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81.
Mabrouk Khelifi Imen Mkaouar Faouzi Hlel Abdelhamid Ben Salah Ridha Zouari 《Ionics》2010,16(8):709-715
The crystal structure of (C5N2H7)4.HBi2Cl11 has been determined at room temperature by single crystal X-ray diffraction. The compound crystallizes in the triclinic system with Pī space group. The crystal structure consists of two asymmetric inequivalent molecules of 4-aminopyridinium and anionic HBi2Cl11 chains. The HBi2Cl11 anionic chains stacked along the a-axis are formed with Bi2Cl11 dimers connected to each other via hydrogen atoms. The crystal packing is stabilized with N–H...Cl hydrogen bonds connecting aminopyridinium units to the HBi2Cl11 anionic chains. The title compound exhibits an order–disorder phase transition at 338 K. The AC electrical conductivity properties of (C5N2H7)4.HBi2Cl11 compound have been investigated by means of impedance spectroscopy measurements over wide ranges of frequencies and temperatures, 200 Hz to 5 MHz and 303 to 418 K, respectively. Detailed analysis of the impedance spectrum suggests that the electrical properties of the material are strongly temperature dependent. The frequency-dependent conductivity data were fitted in the Jonscher's law: $ \sigma \left( \omega \right) = \sigma (0) + A{\omega^n} $ . The nature of variation of DC conductivity suggests Arrhenius type of electrical conductivity. 相似文献
82.
In this paper, we study the k-quasi-M-hyponormal operator and mainly prove that if T is a k-quasi-M-hyponormal operator, then \(\sigma _{ja}(T)\backslash \{0\}=\sigma _{a}(T)\backslash \{0\}\), and the spectrum is continuous on the class of all k-quasi-M-hyponormal operators; let \(d_{AB}\in B(B(H))\) denote either the generalized derivation \(\delta _{AB}= L_{A}-R_{B}\) or the elementary operator \(\Delta _{AB} =L_{A}R_{B}- I\), we show that if A and \(B^{*}\) are k-quasi-M-hyponormal operators, then \(d_{AB}\) is polaroid and generalized Weyl’s theorem holds for \(f(d_{AB})\), where f is an analytic function on \(\sigma (d_{AB})\) and f is not constant on each connected component of the open set U containing \(\sigma (d_{AB})\). In additon, we discuss the hyperinvariant subspace problem for k-quasi-M-hyponormal operators. 相似文献
83.
84.
K2Ca2(SO4)3 microcrystalline pure, doped with Eu, Tb and co-doped with Eu, Tb was prepared by solid-state diffusion method. Nanoparticles of these phosphors were also prepared by the chemical co-precipitation method. The formation of the compounds was confirmed by XRD. The particle size was calculated by broadening of the XRD peaks using Scherrer's formula. The particle size of nanocrystalline powder material was approximately found to be around 20 nm. Thermoluminescence and photoluminescence were studied to see the effect of co-doping and particle size. Tb3+ co-doping decreases the intensity in the Eu2+ doped phosphor due to the energy transfer and multiple de-excitations through various radiative and non-radiative processes. The sensitivity of K2Ca2(SO4)3:Eu,Tb microcrystalline phosphor was around 15 times more than LiF-TLD 100 and 7 times more than CaSO4:Dy. A high temperature peak (615 K) was observed in case of the nanoparticles, which was attributed to a particle size induced phase transition. This was confirmed by differential scanning calormetry measurements. The decrease in the sensitivity in case of nanoparticles is attributed to the particle size effect i.e. volume to surface ratio. Theoretical analysis of the glow curves was done by glow curve convolution deconvolution method to calculate trapping parameters of various peaks. 相似文献
85.
Salah Eddine Ennadifi 《Physics of Particles and Nuclei Letters》2013,10(3):201-204
Motivated by the new physics beyond the Standard Model through the scale at which neutrino mass has origin, we investigate its possible manifestation at low energy within the corresponding propagation of the energetic neutrino. Then, we consider the SN1987A and base on the recorded neutrino data to explore the scale range of the new physics. 相似文献
86.
The double salt hydrate SrCd2Cl6?·?8H2O undergoes a phase transition at T?=?318?K (phase I?–?(T?=?318)?→phase II). The structural characteristics, Raman scattering and dielectric measurements have been investigated. Phase II exhibits monoclinic symmetry (a?=?17.102(6), b?=?21.716(9), c?=?8.582(5)?Å and β?=?91.58(13)°). 相似文献
87.
We study the dynamical invariant for dissipative three coupled oscillators mainly from the quantum mechanical point of view. It is known that there are many advantages of the invariant quantity in elucidating mechanical properties of the system. We use such a property of the invariant operator in quantizing the system in this work. To this end, we first transform the invariant operator to a simple one by using a unitary operator in order that we can easily manage it. The invariant operator is further simplified through its diagonalization via three-dimensional rotations parameterized by three Euler angles. The coupling terms in the quantum invariant are eventually eliminated thanks to such a diagonalization. As a consequence, transformed quantum invariant is represented in terms of three independent simple harmonic oscillators which have unit masses. Starting from the wave functions in the transformed system, we have derived the full wave functions in the original system with the help of the unitary operators. 相似文献
88.
Jaudet C Vignolles D Audouard A Levallois J LeBoeuf D Doiron-Leyraud N Vignolle B Nardone M Zitouni A Liang R Bonn DA Hardy WN Taillefer L Proust C 《Physical review letters》2008,100(18):187005
The de Haas-van Alphen effect was observed in the underdoped cuprate YBa2Cu3O6.5 via a torque technique in pulsed magnetic fields up to 59 T. Above a field of approximately 30 T the magnetization exhibits clear quantum oscillations with a single frequency of 540 T and a cyclotron mass of 1.76 times the free electron mass, in excellent agreement with previously observed Shubnikov-de Haas oscillations. The oscillations obey the standard Lifshitz-Kosevich formula of Fermi-liquid theory. This thermodynamic observation of quantum oscillations confirms the existence of a well-defined, closed, and coherent, Fermi surface in the pseudogap phase of cuprates. 相似文献
89.
90.
Nonlinear Dynamics - Quantum features of time-dependent molecular interactions are investigated by introducing a time-varying Hamiltonian that involves a generalized non-central potential.... 相似文献