Synthesis,characterization of V2O5 nanoparticles and determination of catalase mimetic activity by new colorimetric method

Journal of Thermal Analysis and Calorimetry - This paper deals with an advanced colorimetric method used to determine the catalase mimetic activity of V2O5 nanoparticles by measuring the decrease...     

Influence of the magnetic field on merging flow of the Powell-Eyring fluids: an exact solution

In this article, the merging flow of the stagnation point and the stretching (or shrinking) flows for the Powell-Eyring fluid (one of the non-Newtonian fluids) in the presence of magnetic field is formulated and analyzed mathematically. An analytical solution was developed on the basis of the homotopy analysis method. The effect of the Hartmann number on fluid-velocity and skin-friction is examined. It is observed that the intensive magnetic field reduces the growth of the reverse/secondary flow which is generated after the mixing of the stagnation-point and shrinking-sheet flows. The magnetic force dominates on the viscous force for stretching as well as for shrinking flows. Furthermore, the magnetic force intensifies the axial velocity of the fluids (the Newtonian as well as the Powell-Eyring fluids) but it decays the transverse-velocity of the fluids. Present results are validated with the existing results for the Newtonian fluids and found comparable with negligible errors.     

Application of the green analytical procedure index to the simultaneous analysis of co-formulated tinidazole and ciprofloxacin in pure form,tablet dosage form,and human plasma using an environmentally friendly micellar high-performance thin-layer chromatographic technology

JPC – Journal of Planar Chromatography – Modern TLC - In individuals with chronic refractory pouchitis and other gastrointestinal disorders, the combination of ciprofloxacin (CIP) and...     

Facile,single-pot preparation of nanoporous SiO2 particles (carrier) with AgNPs at core and crust for controlled disinfectant release

This study demonstrates a novel, facile and one-pot approach to synthesize silica nanoparticles with silver at core and crust (SiNP-AgCC). A modified Stöber method was used to make SiNP-AgCC. A significant reduction in the size of SiO₂ nanoparticles was seen, with 2–5 nm AgNPs being uniformly distributed on the surface and 10–20 nm AgNPs in the center. A typical mesoporous SiO₂ particle (SiNP) produced using the Stöber method was transformed to nanoporous SiO₂ by this modified Stöber method. Nanoporous SiO₂ particles with silver in the center are advantageous for slow and consistent Ag⁺ release, which was confirmed by Ag⁺ ion release test. Antibacterial activities of the samples were tested to evaluate the disinfection performance of the samples on gram-negative bacteria (Escherichia coli) using disk diffusion and the LB-agar method. SiNP-AgCC showed prolonged silver release for more than 20 days and improved antibacterial properties even after five days of incubation.     

Ixoroid: a new triterpenoid from the flowers of Ixora coccinea

A new natural terpenoid, ixoroid (1), was isolated from the flower of Ixora coccinea, along with the known constituents stigmast-5-en-3-O-beta-D-glucoside (2), 5-O-caffeoylquinic acid (3) and D-mannitol (4). The structure of ixoroid was elucidated on the basis of extensive 1D- and 2D-NMR studies and mass spectrometry as 21,23-epoxy-tirucall-7-en-3beta-ol (1).     

Enantioselective total synthesis of (+)-gliocladine C: convergent construction of cyclotryptamine-fused polyoxopiperazines and a general approach for preparing epidithiodioxopiperazines from trioxopiperazine precursors

A concise second-generation total synthesis of the fungal-derived alkaloid (+)-gliocladin C (11) in 10 steps and 11% overall yield from isatin is reported. In addition, the epipolythiodioxopiperazine (ETP) natural product (+)-gliocladine C (6) has been prepared in six steps and 29% yield from the di-(tert-butoxycarbonyl) precursor of 11. The total synthesis of 6 constitutes the first total synthesis of an ETP natural product containing a hydroxyl substituent adjacent to a quaternary carbon stereocenter in the pyrrolidine ring.