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181.
The methods applied for natural uranium, radium and thorium determinations in water samples are shortly presented together with some preliminary results. The measurements will be continued as part of an extended program of ecological study of the Danube Delta area.  相似文献   
182.
The rate of nucleophilic substitution at the phosphorus centre of dialkyl methylphosphonates by methoxide and ethoxide has been studied to investigate the possible involvement of hexacoordinated phosphorus species in this reaction. For alkoxide concentrations less than ca. 1.5 M the rate increases with the square of alkoxide concentration. However, consideration of the activity of the alkoxides, represented by an appropriate acidity function, reveals that only one equivalent of alkoxide is involved in the rate-determining step. Thus, there is no requirement to invoke the intermediacy of a hexacoordinated species in the reaction pathway. © John Wiley & Sons, Inc.  相似文献   
183.
Physical Engineering Institute, Moscow. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 34, No. 5, pp. 565–574, May, 1991.  相似文献   
184.
185.
Electron energy distribution functions (eedf) in CO2 laser discharge (He—CO2—N2—CO mixture) have been calculated by solving the Boltzmann equation in the presence of given concentrations of excited (vibrational and electronic) states. The results show a well structured eedf as a result of second kind collisions coming from metastable electronic states of N2 and He as well as a strong dependence of rate coefficients for CO2 dissociation and for the ionization of the different species.  相似文献   
186.
In this paper the explicit form of such systems of conservation laws, which imply an additional conservation law, is determined. It is shown that there are many classes of such systems besides the symmetric conservative ones. From the point of view of phenomenological thermodynamics, this result can be interpreted as a sort of integration of the constraints imposed by the second law of thermodynamics.  相似文献   
187.
188.
The management of voice disorders may follow one of four approaches: surgical, pharmacological, technical aid, and/or voice therapy. The latter approach offers a wide variety of techniques, each based on certain theoretical beliefs. One of these techniques is the Smith Accent Method. The principles and goals of the Accent Method are presented. The results of its application are discussed. This technique proved effective for cases of functional voice disorders, vocal nodules, and some degrees of vocal fold paralysis.  相似文献   
189.
    
From flash photolysis data of benzil and 2,2′-dichlorobenzil, the role of conformeric triplets in the formation of hydrogen adduct radicals has been discussed. The planar relaxed triplet absorbing at 470 nm is less efficient in forming a hydrogen adduct radical as compared to its puckered conformeric partner. Among the hydrogen donors, triethyl amine and isopropanol, the former is more efficient in converting puckered triplets and less efficient in the case of planar conformers. Absorptions of radicals and radical anions of 2,2′-dichlorobenzil appear at 355 nm and 460 nm respectively. These are blue-shifted as compared to those of the parent compound benzil appearing at 370 nm and 540 nm, respectively. This blue-shift has been discussed in terms of steric hindrance due to ortho-substitution.  相似文献   
190.
Branch of Theoretical Problems, USSR Academy of Sciences, Translated from Funktsional'nyi Analiz i Ego Prilozheniya, Vol. 26, No. 1, pp. 89–90, January–March, 1992.  相似文献   
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