复合式反应破片对柴油油箱的毁伤效应试验研究

 设计并制备了两种不同配方的新型复合式反应破片,并进行了该反应破片对装有柴油油箱的毁伤试验。复合式反应破片由壳体、裸反应破片、顶盖组成。裸反应破片采用铝粉和聚四氟乙烯、钛粉和聚四氟乙烯两种材料配方真空高温烧结制成。试验利用12.7 mm弹道枪发射复合式反应破片,并用高速摄影仪记录破片对油箱的毁伤过程。两种配方的复合式反应破片均能穿透6 mm厚油箱壁,并具有明显的引燃效果。试验结果表明,与惰性破片相比,复合式反应破片兼有侵彻能力和引燃纵火能力。     

Modelling Moran Process with Network Dynamics for the Evolution of Cooperation

We introduce a simple model based on the Moran process with network dynamics. Using pair approximation, the cooperation frequencies at equilibrium states are deduced for general interactions. Three usual social dilemmas are discussed in the framework of our model. It is found that they all have a phase transition at the same value of cost-to-benefit ratio. For the prisoner＇s dilemma game, notably it is exactly the simple rule reported in the literature [Nature 441 （2006） 502]. In our model, the simple rule results from the parent-offspring link. Thus the basic mechanism for cooperation enhancement in network reciprocity is in line with the Hamilton rule of kin selection. Our simulations verify the analysis obtained from pair approximation.     

周期性微结构硅基表面辐射特性数值研究

本文通过时域有限差分法求解 M-well 方程组,分析微结构表面与入射辐射间的相互作用,结合近场 - 远场辐射转换模型,获得了尺寸、温度和入射波长等参数对表面双向反射分布函数的影响规律,研究结果为热辐射的光谱和方向调控技术提供了数值基础.     

微波消解-电感耦合等离子体质谱测定大气颗粒物中痕量稀土元素

研究了电感耦合等离子体质谱（ICP-MS）测定大气颗粒物中痕量稀土元素（REEs）的分析方法。在微波条件下,采用HNO3 ＋ H2O2（3 ＋ 1）混合介质能快速而有效地分解颗粒物样品。详细讨论了测定稀土元素的质谱干扰。通过分析不同粒径颗粒物中稀土元素的含量,初步探讨了大气颗粒物中稀土元素的分布规律。结果表明：颗粒物试样的粒径越小,稀土元素的含量越高。分析方法的检出限为0．7～2．8pg／mL,用于大气颗粒物国际标样（SRM 1648）中稀土元素分析,结果与推荐值有良好的一致性。     

激发态的相关基函数理论

本文根据相关基函数理论建立了电子相互作用体系的激发态理论。在Chakravarty-Woo方程的基础上,利用泛函展开和卷积近似得到了单粒子激发而引起的电子密度分布和关联函数变化的自洽方程。由多体理论的激发能的定义出发,求得了导电聚合物(考虑了电子相互作用)的能隙公式,在已知的参数下,给出了与实验相符的结果。 关键词：     

关于铁磁链方程的反散射解法的严格证明和验证

本文对于通常证明中引入的造成困难的因子λ^-1,证明不仅应当略去,而且在略去后,同样可以得到与Takhtajan方程等价的结果,只在λ=0处有预料到的修正。同时,给出了反散射解法的解满足铁磁链方程的普遍验证。 关键词：     

D301R树脂吸附-解吸钼的行为研究

对D301R型阴离子交换树脂吸附-解吸钼的条件进行了研究，采用静态法试验了pH值、钼的浓度等因素对该树脂吸附钼的影响；采用动态法讨论了该树脂对钼的饱和吸附量、解吸剂及其浓度对解吸钼的影响。结果表明在pH2．5，钼的浓度为20g/L时吸附效果最好，树脂对钼的饱和吸附量为1020mg／g，而采用150g/L NaOH溶液解吸钼效果最佳。     

Thermokinetics on the reaction of formation of Dy[(C_5H_8NS_2)_3(C_(12)H_8N_2)]

The enthalpy change of formation of the reaction of hydrous dysprosium chloride with ammonium pyrrolidinedithiocarbamate (APDC) and 1,10-phenanthroline (o-phen·H2O) in absolute ethanol at 298.15 K has been determined as (-16.12±0.05) kJ·mol-1 by a microcalor-meter. Thermodynamic parameters (the activation enthalpy, the activation entropy and the activation free energy), rate constant and kinetics parameters (the apparent activation energy, the pre-exponential constant and the reaction order) of the reaction have also been calculated. The enthalpy change of the solid-phase reaction at 298.15 K has been obtained as (53.59±0.29) kJ·mol-1 by a thermochemistry cycle. The values of the enthalpy change of formation both in liquid-phase and solid-phase reaction indicated that the complex could only be synthesized in liquid-phase reaction.     

相转移催化合成N,N′-二(3,5-二甲基吡唑)烷

近年来,多齿含氮配体在金属有机配合物的合成和研究中日益受到重视,不仅用在高氧化态、缺电子中心的高价过渡金属有机配合物上,而且已开始在低氧化态、富电子中心的低价过渡金属有机配合物上应用,其中一个重要原因是自然界里许多的金属酶普遍含有以氮为配位原子的配体。因此,本文试图研究N,N′-二(3,5-二甲基吡唑)烷的合成。70年代初,Trofimenko 用3,5-二甲基     

Application to the Determination of Ecdysterone in Traditional Chinese Medicine Loulu by High Performance Liquid Chromatography Coupled with Flow Injection Micro-column Pre-separation Technique

Loulu is a traditional Chinese medicine which has obvious activities in anti-peroxidantion, anti-atherosclofosis and immunopotentintion. The pharmacological activities of ecdysterone in Loulu are in good agreement with the curative effects of Loulu. Therefore, the quantitative determination of ecdysterone in Loulu will be helpful in further researching the medicinal mechanism. The components of Loulu are very complex. Many overlapping peaks from interference will be present in chromatograms if the sample is directly determined by HPLC. So it is very important to search for a simple, rapid and effective sample pretreatment technique. Flow injection analysis, as an effective sample treatment technique, has applied in many fields. In this work, a flow injection micro-column system for the sample pretreatment coupling HPLC was proposed. Ecdysterone in.Loulu was pre-separated with the designed system, and then determined by HPLC. The separation performance, the influence factors of the pre-separation and the operation parameters of the HPLC have investigated in detail. The experimental results demonstrated that the present system is simple, efficient and no pollution. The method was applied to the determination of ecdysterone in real samples.