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261.
[reaction: see text]. Reaction of nitrones with terminal alkynes takes place readily in the presence of a substoichiometric amount of diethylzinc in toluene, affording N-propargyl-hydroxylamines in excellent yields and purity. 相似文献
262.
Sandra Feisel Joachim von zur Gathen M. Amin Shokrollahi. 《Mathematics of Computation》1999,68(225):271-290
Gauss periods have been used successfully as a tool for constructing normal bases in finite fields. Starting from a primitive th root of unity, one obtains under certain conditions a normal basis for over , where is a prime and for some integer . We generalize this construction by allowing arbitrary integers with , and find in many cases smaller values of than is possible with the previously known approach.
263.
264.
Sandra di Rocco 《Mathematische Nachrichten》1996,179(1):47-56
A k-very ample line bundle L on a Del Pezzo Surface is numerically characterized, improving the results of Biancofiore— Ceresa in [7]. 相似文献
265.
Background: The translation or stability of the mRNAs from ferritin, m-aconitase, erythroid aminoevulinate synthase and the transferrin receptor is controlled by the binding of two iron regulatory proteins to a family of hairpin-forming RNA sequences called iron-responsive elements (IREs). The determination of higher-solution nuclear magnetic resonance (NMR) structures of IRE variants suggests an unusual hexaloop structure, leading to an intra-loop G-C base pair and a highly exposed loop guanine, and a special internal loop/bulge in the ferritin IRE involving a shift in base pairing not predicted with standard algorithms.Results: Cleavage of synthetic 55- and 30-mer RNA oligonucleotides corresponding to the ferritin IRE with complexes based on oxoruthenium(IV) shows enhanced reactivity at a hexaloop guanine and at a guanine adjacent to the internal loop/bulge with strong protection at a guanine in the internal loop/bulge. These results are consistent with the recent NMR structures. The synthetic 55-mer RNA binds the iron-regulatory protein from rabbit reticulocyte lysates. The DNA analogs of the 55- and 30-mers do not show the same reactivity pattern.Conclusions: The chemical reactivity of the guanines in the ferritin IRE towards oxoruthenium(IV) supports the published NMR structures and the known oxidation chemistry of the metal complexes, The results constitute progress towards developing stand-alone chemical nucleases that reveal significant structural properties and provide results that can ultimately be used to constrain molecular modeling. 相似文献
266.
We consider the model with kinetic excitation into the quasicontinuum (KEQ) for resonant polyatomic molecules which absorb laser radiation and are surrounded by buffer molecules. KEQ takes place when the resonant molecules in the lower part of the energy spectrum interact weakly with the laser radiation, but the molecules in the quasicontinuum are rapidly excited to still higher energy and dissociate. Under these conditions the collisions of the resonant and buffer molecules lead to excitation of resonant molecules into the quasicontinuum because the population of the quasicontinuum is much less than its thermodynamical equilibrium value. It is found, that the smaller the V-T relaxation time τVT, the larger the rate of KEQ and the dissociation rate (if only τVT is not too small). Thus, if we change the experimental conditions and decrease τVT (for instance, by passing from the heavy buffer gas Xe to the light buffer gas He), for some resonant molecules we may observe that the probability of dissociation increases. 相似文献
267.
Brian Hudson David J. Livingstone Elizabeth Rahr 《Journal of computer-aided molecular design》1989,3(1):55-65
Summary Pattern recognition methods, particularly the unsupervised learning techniques, are well suited for the preliminary analysis of the large data sets produced by computer chemistry. The use of linear and non-linear display methods for such exploratory analysis are exemplified with the aid of two data sets of biologically active molecules. Advantages and disadvantages of these techniques are discussed. 相似文献
268.
Elizabeth K. Heaney S.R. Logan William E. Watts 《Journal of organometallic chemistry》1978,153(2):229-237
In aqueous solution (pH 9) containing N2O, the unsaturated acids -FcCHCH(CH2)nCO2H (n = 0 and 1) and FcCCCO2H each undergo photo-oxidation, upon illumination with u.v. light of wavelength 240-250 nm, giving dipolar ferricenium species which may be chemically reduced back to the original acids. The mechanism of photo-oxidation, which is inhibited by ethanol, appears to be similar to that previously proposed for saturated ω-ferrocenylalkanoic acids. 相似文献
269.
Summary A method is described for roughening the surface of sodalime glass capillaries by depositing sodium chloride dendrites on
the inner wall. The sodium chloride layer improves the wettability of the wall and shows favourable adsorption properties.
For apolar and polar stationary phases coating efficiencies of 60 to 85% are attained. 相似文献
270.
Elizabeth K. Heaney S.R. Logan William E. Watts 《Journal of organometallic chemistry》1978,150(2):309-319
The anions of 4-([3]ferrocenophanyl)butanoic acids (Id and IId), when excited by light of around 240 nm wavelength in aqueous solution in the presence of N2O, undergo photo-oxidation to zwitterions (III and IV respectively) in a manner completely analogous to the reaction of 4-ferrocenylbutanoate anion. The differences in the kinetic parameters of the reactions are thought to be attributable in part to slight tilting of the cyclopentadienyl rings caused by the connecting trimethylene bridge. 相似文献