Phase transformation in Sm2O3 at high pressure: In situ synchrotron X-ray diffraction study and ab initio DFT calculation

Sm₂O₃ was compressed at room temperature up to 44.0 GPa and then decompressed back to ambient pressure. In situ X-ray diffraction was used to monitor the structural changes in the sample. A cubic to hexagonal phase transformation was observed in Sm₂O₃ for the first time. After decompression back to ambient pressure, the hexagonal phase was not quenchable and transformed to a monoclinic phase. Ab initio Density- Functional-Theory (DFT) calculations were performed to obtain theoretical data for comparison with the experimental results and elucidation of the transformation mechanism. A possible phase transformation mechanism that is consistent with the experimental results and theoretical calculations is proposed.     

All-optical dual-direction half-subtracter based on sum-frequency generation

We report a simple method to realize all-optical dual-direction half-subtracter at 40 Gb/s based on sum-frequency generation (SFG) using only one periodically poled lithium niobate (PPLN) waveguide. The SFG process generates the Borrow outputs and the combination of the outputs from PPLN after SFG results in the Difference. The operation performance of the proposed scheme is simulated, including eye diagrams, Q-factor, extinction ratio, and tunability. For different input optical powers, the length of the PPLN waveguide is optimized.     

Silica waveguide ring resonators with multi-turn structure

Optical waveguide ring resonator is the basic element of resonator integrated optic gyro (RIOG). In this paper, we report a novel configuration of optical waveguide ring resonator using a multi-turn structure. The characteristic of the light propagating across the crossed waveguides is analyzed using the finite difference beam propagation method. The relationship between the propagation loss and the intersection angle for arbitrary intersecting angles has been analyzed. Some crossed waveguides are fabricated in silica waveguides to verify the theoretical results. On this basis, the influences of the loop numbers and the excess loss of the crossed waveguide on the limited sensitivity of the RIOG have been analyzed. There is a critical intersection angle for certain resonator, only when the intersection angle is bigger than the critical angle, the gyro sensitivity can be improved by increasing the loop numbers. This will be helpful to how to determine the optimum length in resonator for its application in RIOG.     

A global design of high power Nd-Yb co-doped fiber lasers

A global optimization method - niche hybrid genetic algorithm (NHGA) based on fitness sharing and elite replacement is applied to optimize Nd³⁺-Yb³⁺ co-doped fiber lasers (NYDFLs) for obtaining maximum signal output power. With a objective function and different pumping powers, five critical parameters (the fiber length, L; the proportion of pump power for pumping Nd³⁺, η; Nd³⁺ and Yb³⁺ concentrations, N_Nd and N_Yb and output mirror reflectivity, R_out) of the given NYDFLs are optimized by solving the rate and power propagation equations. Results show that dividing equally the input pump power among 808 nm (Nd³⁺) and 940 nm (Yb³⁺) is not an optimal choice and the pump power of Nd³⁺ ions should be kept around 10-13.78% of the total pump power. Three optimal schemes are obtained by NHGA and the highest slope efficiency of the laser is able to reach 80.1%.     

Effects of solvent composition on the electrochemical performance of Li2FeSiO4/C cathode materials synthesized via tartaric-acid-assisted sol–gel method

Li₂FeSiO₄/C composites were synthesized via a tartaric-acid-assisted sol–gel method with ethanol and ethylene glycol (EG) as mixed solvents. Effects of solvent composition on the physical properties and electrochemical performances of Li₂FeSiO₄/C were studied. The materials were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical performances of Li₂FeSiO₄/C were evaluated by galvanostatic charge–discharge and electrochemical impedance spectra (EIS) measurements. The results show that the addition of EG to ethanol solvent during preparation has a positive effect on the electrochemical performance of Li₂FeSiO₄/C. The sample synthesized using EG–ethanol with the volume ratio of 2:7 has the best electrochemical performance. It delivers an initial discharge capacity of 105 mAh g^?1 at C/16. AC impendence investigation shows that Li₂FeSiO₄/C synthesized using the optimal EG/ethanol volume ratio has lower resistance of electrode/electrolyte interface and higher lithium-ion diffusion coefficient than that synthesized using ethanol as solvent.     

Instability-free ion acceleration by two laser pulses

We demonstrate the instability-free ion acceleration regime by introducing laser control with two parallel circularly polarized laser pulses at an intensity of I = 6.8 × 10²¹?W/cm², normally incident on a hydrogen foil. The special structure of the equivalent wave front of those two pulses, which contains Gaussian peaks in both sides and a concavity in the centre (2D), can suppress the transverse instabilities and hole boring effects to constrain a high density ion clump in the centre of the foil, leading to an acceleration over a long distance and gain above 1GeV/u for the ion bunches.     

Investigation of polymer/inorganic hybrid photovoltaic device using quantum dots as the interface modifier

CdS quantum dots (QDs) were introduced as an interface modifier in the poly(3-hexylthiophene) (P3HT)/TiO₂ nanorod arrays hybrid photovoltaic device. The presence of CdS QDs interlayer was found to provide enhanced light absorption, increased interfacial recombination resistance at the P3HT/TiO₂ interfaces, thus leading to a lower recombination rate of the electrons due to the stepwise structure of band edge in P3HT/CdS/TiO₂, which accounts for the observed enhanced photocurrent and photovoltage of the hybrid solar cells. The optimized performance was achieved in P3HT/CdS/TiO₂ hybrid solar cells after deposition of CdS QDs for 10 cycles, with a power conversion efficiency of 0.57 %, which is nearly ten times higher than that of P3HT/TiO₂. The findings indicate that inorganic semiconductor quantum dots provide effective means to improve the performance of polymer/TiO₂ hybrid solar cells.     

蒸汽喷射器变工况性能的CFD探讨

利用二维轴对称,真实气体模型对喷射式制冷空调系统的喷射器进行CFD计算。真实气体模型占用较多的计算机资源,但它的计算结果更加真实。计算的目的在于得到在变工况条件下喷射器性能的变化和制冷系统性能的变化情况。在计算范围中,存在一最优的发生压力Pg*(3.973568bar),使得此时的喷射系数和系统COP最大。当Pg>Pg*时,喷射系数和COP随着发生压力的增加而减少;当Pg相似文献   

Evolution of downsized crescent-shaped dune in wind tunnel experiment

The migration of a downsized crescent-shaped dune was investigated in a wind tunnel experiment.Quantified upwind influx and vertical oscillation of the sand bed were introduced to modulate the saturation level of the sand flux above the dune surface to affect dune evolution.The evolution was recorded by top-view photography and then abstracted as the evolution of self-defined characteristic quantities using a digital image processing algorithm.The results showed that,in contrast to the case for spanwise quantities,the evolution of streamwise quantities corresponds to a linear increase in the modulation magnitude more positively and in a monotonic and convergent manner.In contrast with quantities on the windward face,the changes in quantities with respect to the horns were nonmonotonic with time and almost uncorrelated with the variation in modulation strength,which reveals the distinctiveness of leeside evolution.