首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   238篇
  免费   2篇
  国内免费   7篇
化学   109篇
晶体学   1篇
力学   3篇
数学   86篇
物理学   48篇
  2022年   3篇
  2021年   9篇
  2020年   8篇
  2019年   6篇
  2018年   2篇
  2017年   5篇
  2016年   8篇
  2015年   4篇
  2014年   10篇
  2013年   15篇
  2012年   9篇
  2011年   15篇
  2010年   14篇
  2009年   13篇
  2008年   12篇
  2007年   15篇
  2006年   13篇
  2005年   15篇
  2004年   7篇
  2003年   9篇
  2002年   12篇
  2001年   3篇
  1999年   4篇
  1998年   1篇
  1997年   1篇
  1996年   3篇
  1995年   1篇
  1994年   2篇
  1993年   1篇
  1992年   2篇
  1991年   1篇
  1990年   2篇
  1988年   1篇
  1987年   1篇
  1986年   2篇
  1985年   2篇
  1984年   3篇
  1983年   1篇
  1982年   2篇
  1981年   1篇
  1980年   3篇
  1978年   1篇
  1976年   1篇
  1975年   1篇
  1973年   2篇
  1969年   1篇
排序方式: 共有247条查询结果,搜索用时 62 毫秒
151.
We prove the existence of integral solutions to the nonlocal Cauchy problem in a Banach space X, where is m-accretive and such that –A generates a compact semigroup, has nonempty, closed and convex values, and is strongly-weakly upper semicontinuous with respect to its second variable, and . The case when A depends on time is also considered.   相似文献   
152.
Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeL(B5)(NCS)(2)].trans-[FeL(B5)(NCS)(2)]}.CH(3)OH, , (L(B5) = N,N'-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1,3-diamine); the synthesis, X-ray structure, and magnetic and M?ssbauer study of this unique example of co-crystallised geometric, conformational and electronic isomers are reported.  相似文献   
153.
The ground states of FeS(2) and FeS(2)(-), and several low-lying excited electronic states of FeS(2) that are responsible for the FeS(2)(-) photoelectron spectrum, are calculated. At the B3LYP level an open, quasi-linear [SFeS](-) conformation is found as the most stable structure, which is confirmed at the ab initio CASPT2 computational level. Both the neutral and the anionic unsaturated complexes possess high-spin electronic ground states. For the first time a complete assignment of the photoelectron spectrum of FeS(2)(-) is proposed. The lowest energy band in this spectrum is ascribed to an electron detachment from the two highest-lying 3dpi antibonding orbitals (with respect to the iron-sulfur bonding) of iron. The next-lowest experimental band corresponds to an electron removal from nonbonding, nearly pure sulfur orbitals. The two highest bands in the spectra are assigned as electron detachments from pi and sigma bonding mainly sulfur orbitals.  相似文献   
154.
155.
Necessary conditions for the optimality of a pair with respect to a locally Lipschitz cost functional L(y,u) , subject to Ay + F(y) = Cu + B(u) , are given in terms of generalized gradients. Here A and C are densely defined, closed, linear operators on some Banach spaces, while F and B are (Fréchet) differentiable maps, which are suitably related to A and C . Various examples and potential applications to nonlinear programming models and nonlinear optimal control of partial differential equations are also discussed. Accepted 18 March 1998  相似文献   
156.
The synthesis and characterization of new symmetrical FeII complexes, [FeLA(NCS)2] (1), and [FeLBx(NCS)2] (24), are reported (LA is the tetradentate Schiff base N,N′-bis(1-pyridin-2-ylethylidene)-2,2-dimethylpropane-1,3-diamine, and LBx stands for the family of tetradentate Schiff bases N,N′-bis[(2-R-1H-imidazol-4-yl)methylene]-2,2-dimethylpropane-1,3-diamine, with: R = H for LB1 in 2, R = Me for LB2 in 3, and R = Ph for LB3 in 4). Single-crystal X-ray structures have been determined for 1 (low-spin state at 293 K), 2 (high-spin (HS) state at 200 K), and 3 (HS state at 180 K). These complexes remain in the same spin-state over the whole temperature range [80–400 K]. The dissymmetrical tetradentate Schiff base ligands LCx, N-[(2-R2-1H-imidazol-4-yl)methylene]-N′-(1-pyridin-2-ylethylidene)-2,2-R1-propane-1,3-diamine (R1 = H, Me; R2 = H, Me, Ph), containing both pyridine and imidazole rings were obtained as their [FeLCx(NCS)2] complexes, 510, through reaction of the isolated aminal type ligands 2-methyl-2-pyridin-2-ylhexahydropyrimidine (R1 = H, 57) or 2,5,5-trimethyl-2-pyridin-2-ylhexahydropyrimidine (R1 = Me, 810) with imidazole-4-carboxaldehyde (R2 = H: 5, 8), 2-methylimidazole-4-carboxaldehyde (R2 = Me: 6, 9), and 2-phenyl-imidazole-4-carboxaldehyde (R2 = Ph: 7, 10) in the presence of iron(II) thiocyanate. Together with the single-crystal X-ray structures of 7 and 9, variable-temperature magnetic susceptibility and Mössbauer studies of 510 showed that it is possible to tune the spin crossover properties in the [FeLCx(NCS)2] series by changing the 2-imidazole and/or C2-propylene susbtituent of LCx.  相似文献   
157.
158.
A versatile, modular in situ high-intensity monochromatic illumination set-up installed on a standard Q-band ESR spectrometer equipped with a cryostat and probe head for measurements at cryogenic temperatures, which can be easily assembled from commercially available optical components is presented. Using as monochromatic light sources pig-tailed laser diodes (LDs) or fiber-coupled light-emitting diodes (LEDs), a high efficiency of the light transfer (more than 95%) through an optical guide inserted in the sample holder is achieved in the sample area of the microwave cavity. With various LEDs and LDs, one can perform ESR in situ illumination experiments from UV to far-IR, in both cw and pulse mode. Its operation is illustrated with an experiment revealing the presence of certain ESR silent defects in oxygen-doped floating-zone ultrapure Si samples irradiated at room temperature with high-energy–high-fluence electron beams and pulse annealed up to 300 °C. New information is obtained by comparing the ESR spectra recorded at T = 120 K, without and with 1.06 µm across-the-gap in situ illumination.  相似文献   
159.
160.
The textural properties of butter are influenced by its fat content and implicitly by the fatty acids composition. The impact of butter’s chemical composition variation was studied in accordance with texture and color properties. From 37 fatty acids examined, only 18 were quantified in the analyzed butter fat samples, and approximately 69.120% were saturated, 25.482% were monounsaturated, and 5.301% were polyunsaturated. The butter samples’ viscosity ranged between 0.24 and 2.12 N, while the adhesiveness ranged between 0.286 to 18.19 N·mm. The principal component analysis (PCA) separated the butter samples based on texture parameters, fatty acids concentration, and fat content, which were in contrast with water content. Of the measured color parameters, the yellowness b* color parameter is a relevant indicator that differentiated the analyzed sample into seven statistical groups; the ANOVA statistics highlighted this difference at a level of p < 0.001.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号