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941.
942.
Deposition and characterization of TiAlSiN nanocomposite coatings prepared by reactive pulsed direct current unbalanced magnetron sputtering 总被引:3,自引:0,他引:3
Harish C. Barshilia Moumita Ghosh Shashidhara Raja Ramakrishna K.S. Rajam 《Applied Surface Science》2010,256(21):6420-6426
This work reports the performance of high speed steel drill bits coated with TiAlSiN nanocomposite coating at different Si contents (5.5-8.1 at.%) prepared using a four-cathode reactive pulsed direct current unbalanced magnetron sputtering system. The surface morphology of the as-deposited coatings was characterized using field emission scanning electron microscopy. The crystallographic structure, chemical composition and bonding structure were evaluated using X-ray diffraction, energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, respectively. The corrosion behavior, mechanical properties and thermal stability of TiAlSiN nanocomposite coatings were also studied using potentiodynamic polarization, nanoindentation and Raman spectroscopy, respectively. The TiAlSiN coating thickness was approximately 2.5-2.9 μm. These coatings exhibited a maximum hardness of 38 GPa at a silicon content of approximately 6.9 at.% and were stable in air up to 850 °C. For the performance evaluation, the TiAlSiN coated drills were tested under accelerated machining conditions by drilling a 12 mm thick 304 stainless steel plate. Under dry conditions the uncoated drill bits failed after drilling 50 holes, whereas, TiAlSiN coated drill bits (Si = 5.5 at.%) drilled 714 holes before failure. Results indicated that for TiAlSiN coated drill bits the tool life increased by a factor of more than 14. 相似文献
943.
Anne‐Christine Chamayou Chaitali Biswas Ashutosh Ghosh Christoph Janiak 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(8):m311-m313
The crystal structure of the title compound, [Cu(C6H4NO2)(C2H3O2)(C3H4N2)(H2O)]·0.87H2O, has a square‐pyramidal‐coordinated CuII centre (the imidazole is trans to the picolinate N atom, the acetate is trans to the picolinate –CO2 group and the aqua ligand is in a Jahn–Teller‐elongated apical position) and has two symmetry‐independent molecules in the unit cell (Z′ = 2), which are connected through complementary imidazole–picolinate N—H...O hydrogen bonding. The two partially occupied solvent water molecules are each disordered over two positions. The disordered solvent water molecules, together with pseudosymmetry elements, support the notion that a crystal structure with multiple identical chemical formula units in the structural asymmetric unit (Z′ > 1) can represent a crystal `on the way', that is, a kinetic intermediate form which has not yet reached its thermodynamic minimum. Neighbouring molecules form π–π stacks between their imidazole and picolinate N‐heterocycles, with centroid–centroid distances in the range 3.582 (2)–3.764 (2) Å. 相似文献
944.
The large deviations of an infinite moving average process with exponentially light tails are very similar to those of an i.i.d. sequence as long as the coefficients decay fast enough. If they do not, the large deviations change dramatically. We study this phenomenon in the context of functional large, moderate and huge deviation principles. 相似文献
945.
Green fluorescent protein-expressing Escherichia coli as a model system for investigating the antimicrobial activities of silver nanoparticles 总被引:1,自引:0,他引:1
Gogoi SK Gopinath P Paul A Ramesh A Ghosh SS Chattopadhyay A 《Langmuir : the ACS journal of surfaces and colloids》2006,22(22):9322-9328
Recombinant Escherichia coli (E. coli) bacteria expressing green fluorescent protein (GFP) was used as a model system to investigate the antimicrobial activities of Ag nanoparticles (NPs). A convenient in situ method of Ag NP synthesis using sodium borohydride, in the bacterial growth medium, was developed to produce preformed NPs for the study. Fluorescence spectroscopic and microscopic techniques allowed rapid detection of time-dependent changes in bacterial growth as well as fluorescence characteristics in the presence of Ag NPs. In addition, X-ray diffraction, UV-vis spectroscopic, and transmission electron microscopic measurements were carried out to understand the effect of Ag NPs on the bacteria. Our observations indicated that Ag NPs, above a certain concentration, not only were bactericidal but also were found to reduce the sizes of treated bacteria in comparison to untreated ones. Cell lysis of Ag NP-treated bacteria was suggested by the increased GFP fluorescence obtained in the medium. In vitro DNA-Ag NP interaction was detected by spectrophotometric analysis. However, electrophoresis studies indicated no direct effect of Ag NPs on DNA or protein profiles. 相似文献
946.
