a non-complete vector field which outside a compact set is gradient conformal and non-vanishing. 相似文献
180.
Mioara Drobota Zdenka Persin Lidija Fras Zemljic Tamiselvan Mohan Karin Stana-Kleinschek Ales Doliska Matej Bracic Volker Ribitsch Valeria Harabagiu Sergiu Coseri 《Central European Journal of Chemistry》2013,11(11):1786-1798
The functionalization of poly(ethylene terephthalate) (PET) surface films by reactions with multifunctional amines such as triethylenetetramine (TETA), and tetraethylenepentamine (TEPA) was investigated. For the functionalization of PET films surface we used a new way of treatment, a “sandwich model”. Physical-chemical properties of functionalized PET films were analysed. Qualitative and quantitative determination of the introduced amine groups were examined by means of Fourier Transform Infrared Attenuated Total Reflexion (FTIR — ATR), X-ray photoelectron spectroscopy (XPS), and potentiometric titration. Gained wetting properties were determined by using contact angle measurements and thoroughly analysed by acid-base approach. In addition, surface topography was investigated by atomic force microscopy (AFM). The amount of the introduced amino groups after TETA incorporation has been found to be two times higher as compared to TEPA. Wetting properties were significantly improved after aminolysis. Surface free energy was higher for PET — TETA treated film than that observed for PET — TEPA treated which is in accordance with titration results. The collagen immobilization onto PET treated films was evidenced by using AFM and subsequently by using XPS. 相似文献