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981.
982.
983.
984.
The adsorptive denitrogenation from fuels over three metal-organic frameworks(MIL-96(Al),MIL-53(Al)and MIL-101(Cr))was studied by batch adsorption experiments.Four nitrogen-containing compounds(NCCs)pyridine,pyrrole,quinoline and indole were used as model NCCs in fuels to study the adsorption mechanism.The physicochemical properties of the adsorbents were characterized by XRD,N2physical adsorption,FT-IR spectrum and Hammett indicator method.The metal-organic frameworks(MOFs),especially the MIL-101(Cr)containing Lewis acid sites as well as high specific surface area,can adsorb large quantities of NCCs from fuels.In addition,the adsorptive capacity over MIL-101(Cr)will be different for NCCs with different basicity.The stronger basicity of the NCC is,the more it can be absorbed over MIL-101(Cr).Furthermore,pore size and shape also affect the adsorption capacity for a given adsorbate,which can be proved by the adsorption over MIL-53(Al)and MIL-96(Al).The pseudo-second-order kinetic model and Langmuir equation can be used to describe kinetics and thermodynamics of the adsorption process,respectively.Finally,the regeneration of the used adsorbent has been conducted successfully by just washing it with ethanol. 相似文献
985.
The detailed reaction pathway and coke formation mechanism over Pt/metal oxide nanoparticles during the steam reforming of ethanol(SRE) at 300℃were studied.The catalysts were prepared by incipient wetness impregnation method and were characterized with CO pulse chemisorption, BET surface measurement,oxygen adsorption,ethanol-TPD,NH3-TPD,and TPO.The SRE activity of the catalysts with steam/ethanol molar ratio of 3/1 was tested using a continuous fixed-bed reactor.Strong interaction between Pt and supports causes lower H2 production temperatures and no C2H4 formation,while weak interaction leads to C2H4 formation and strong bonded CO on Pt particles during ethanol-TPD. H2 production over Pt-based catalysts is mainly resulted from the decomposition and dehydrogenation of ethanol,and decarbonylation of acetaldehyde.Meanwhile,coke can be formed from acetaldehyde,acetone,C2H4 and CO.However,when the interaction between Pt and supports is weak,more coke is formed especially from acetone,C2H4 and CO.When the interaction is strong,no coke formation is observed due to high oxygen storage capacity of the catalyst. 相似文献
986.
The construction and characteristic performance of a PVC membrane electrode responsive for sodium dodecylsulfate (SDS) are described in this paper. The electrode based on CTA+DS? ion pair as ionophore in PVC membrane displays a Nernstian slope of ?58.8 ± 0.7 mV/decade in a 1.32 × 10?6 to 3.75 × 10?3 mol L?1 concentration range and a limit of detection of 1.13 × 10?6 mol L?1. The electrode can be used for 3 months without showing significant changes in the value of slope or working range. The electrode has been utilized as an end point indicator electrode for potentiometric titration involving Hyamine as titrant. More than 100 titrations were carried out for the evaluation of the electrode parameters: the standard deviations of the equivalent volume and the equivalent potential, the height of the potential jump and the number of faulty titrations. The behavior of the electrode was assessed with regard to their usefulness in routine analysis. 相似文献
987.
Bao-Lei Wang Qing-Nan Li Yi-Zhou Zhan Li-Xia Xiong Shu-Jing Yu Zheng-Ming Li 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):483-491
Abstract A novel series of pyrazole derivatives containing substituted phenylsulfinyl/sulfonyl group have been synthesized via the oxidation of intermediate pyrazole sulfoether with H2O2 in acetic acid. The novel compounds were characterized by melting point, 1H NMR, FT-IR, MS, and elemental analysis or HRMS. The biological activity results showed that most of the title compounds exhibit significant fungicidal activities against Alternaria solani Sorauer, Phytophthora capsici, and Corynespora cassiicola. [Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental files: Additional text and figures.] 相似文献
988.
C. Y. Wang 《Archive of Applied Mechanics (Ingenieur Archiv)》2013,83(1):171-176
The vibration of a cantilever beam with constant thickness and linearly tapered sides is solved using a novel accurate, efficient initial value numerical method. The effects of tip mass, base fixity, and taper on the natural frequencies are determined. This geometrically anisotropic beam vibrates in a mixture of modes in two perpendicular directions. 相似文献
989.
Sin-Chung Chang Yuhui Wu Xiao-Yen Wang 《International Journal of Computational Fluid Dynamics》2013,27(5):359-380
A local time-stepping procedure for the space-time conservation element and solution element (CESE) method has been developed. This new procedure allows for variation of time-step size in both space and time, and can also be extended to become multi-dimensional solvers with structured/unstructured spatial grids. Moreover, it differs substantially in concept and methodology from the existing approaches. By taking full advantage of key concepts of the CESE method, in a simple and efficient manner it can enforce flux conservation across an interface separating grid zones of different time-step sizes. In particular, no correction pass is needed. Numerical experiments show that, for a variety of flow problems involving moving shock and flame discontinuities, accurate and robust numerical simulations can be achieved even with a reduction in time-step size on the order of 10 or higher for grids across a single interface. 相似文献
990.