Mondal JA Ghosh HN Mukherjee T Palit DK 《The journal of physical chemistry. A》2006,110(44):12103-12112
Ultrafast relaxation dynamics of the S2 and S1 states of 4,4'-bis(N,N-dimethylamino)thiobenzophenone (Michler's thione, MT) have been investigated in different kinds of solvents, using steady-state absorption and emission as well as femtosecond transient absorption and fluorescence up-conversion spectroscopic techniques. Steady-state fluorescence measurements, following photoexcitation to the S2 state of MT, reveal weak fluorescence from the S2 state (phi F approximately 10(-3) in nonpolar and 10(-4) in polar solvents) but much weaker fluorescence from the S1 state. Yield of fluorescence from the S2 state is reduced in polar solvents because of reduced energy gap between the S2 and S1 states, Delta E(S2-S1), as well as interaction with the solvent molecules. Occurrence of S2-fluorescence in polar solvents, despite small energy gap, suggests that symmetry allowed S2(1A1) --> S0 (1A1) radiative and symmetry forbidden S2(1A1) --> S1 (1A2) nonradiative transitions are the factors responsible for the S2 fluorescence in MT. Lifetime of the S2 state is shorter (varying in the range 0.28-3.5 ps in different solvents) than that predicted from the Delta E(S2-S1) value and this can be attributed to its flexible molecular structure, which promotes an efficient intramolecular radiationless deactivation pathways. The lifetime of the S1 state (approximately 1.9-6.5 ps) is also very short because of small energy difference between the S1 and T1 states (Delta E(S1-T1) approximately 300 cm(-1)) in cyclohexane and hydrogen-bonding interaction as well as the presence of the isoenergetic T1(pipi*) state to enhance the rate of the intersystem crossing process from the S1(npi*) state in protic solvents. 相似文献
947.
Bayraktar H Ghosh PS Rotello VM Knapp MJ 《Chemical communications (Cambridge, England)》2006,(13):1390-1392
Functionalized gold nanoparticles bind selectively to cytochrome c or cytochrome c peroxidase and inhibit enzyme turnover. 相似文献
948.
The dynamics under the joint action of radiation damping and the distant dipolar field in high-field solution magnetic resonance are investigated. Different dynamical regimes during the evolution are identified and their individual features are discussed. In the steady state, the dynamics can be associated with a strange attractor in phase space on which the motion is chaotic. The possibility of the observed chaotic motion being spatiotemporal is examined. 相似文献
949.
A new approach to carbasugars in enantiomerically pure form is reported. The key step involves ring-closing metathesis of dienols 6 derived from a (R)-(+)-glyceraldehyde derivative 4 to form the substituted cyclopentenol 9 and cyclohexenol 34a. Stereocontrolled addition of hydroxyl groups followed by conversion of the ketal unit to hydroxymethyl group in these intermediates led to carbapentoses and -hexoses. Stereoselectivity during introduction of hydroxyl groups arises through the steric hindrance posed by the allylic substituents. A remarkable feature of the present approach is the accessibility of both d- and l-series of carbapentoses as illustrated by the synthesis of beta-D- and beta-L-carbaribofuranoses 17 and 20, respectively. Carba-alpha-D-ribofuranose 25, the biosynthetic intermediate to the antibiotic aristeromycin, has also been synthesized from the same cyclopentenol 9. Functional group manipulation in the cyclopentenol 9a also enabled access to carbaarabinofuranose 32. The present synthetic strategy can be extended for the synthesis of carbahexopyranose, as illustrated by the synthesis of carba-alpha-L-gulopyranose 40b. 相似文献
950.
We present a cellular automaton (CA) model of particles in a single-file motion with free particle exchange at the boundaries of a one-dimensional channel connected to two infinite reservoirs in order to study the self-transmission of particles with excluded mutual passage. The parallel, local and homogeneous rule sets of the CA algorithm consider two different interactions of varying strength between particles, without any specific particle-channel interaction. CA model results suggest that one hallmark of single-file motion is the conduction bursts at a particular time scale, which have thus far only been discovered for hydrogen bond networked water translocation. The cumulative transport probabilities of particles through single-file channels of different length follow a single profile, which can be obtained through proper scaling of time. The universal features of our results suggest new experiments in single-file channel with fluids other than water. 相似文献