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991.
Characterization of autocatalytic decomposition reactions is important
for the safe handling and storage of energetic materials. Isothermal differential
scanning calorimetry (DSC) has been widely used to detect autocatalytic decomposition
of energetic materials. However, isothermal DSC tests are time consuming and
the choice of experimental temperature is crucial. This paper shows that an
automatic pressure tracking calorimeter (APTAC) can be a reliable and efficient
screening tool for the identification of autocatalytic decomposition behavior
of energetic materials.
Hydroxylamine nitrate (HAN) is an important
member of the hydroxylamine family. High concentrations of HAN are used as
liquid propellants, and low concentrations of HAN are used primarily in the
nuclear industry for decontamination of equipment. Because of its instability
and autocatalytic decomposition behavior, HAN has been involved in several
incidents. 相似文献
992.
The kinetics of reactions occurring at the gas-exposed surfaces of charged mixed ionic electronic conductors (MIECs) are examined
from theoretical first principles. Analysis based on the classical electrochemical potential-transition state theory model
reveals that the nature of the reactions is electrochemical in general. However, the influence of the surface potential on
the reaction rate is opposite for adsorption and incorporation reactions. Two-dimensional finite volume models of an MIEC
as working electrode in a half-cell configuration are presented. The results for a simple, two-step reduction process show
that the effect of the surface potential on the rate of reactions is minimal for incorporation-limited reactions but more
influential for adsorption-limited reactions.
An erratum to this article is available at . 相似文献
993.
994.
L. M. Gornostaev E. A. Bocharova N. V. Geets 《Russian Journal of Organic Chemistry》2006,42(9):1289-1292
1,3-Dichloro-2-nitrosobenzene and 1,3-dibromo-5-fluoro-2-nitrosobenzene reacted with amines to give previously unknown nitrosobenzene derivatives containing alkylamino groups in positions 3 and 5. 相似文献
995.
M. R. Darafsheh N. S. Karamzadeh A. R. Moghaddamfar 《Journal of Applied Mathematics and Computing》2006,21(1-2):437-450
IfG is a finite group, we define its prime graph Г(G), as follows: its vertices are the primes dividing the order ofG and two verticesp, q are joined by an edge, if there is an element inG of orderpq. We denote the set of all the connected components of the graph Г(G) by T(G)= {πi(G), fori = 1,2, …,t(G)}, where t(G) is the number of connected components of Г(G). We also denote by π(n) the set of all primes dividingn, wheren is a natural number. Then ¦G¦ can be expressed as a product of m1, m2, …, mt(G), where mi’s are positive integers with π(mi) = πi. Thesem i ’s are called the order components ofG. LetOC(G) := {m 1,m 2, …,m t (G)} be the set of order components ofG. In this paper we prove that, if G is a finite group andOC(G) =OC(M), where M is a finite simple group witht(M) ≥ 2, thenG is neither Frobenius nor 2-Frobenius. 相似文献
996.
Rogério S. Mol 《Bulletin of the Brazilian Mathematical Society》2006,37(1):29-48
Résumé. Nous définissons des classes polaires associées à une distribution holomorphe singulière de sous-espaces tangents d’une variété
projective lisse. Nous prouvons que ces classes polaires peuvent être calculées en fonction des classes de Chern-Mather du
faisceau tangent de la distribution et réciproquement. Nous utilisons leurs degrés pour borner les degrés de certaines classes
polaires associés à une variété invariante.
*Ce travail a été soutenu par l’Accord de Coopération France-Brésil (CNRS/CNPq) et par la Fondation CAPES-Brésil. 相似文献
997.
998.
The magnetic properties of annealed Fe-Pt multilayer thin films with a broad composition range were investigated in order to identify the effects of composition and annealing temperature on the achievable coercive field, and to identify its maximum at low processing temperatures. Two types of multilayer systems were deposited as materials libraries to vary the composition from Fe20Pt80 to Fe75Pt25. The first type of multilayer was comprised of alternating opposing wedges, whereas the second type consisted of repeated uniform Fe and Pt layers interspersed periodically with Fe wedge layers. It was found that coercive fields μ0HC > 0.7 T can be achieved at an annealing temperature of about 300 °C (60 min) for both types of multilayers as long as the composition is close to 50:50. Higher annealing temperatures are needed for films, which deviate from this composition. Increasing the annealing temperature up to 700 °C leads to increased coercivity values. Multilayers with additional Fe layers showed increased remanence but reduced coercive fields. 相似文献
999.
Electron beam processing of poly(ethylene terephthalate) (PET) films is found to promote significant changes in the melting heat, intrinsic viscosity and polymer film-liquid (water, isooctane and toluene) boundary surface tension. These properties are featured with several maximums depending on the absorbed dose and correlating with the modification of PET surface functionality. Studies using adsorption of acid-base indicators and IR-spectroscopy revealed that the increase of PET surface hydrophilicity is determined by the oxidation of methylene and methyne groups. Electron beam treatment of PET films on the surface of N-vinylpyrrolidone aqueous solution provided graft copolymerization with this comonomer at optimum process parameters (energy 700 keV, current 1 mA, absorbed dose 50 kGy). 相似文献
1000.
We discuss the spectral lineshapes of reflectance and modulated reflectance (MR) measurements on optoelectronic device structures such as epi-layers, quantum wells (QWs), vertical-cavity surface emitting-lasers (VCSELs) and resonant-cavity light-emitting diodes (RCLEDs). We consider the various methods for the extraction of built-in electric fields and band-gap energies from Franz-Keldysh oscillations (FKO), using the example of a tensilely strained InGaAs QW system, whose InGaAsP barriers yield strong FKO. We describe how critical point transition energies can be easily obtained by eye from Kramers-Kronig (KK) transforms of low field or QW modulation spectra, using the example of the modulated transmittance spectra of dilute-nitrogen InGaAsN p-i-n structures. We also discuss how the ordinary reflectivity spectrum, usually acquired at the same time as the MR signal, may also be exploited to extract layer thicknesses and compositions, and information about the active QW absorption spectrum in VCSEL and RCLED structures. 相似文献