Construction of a singular elliptic-harmonic measure

The authors study an example, suggested by E. De Giorgi, of a second-order uniformly elliptic partial differential operator in divergence form with continuous coefficients on a smooth domain in the plane such that the associated harmonic measure on the boundary is not absolutely continuous with respect to the ordinary surface measure.     

ELECTRE: Robust ordinal regression for outranking methods

We present a new method, called ELECTRE^GKMS, which employs robust ordinal regression to construct a set of outranking models compatible with preference information. The preference information supplied by the decision maker (DM) is composed of pairwise comparisons stating the truth or falsity of the outranking relation for some real or fictitious reference alternatives. Moreover, the DM specifies some ranges of variation of comparison thresholds on considered pseudo-criteria. Using robust ordinal regression, the method builds a set of values of concordance indices, concordance thresholds, indifference, preference, and veto thresholds, for which all specified pairwise comparisons can be restored. Such sets are called compatible outranking models. Using these models, two outranking relations are defined, necessary and possible. Whether for an ordered pair of alternatives there is necessary or possible outranking depends on the truth of outranking relation for all or at least one compatible model, respectively. Distinguishing the most certain recommendation worked out by the necessary outranking, and a possible recommendation worked out by the possible outranking, ELECTRE^GKMS answers questions of robustness concern. The method is intended to be used interactively with incremental specification of pairwise comparisons, possibly with decreasing confidence levels. In this way, the necessary and possible outranking relations can be, respectively, enriched or impoverished with the growth of the number of pairwise comparisons. Furthermore, the method is able to identify troublesome pieces of preference information which are responsible for incompatibility. The necessary and possible outranking relations are to be exploited as usual outranking relations to work out recommendation in choice or ranking problems. The introduced approach is illustrated by a didactic example showing how ELECTRE^GKMS can support real-world decision problems.     

Area-Minimizing Currents mod 2Q: Linear Regularity Theory

We establish a theory of Q -valued functions minimizing a suitable generalization of the Dirichlet integral. In a second paper the theory will be used to approximate efficiently area minimizing currents mod(p) when p = 2Q , and to establish a first general partial regularity theorem for every p in any dimension and codimension . © 2020 Wiley Periodicals LLC.     

The fragmentation of 5- and 3-substituted thiophene-2-carboxamides under electron impact

The 70 eV electron impact mass spectra of twelve 5- and 3-substituted thiophene-2-carboxamides are discussed with the aid of exact mass measurements and labelling experiments. All mass spectra exhibit pronounced molecular ions. Some isomeric 5- and 3-substituted title compounds can be differentiated by mass spectrometry. The fragmentation is influenced by a strong ‘ortho-effect’ which activates the NH₃ elimination. In the other cases the most important fragmentation is NH₂˙ loss, followed by CO elimination.     

Rough set approach to multiple criteria classification with imprecise evaluations and assignments

Dominance-based Rough Set Approach (DRSA) has been introduced to deal with multiple criteria classification (also called multiple criteria sorting, or ordinal classification with monotonicity constraints), where assignments of objects may be inconsistent with respect to dominance principle. In this paper, we consider an extension of DRSA to the context of imprecise evaluations of objects on condition criteria and imprecise assignments of objects to decision classes. The imprecisions are given in the form of intervals of possible values. In order to solve the problem, we reformulate the dominance principle and introduce second-order rough approximations. The presented methodology preserves well-known properties of rough approximations, such as rough inclusion, complementarity, identity of boundaries and precisiation. Moreover, the meaning of the precisiation property is extended to the considered case. The paper presents also a way to reduce decision tables and to induce decision rules from rough approximations.     

Soret effects on the onset of convection in rotating porous layers via the “auxiliary system method”

The onset of convection in a ternary horizontal porous fluid layer, heated from below and salted from above and below, in the presence of Soret thermo-diffusive effects (in the Darcy–Boussinesq scheme) is investigated. Via a new approach (“auxiliary system method”), it is shown that do not exist subcritical instabilities and that the global nonlinear stability is guaranteed by the linear stability. The Soret stabilizing-destabilizing effects, via algebraic conditions in closed forms, are obtained also discovering symmetries and skew-symmetries hidden in the Darcy–Boussinesq equations.     

A class of piecewise interpolating functions based on barycentric coordinates

Piecewise interpolation methods, as spline or Hermite cubic interpolation methods, define the interpolant function by means of polynomial pieces and ensure that some regularity conditions are guaranteed at the break-points. In this work, we propose a novel class of piecewise interpolating functions whose expression depends on the barycentric coordinates and a suitable weight function. The underlying idea is to specialize to the 1D settings some aspects of techniques widely used in multi-dimensional interpolation, namely Shepard’s, barycentric and triangle-based blending methods. We show the properties of convergence for the interpolating functions and discuss how, in some cases, the properties of regularity that characterize the weight function are reflected on the interpolant function. Numerical experiments, applied to some case studies and real scenarios, show the benefit of our method compared to other interpolant models.     

A two immiscible liquids penetration model for surface-driven capillary flows

This is a mathematical and numerical study of liquid dynamics in a horizontal capillary. We present a two-liquids model which takes into account the effects of real phenomena like the outside flow dynamics. Moreover, we report on results obtained by an adaptive numerical method. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Molecular organization and syn ? anti conformational equilibria in ethane-bridged bis(zinc porphyrin) floating films at the air-water interface

The behavior of the symmetrical ethane-bridged bis(Zn porphyrin) (1) has been investigated at the air-water interface. The molecular organization of floating films of pure 1 and its mixture with amphiphilic substances, such as arachidic acid and n-octadecylamine, was inspected by means of surface pressure-area isotherms, Brewster angle microscopy and reflection spectroscopy in the UV-Vis region. The overall results suggest the presence in all cases of mainly the anti conformer of 1 even when the dimer was spread on pure water, through the ligation of water molecules to the zinc atoms in the axial positions. It was also demonstrated for the first time that the syn-to-anti conformational transition of the porphyrin dimer can be accelerated by the ligation of suitable amphiphiles even at the liquid-air interface. In particular, it is noted that n-octadecylamine, and arachidic acid (to a lesser extent), added to the system as amphiphiles, drive the syn ? anti equilibrium of 1 towards the anti form through the axial ligation of the amino or carboxylate group to the zinc atoms.