Statistical Entropy of Black Hole without Truncation Factor

The scatting probability of scalar particles near the event horizon is obtained by solving Klein-Gordon equation in curved space-time. By considering the reaction of a black hole radiation in space-time background, we find that Hawking radiation is not a strictly pure thermal-spectrum and scatting probability is related to the B-H entropy change of black hole. The statistical entropy of black hole is calculated based on the relations between entropy and thermodynamic probability of a macroscopic state in statistical equilibrium. The results show that the statistical entropy of black hole without using any truncation factor is proportional to the area of event horizon.     

Deterministic Assisted Clone of an Arbitrary Two- and Three-qubit States via Multi-qubit Brown State

We present two schemes for deterministic assisted clone(DAC) of an unknown two- and three-qubit entangled states with assistance via muti-qubit Brown state. In the schemes, the sender wish to teleport an unknown original entangled state which from the state preparer, and then create a perfect copy of the unknown state at her place. The DAC schemes include two stages. The first stage requires teleportation with Bell-state measurements via a five-qubit Brown state(or seven-qubit Brown state) as the quantum channel. In the second stage, to help the sender realize the quantum cloning, the state preparer performs projective measurements on their own particles which from the sender, then the sender can acquire a perfect copy of the unknown state by means of some appropriate unitary operations. Furthermore, the total success probability for assisted cloning a perfect copy of the unknown state can reach 1 in our schemes.     

An Novel Protocol for the Quantum Secure Multi-Party Summation Based on Two-Particle Bell States

A protocol for the quantum secure multi-party summation based on two-particle Bell states is proposed. In this protocol, two-particle Bell states are used as private information carriers. Without using the entangled character of Bell states, we also use Pauli matrices operations to encode information and Hadamard matrix to extract information. The proposed protocol can also resist various attacks and overcomes the problem of information leakage with acceptable efficiency. In theory, our protocol can be used to build complex secure protocols for other multiparty computations and also lots of other important applications in distributed networks.     

Quantum Image Encryption Based on Iterative Framework of Frequency-Spatial Domain Transforms

A novel quantum image encryption and decryption algorithm based on iteration framework of frequency-spatial domain transforms is proposed. In this paper, the images are represented in the flexible representation for quantum images (FRQI). Previous quantum image encryption algorithms are realized by spatial domain transform to scramble the position information of original images and frequency domain transform to encode the color information of images. But there are some problems such as the periodicity of spatial domain transform, which will make it easy to recover the original images. Hence, we present the iterative framework of frequency-spatial domain transforms. Based on the iterative framework, the novel encryption algorithm uses Fibonacci transform and geometric transform for many times to scramble the position information of the original images and double random-phase encoding to encode the color information of the images. The encryption keys include the iterative time t of the Fibonacci transform, the iterative time l of the geometric transform, the geometric transform matrix G i which is n × n matrix, the classical binary sequences K (\(k_{0}k_{1}{\ldots } k_{2^{2n}-1}\)) and \(D(d_{0}d_{1}{\ldots } d_{2^{2n}-1}\)). Here the key space of Fibonacci transform and geometric transform are both estimated to be 2²⁶. The key space of binary sequences is (2 ^n×n ) × (2 ^n×n ). Then the key space of the entire algorithm is about \(2^{2{n^{2}}+52}\). Since all quantum operations are invertible, the quantum image decryption algorithm is the inverse of the encryption algorithm. The results of numerical simulation and analysis indicate that the proposed algorithm has high security and high sensitivity.     

Meson Effect in the Proto Neutron Star PSR J0348+0432

The effect of mesons f ₀(975) (named as f), ?(1020) (named as ?) and δ on the moment of inertia of the PNS PSR J0348+0432 is examined in the framework of the relativistic mean field theory considering the baryon octet. It is found that the energy density ε and pressure p will increase considering the mesons δ whereas will decrease as the mesons f and ? being considered. When the mesons f,? and δ are considered, the energy density and pressure will all decrease. It is also found that the contribution of mesons f, ? and δ to the central energy density is only the central energy density’s 0.06 ～0.6% whereas the contribution of mesons f, ? and δ to the central pressure is the central pressure’s 4 ～7%. For the radius, it will decrease when the contributions of mesons f, ? and δ are considered. The moment of inertia I will increase considering the mesons δ whereas will decrease as the mesons f and ? being considered. When the mesons f, ? and δ are all considered, the moment of inertia will decrease. It is found that the contribution of mesons f and ? to moment of inertia is 4 ～9 times larger than that of mesons δ. Our results show that the mesons f, ? and δ contribute to the moment of inertia’s 2 ～5%.     

