Effect of distortion in electron impact excitation in Coulomb-projected Born approximation

We have calculated total and differential cross-sections for 1s →ns (n = 2, 3, 4) electron impact excitation of hydrogen and hydrogenic ions at various energies in Coulomb-projected Born approximation. Distortion due to static interactions, target polarization and exchange effects has been incorporated in the initial channel. The present calculations have been compared with other theoretical and experimental results.     

Kinetics and mechanism of polymerization of methyl methacrylate initiated by stibonium ylide

Homopolymerization of methyl methacrylate (MMA) was carried out in the presence of triphenylstibonium 1,2,3,4-tetraphenyl-cyclopentadienylide as an initiator in dioxane at 65°C±0·l°C. The system follows non-ideal radical kinetics (R _p ∝ [M]^1·4 [I]^0·44 @#@) due to primary radical termination as well as degradative chain-transfer reaction. The overall activation energy and average value ofk ₂ ^p /k _t were 64 kJmol⁻¹ and 0.173 × 10⁻³ 1 mol⁻¹ s⁻¹ respectively     

Kinetics and mechanism of the reactions of hexaaqua rhodium (III) with sulphur (IV) in aqueous medium

An O-bonded sulphito complex, Rh(OH₂)₅(OSO₂H)²⁺, is reversibly formed in the stoppedflow time scale when Rh(OH₂) ₆ ³⁺ and SO₂/HSO ₃ ⁻ buffer (1 <pH< 3) are allowed to react. For Rh(OH₂)₅OH₂₊+ SO₂ □ Rh(OH₂)₅(OSO₂H)²⁺ (k₁/k_-1), k₁ = (2.2 ±0.2) × 10³ dm³ mol⁻¹ s⁻¹, k₋1 = 0.58 ±0.16 s⁻¹ (25°C,I = 0.5 mol dm⁻³). The protonated O-sulphito complex is a moderate acid (K _d = 3 × 10⁻⁴ mol dm⁻³, 25°C, I= 0.5 mol dm⁻³). This complex undergoes (O, O) chelation by the bound bisulphite withk= 1.4 × 10⁻³ s⁻¹ (31°C) to Rh(OH₂)₄(O₂SO)⁺ and the chelated sulphito complex takes up another HSO ₃ ⁻ in a fast equilibrium step to yield Rh(OH₂)₃(O₂SO)(OSO₂H) which further undergoes intramolecular ligand isomerisation to the S-bonded sulphito complex: Rh(OH₂)₃(O₂SO)(OSO₂)^- → Rh(OH₂)₃(O₂SO)(SO₃)⁻ (k _iso = 3 × 10⁻⁴ s⁻¹, 31°C). A dinuclear (μ-O, O) sulphite-bridged complex, Na₄[Rh₂(μ-OH)₂(OH)₂(μ-OS(O)O)(O₂SO)(SO₃) (OH₂)]5H₂O with (O, O) chelated and S-bonded sulphites has been isolated and characterized. This complex is sparingly soluble in water and most organic solvents and very stable to acid-catalysed decomposition     

An efficient total synthesis of sulfobacin A

A short and efficient enantioselective synthesis of sulfobacin A has been achieved using the Sharpless asymmetric dihydroxylation and the regiospecific nucleophilic opening of a cyclic sulfate as the key steps.     

Synthesis of a hairpin pyrrole-imidazole polyamide conjugate containing a quinone methide precursor and vinyl linking group

Standard procedures for elaborating a quinone methide precursor for conjugation to a DNA ligand was not compatible with the presence of a vinyl group. Instead, an acrylate linker was attached by Heck coupling subsequent to o-substitution of the phenolic precursor. This transformation required protection of the phenolic group and use of ethyl acrylate rather than acrylic acid. The presence of the vinyl group also rendered the quinone methide precursor more labile to alkaline conditions than its equivalent saturated derivative and required mild conditions for coupling to the pyrrole-imidazole polyamide.     

The sojourn time and related characteristics of the age-dependent branching process

An age-dependent branching process where disasters occur as a renewal process leading to annihilation or survival ofall the cells, is considered. For such a process, the total mean sojourn time of all the cells in the system is analysed using the regeneration point technique. The mean number of cells which die in timet and its asymptotic behaviour are discussed. When the disasters arrival as a Poisson process and the lifetime of the cells follows exponential distribution, elegant inter-relationships are found among the means of (i) the total number of cells which die in timet (ii) the total sojourn time of all cells in the system upto timet and (iii) the number of living cells at timet. Some of the existing results are deduced as special cases for related processes.     

Study of solar features causing GMSs with 250γ<<Emphasis Type="Italic">H</Emphasis><400γ

The effect of solar features on geospheric conditions leading to geomagnetic storms (GMSs) with planetary index,A ^P ≥ 20 and the range of horizontal component of the Earth’s magnetic fieldH such that 250γ <H < 400γ has been investigated using interplanetary magnetic field (IMF), solar wind plasma (SWP) and solar geophysical data (SGD) during the period 1978–99. Statistically, it is observed that maximum number of GMSs have occurred during the maximum solar activity years of 21st and 22nd solar cycles. A peculiar result has been observed during the years 1982, 1994 when sunspot numbers (SSNs) decrease very rapidly while numbers of GMSs increase. No distinct association between yearly occurrence of disturbed days and SSNs is observed. Maximum number of disturbed days have occurred during spring and rainy seasons showing a seasonal variation of disturbed days. No significant correlation between magnitude (intensity) of GMSs and importance ofH _α , X-ray solar flares has been observed. Maximum number of GMSs is associated with solar flares of lower importance, i.e., SF during the period 1978-93.H _α , X-ray solar flares occurred within lower helio-latitudes, i.e., (0–30)°N to (0–30)°S are associated with GMSs. NoH _α , X-ray solar flares have occurred beyond 40°N or 40°S in association with GMSs. In helio-latitude range (10–40)°N to (10–40)°S, the 89.5% concentration of active prominences and disappearing filaments (APDFs) are associated with GMSs. Maximum number of GMSs are associated with solar flares. Coronal mass ejections (CMEs) are related with eruptive prominences, solar flares, type IV radio burst and they occur at low helio-latitude. It is observed that CMEs related GMS events are not always associated with high speed solar wind streams (HSSWSs). In many individual events, the travel time between the explosion on the Sun and maximum activity lies between 58 and 118 h causing GMSs at the Earth.     

Robust Adaptive Identification of Fuzzy Systems with Uncertain Data

This study presents a method of adaptive identification of parameters describing Sugeno fuzzy inference system in presence of bounded disturbances while maintaining the readability and interpretability of the fuzzy model during and after identification. This method do not require any a priori knowledge of a bound on the disturbance and noise and of a bound on the unknown parameters values. The method can be used for the robust and adaptive identification of slowly time varying nonlinear systems using fuzzy inference systems. The suggested method was used to build a fuzzy expert system that approximates the functional relationship between physical fitness and some of the measurable physiological parameters by their real measurements and opinion (human-experiences) of a medical expert.