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用分步激发方法及偏振光技术,测定了锶的(5p3/2ns)1(n=13-21)及(5p3/2 nd)3(n=13-24)各自电离谱,在低于5p1/2电离限的(5p3/2ns)1态的实电子激发谱中,出现对应于(5p1/2ns)1及(5p1/2nd)1的畸变峰,畸变峰也出现于(5p3/2nd)3的实电子激发谱中。这说明(5pjns)(5pjnd)自电离系列间存在相互作用。
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SUCHANDRA BANDYOPADHYAY KAKALI SEN SHARMISTHA DUTTA CHOUDHURY SAMITA BASU 《Molecular physics》2013,111(8):1079-1084
Photoinduced electron transfer reactions in solution produce two primary geminate radical ion pairs: contact ion pair or exciplex and solvent-separated ion pair. The magnetodynamics of radical ion pairs involves suppression of the spin-evolution between singlet and triplet states of a fraction of solvent-separated ion pairs, the partners of which undergo prior diffusion to attain the distance where exchange interaction is negligible, in the presence of an external low magnetic field of the order of the hyperfine interactions present in the system. This results in an increase in geminate recombination of the singlet solvent-separated ion pairs and enhancement in exciplex luminescence since the precursor radical ion pair is singlet. Although seemingly magnetodynamics is a diffusion-controlled phenomenon that should depend mainly on the dielectric constant of the medium (keeping viscosity almost constant), it is not true for all the exciplex systems since the nature of the magnetic field effect versus medium dielectric curves differ from each other in peak positions, peak heights and onset points. To investigate this differential nature, magnetic field effects among exciplex systems consisting of different derivatives of carbazole as electron donors are compared with a universal acceptor, 1,4-dicyano-benzene, with the pyrene—N,N-dimethylaniline exciplex system as reference. It was found that, apart from the solvent dielectric, the exciplex energy and the bulk effect of the steric constraints present on either donor or acceptor site, regulating the optimum inter-radical distance in the initially formed radical ion pair, are the key factors in controlling the magnetodynamic behaviour. 相似文献
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We investigate phase-locked solutions of a continuum field of nonlocally coupled identical phase oscillators with distance-dependent
propagation delays. Equilibrium relations for both synchronous and travelling wave solutions in the parameter space characterizing
the nonlocality and time delay are delineated. For the synchronous states a comprehensive stability diagram is presented that
provides a heuristic synchronization condition as well as an analytic relation for the marginal stability curve. The relation
yields simple stability expressions in the limiting cases of local and global coupling of phase oscillators. 相似文献
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A new kind of regular orthogroups, namely, the LR-normal orthogroups is introduced and investigated. In particular, we will introduce the gearing techniques for fitting semigroup components on a semilattice in the construction of LR-normal orthogroups. 相似文献
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用多步激发的方法,将Sr原子从基态5s~2经价态4α~(-2)激发至(4d_(3/2)np,n_f)J=1和(4d_(5/2)np,nf)J=1自电离系列,观察其在外电场0~5kV/cm内的光谱.对所观察到的n=12,13,14附近的斯塔克谱图进行了分析与讨论. 相似文献
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A P KULKARNI S JAIN M P KAMATH A S JOSHI P A NAIK P D GUPTA K ANNAPURNA A K MANDAL B KARMAKAR R SEN 《Pramana》2014,82(1):159-163
High energy, high power (HEHP) Nd:glass laser systems are used for inertial confinement fusion and equation of state (EOS) studies of materials at high temperature and pressure. A program has been undertaken for the indigenous development of Nd-doped phosphate laser glass rods and discs for HEHP lasers. In this paper, we report the characterization of the Nd-doped phosphate laser glass rods produced under this program and compare the indigenously developed laser glass to LHG-8 laser glass of M/s Hoya, Japan. We experimentally measured the values of the stimulated emission cross-section (σ) and coefficient of intensity-dependent refractive index (n 2) and hence the figure of merit F = σ / n2 of the indigenous phosphate laser glass rods. This value is found comparable to the reported value of identically doped Nd:glass rods. 相似文献
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