A highly Selective Fluorescent Sensor for Monitoring Cu<Superscript>2+</Superscript> Ion: Synthesis,Characterization and Photophysical Properties

A new fluorescent sensor, 4-allylamine-N-(N-salicylidene)-1,8-naphthalimide (1), anchoring a naphthalimide moiety as fluorophore and a Schiff base group as receptor, was synthesized and characterized. The photophysical properties of sensor 1 were conducted in organic solvents of different polarities. Our study revealed that, depending on the solvent polarity, the fluorescence quantum yields varied from 0.59 to 0.89. The fluorescent activity of the sensor was monitored and the sensor was consequently applied for the detection of Cu²⁺ with high selectivity over various metal ions by fluorescence quenching in Tris-HCl (pH = 7.2) buffer/DMF (1:1, v/v) solution. From the binding stoichiometry, it was indicated that a 1:1 complex was formed between Cu²⁺ and the sensor 1. The fluorescence intensity was linear with Cu²⁺ in the concentration range 0.5–5 μM. Moreso, the detection limit was calculated to be 0.32 μM, which is sufficiently low for good sensitivity of Cu²⁺ ion. The binding mode was due to the intramolecular charge transfer (ICT) and the coordination of Cu²⁺ with C = N and hydroxyl oxygen groups of the sensor 1. The sensor proved effective for Cu²⁺ monitoring in real water samples with recovery rates of 95–112.6 % obtained.     

Metal Quinolates as Phosphors for PC-LED Applications

Metal quinolates, Liq Alq₃ Znq₂ Mgq₂ exhibit efficient luminescence in blue green region and find applications as emission layer in OLEDs. In most of these quinolates the excitation spectra are broad in the range 350 to 410 nm, just short of emission spectra of efficient GaN based blue LEDs. In this paper we report metal quinolates synthesized by slightly modified method in which the excitation gets extended beyond 450 nm so that there is better overlap between emission spectra of blue LED and the excitation spectra. Therefore these phosphors may be used for PC-LED applications.     

A Ratiometric and near-Infrared Fluorescent Probe for Imaging Cu<Superscript>2+</Superscript> in Living Cells and Animals

We have rationally constructed a novel ratiometric and near-infrared Cu²⁺ fluorescent probe based on a tricarbocyanine chromophore. The new probe NIR-Cu showed a ratiometric fluorescent response to Cu²⁺ with a large emission wavelength shift (up to 142 nm) in the far-red to near-infrared region. The probe also displayed a large variation in the fluorescence ratio (I₆₃₆/I₇₇₈) to Cu²⁺ species with high sensitivity and selectivity. Additionally, the developed probe NIR-Cu was suitable for fluorescence imaging of Cu²⁺ in living cells and mice.     

Comparison of the Optoelectronic Performance of Neutral and Cationic Forms of Riboflavin

The riboflavin dye 2,3,4,5-tetra-O-acetyl-1-[3-(6-bromohexyl)-7,8-dimethyl-2,4-dioxo-3,4-dihydrobenzo[g]pteridin-10(2H)-yl]-1-deoxypentitol and its pyridinium salt were synthesized, and studied by absorption and fluorescence spectroscopy in solutions and on thin film states. The first absorption band of riboflavin-pyridinium salt derivative is red-shifted by 10 nm compared to neutral one on film. Cationic riboflavin derivative shows significant wavelength changes on its fluorescence emission spectrum in the excited state depending on the solvent polarity and the electronic environment. The fluorescence quantum yields of cationic riboflavin gave much higher values as compared to that of its neutral form. The fluorescence lifetimes were found to be in the range of 5.5–6.6 ns with mono ? exponential behavior. These dyes possess low-lying HOMO energy levels which are suitable to be able to inject holes to donor polymers so that they can be used as acceptor component in the active layer of bulk heterojunction solar cells (BHJ-SCs). Photovoltaic responses are reported for P3HT:riboflavin active layer wherein the synthesized dyes are used as acceptor component. Also, neutral riboflavin shows greater electron mobility value of 1.3 × 10^?3 cm²/V?s compared to its cationic derivative.     

Novel Fluorometric Turn On Detection of Aluminum by Chalcone-Based Chemosensor in Aqueous Phase

A novel, 100% water-soluble chalcone based chemosensing receptor {1-[3-(2-Hydroxy-phenyl)-3-oxo-propenyl]-naphthalen-2-yloxy}-acetic acid, L was synthesized and characterized. The receptor L is designed based on the chelation enhanced fluorescence (CHEF) mechanism. The chemosensing properties of L were evaluated by UV–vis and fluorescence spectrometric methods. It exhibits highly selective recognition ability towards aluminum ions in water over other metal ions. The binding stoichiometry of L? Al³⁺ complex is 2:1 by means of Job’s plot and the detection limit is 5.66?×?10^??8 M.