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21.
Maria D. Manrique-Juarez Dr. Fabrice Mathieu Dr. Victoria Shalabaeva Dr. Jean Cacheux Sylvain Rat Dr. Liviu Nicu Dr. Thierry Leïchlé Dr. Lionel Salmon Dr. Gábor Molnár Dr. Azzedine Bousseksou 《Angewandte Chemie (International ed. in English)》2017,56(28):8074-8078
We report on a bistable MEMS device actuated by spin-crossover molecules. The device consists of a freestanding silicon microcantilever with an integrated piezoresistive detection system, which was coated with a 140 nm thick film of the [Fe(HB(tz)3)2] (tz=1,2,4-triazol-1-yl) molecular spin-crossover complex. Switching from the low-spin to the high-spin state of the ferrous ions at 338 K led to a reversible upward bending of the cantilever in agreement with the change in the lattice parameters of the complex. The strong mechanical coupling was also evidenced by the decrease of approximately 66 Hz in the resonance frequency in the high-spin state as well as by the drop in the quality factor around the spin transition. 相似文献
22.
Loïc Salmon Guillaume Bouvignies Dr. Phineus Markwick Dr. Nils Lakomek Dr. Scott Showalter Dr. Da‐Wei Li Dr. Korvin Walter Christian Griesinger Prof. Rafael Brüschweiler Prof. Martin Blackledge Dr. 《Angewandte Chemie (International ed. in English)》2009,48(23):4154-4157
A robust procedure for the determination of protein‐backbone motions on time scales of pico‐ to milliseconds directly from residual dipolar couplings has been developed that requires no additional scaling relative to external references. The results for ubiquitin (blue in graph: experimental N? HN order parameters) correspond closely to the amplitude, nature, and distribution of motion found in a 400 ns molecular‐dynamics trajectory of ubiquitin (red).
23.
Tomás Moya-Pizarro Roger Salmon Léopold Fournes Gilles Le Flem Barbara Wanklyn Paul Hagenmuller 《Journal of solid state chemistry》1984,53(3):387-397
Single crystals of the high-temperature form of NaFeP2O7 have been grown by a flux technique. II-NaFeP2O7 crystallizes in the monoclinic space group with lattice parameters: a = 7.298(2) Å, b = 7.874(2) Å, c = 9.536(3) Å, β = 111.85(2)°. The structure refined from 1481 independent reflections leads to R = 0.044 and confirms the work previously published by M. Gabelica-Robert, M. Goreaud, P. Labbe, and B. Raveau (J. Solid State Chem.45, 389, 1982). Magnetic Mössbauer resonance studies have shown the existence of antiferromagnetic ordering with a weak ferromagnetic component below 30 K. The FeO bond is markedly ionic in character due to the highly polarizing power of phosphorus in tetrahedral site. 相似文献
24.
G. Méjean J. Kasparian J. Yu S. Frey E. Salmon R. Ackermann J.P. Wolf L. Bergé S. Skupin 《Applied physics. B, Lasers and optics》2006,82(3):341-345
We report new experimental and numerical results on supercontinuum generation at ultraviolet/visible wavelengths produced
by the propagation of infrared femtosecond laser pulses in air. Spectral broadening is shown to similarly affect single filaments
over laboratory distance scales, as well as broad beams over long-range propagation distances. Numerical simulations display
evidence of the crucial role of third harmonic generation in the build-up of UV–visible wavelengths, by comparison with current
single-envelope models including chromatic dispersion and self-steepening.
PACS 52.38.Hb; 42.65.Tg; 42.65.Jx; 42.68.Ay 相似文献
25.
A range is defined for the effects of parity dependence in heavy-ion scattering. This range is shown to be related to the terms of the antisymmetrizer which exchange the largest number of nucleons between both nuclei. A simple formula, derived in the two-center harmonic oscillator model, gives an upper bound for the parity range. A criterion is proposed to determine whether a parity-dependent real part should be used in heavy-ion optical potentials. The most important parity effects should be expected in scattering between nuclei with neighbouring masses. 相似文献
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The first part of this paper deals with the Frey-Salmon irreversibility hypothesis, the kinetic equation that is deduced therefrom, and the comparison with experiment for the viscosity and thermal conductivity coefficients. The relaxation time which has been introduced is the average value of the duration of a collision. The second part deals with a new irreversibility hypothesis which leads to a kinetic equation of the same form as the first but in which the relaxation time is deduced from the interparticle potential. 相似文献
29.
Paolo Salmon 《Milan Journal of Mathematics》1980,50(1):135-140
30.
Salmon L Thuéry P Asfari Z Ephritikhine M 《Dalton transactions (Cambridge, England : 2003)》2006,(24):3006-3014
Reactions of UCl4 with 25,27-dimethoxy-5,11,17,23-tetra-tert-butylcalix[4]arene (H2Me2calix) in THF or pyridine at 80 degrees C gave [UCl2(Me2calix)L2] [L = THF (1) or pyridine (2)]. Similar treatment of U(acac)(4) (acac = MeCOCHCOMe) with H2Me2calix in THF or pyridine afforded [U(acac)2(Me2calix)] (3). The bis-calixarene compound [U(Me2calix)(H2calix)] (4) was obtained by reaction of U(OTf)4 or U(OTf)3 with H2Me2calix in pyridine at 110 degrees C. Treatment of UCl4 with H2Me2calix in pyridine at 110 degrees C gave [Mepy][UCl2(Hcalix)(py)2] (5) resulting from demethylation and acid cleavage of the methoxy groups of the calixarene ligand of 2. Adventitious traces of air were responsible for the formation of [Hpy][Mepy]4[{UCl(calix)}3(mu3-O)][UCl6] (6) during the reaction of UCl4 and H2Me2calix, and of [{U(Me2calix)(mu3-O)LiCl(THF)}2] (7) during the reaction of 2 with tBuLi. The X-ray crystal structures of 1.2THF, 2.2py, 3.0.25L (L = THF and py), 4.2py, 5, 6.3py and 7.THF have been determined. 相似文献