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991.
Wenjie Sui Shunqin Li Xiaodan Zhou Zishan Dou Rui Liu Tao Wu Hongyu Jia Guanhua Wang Min Zhang 《Molecules (Basel, Switzerland)》2021,26(13)
In this work, steam explosion (SE) was exploited as a potential hydrothermal-humification process of vegetable wastes to deconstruct their structure and accelerate their decomposition to prepare humified substances. Results indicated that the SE process led to the removal of hemicellulose, re-condensation of lignin, degradation of the cellulosic amorphous region, and the enhancement of thermal stability of broccoli wastes, which provided transformable substrates and a thermal-acidic reaction environment for humification. After SE treatment, total humic substances (HS), humic acids (HAs), and fulvic acids (FAs) contents of broccoli samples accounted for up to 198.3 g/kg, 42.3 g/kg, and 166.6 g/kg, and their purification were also facilitated. With the increment of SE severity, structural characteristics of HAs presented the loss of aliphatic compounds, carbohydrates, and carboxylic acids and the enrichment of aromatic structures and N-containing groups. Lignin substructures were proved to be the predominant aromatic structures and gluconoxylans were the main carbohydrates associated with lignin in HAs, both of their signals were enhanced by SE. Above results suggested that SE could promote the decomposition of easily biodegradable matters and further polycondensation, aromatization, and nitrogen-fixation reactions during humification, which were conducive to the formation of HAs. 相似文献
992.
The lubrication layer plays a governing role in predicting the pumpability of fresh concrete. To determine the effect of measurement methods on the characterization of the rheological properties of the lubrication layer, different measurement systems, including Sliper, tribometer, and the utilization of a mortar rheometer, were employed. The rheological properties and workability of bulk concrete were measured in parallel to investigate the correlation between them and the rheological properties of the lubrication layer. The results show that the measured values of the rheological parameters of the lubrication layer differ due to the systematic deviation between different measurement methods. The results obtained by both tribometer and mortar rheometer were well-correlated, having a linear relationship with the rheological parameters of bulk concrete. The correlation coefficient between results gained with Sliper and rheological parameters of concrete or lubrication layer determined with other methods was not high enough. Addition friction led to the large accidental error and overestimated yield stress obtained with Sliper. The workability of concrete is only suitable for characterizing the rheological properties of bulk concrete. 相似文献
993.
The geometry, electronic structure, and catalytic properties for CO oxidation of Pt atom supported on pri-graphene (PG), Haeckelite (H), and Stone–Wales-defect-graphene are investigated by density functional theory (DFT) calculations. In contrast to a Pt atom on PG, defective graphene, especially the Haeckelite, strongly stabilises the Pt atom and makes it more positive and thus the CO poisoning. At the same time the catalytic activities are as high as the pristine one. Langmuir–Hinshelwood mechanisms are favoured as the starting state and are followed by the Eley–Rideal reaction. The results indicate the benefit of Haeckelite as a substrate for the Pt atom and validate the reactivity of catalysts on the atomic scale with low cost and high activity. 相似文献
994.
Helico-conical beam is attractive for its phase front is nonseparable helical and conical phase function, which produces a spiral intensity distribution occurs at the focal plane. In this letter, the focal properties of cosh-Gaussian beam with helico-conical wavefront were investigated to show that helico-conical phase front does not always produce spiral intensity distribution. On increasing decentered parameters in cosh parts of the beams, the spiral focal pattern evolves into multiple intensity peaks with center main strongest peak. Under condition of higher decentered parameters, the focal spiral curve disappears. In addition, the topological charge also affects the focal pattern considerably. 相似文献
995.
In this paper, a novel curvelet based digital image compression scheme is proposed. Aiming at achieving high compression ratio, the proposed scheme embeds a representative machine learning method, core vector machine (CVM), in the encoding process of the image compression technique. The core vector machine (CVM) has been introduced as an extremely fast classifier which is demonstrably superior to standard support vector machine (SVM) on very large datasets. In this scheme, we appropriately utilize the characteristic of CVM to reduce huge numbers of curvelet coefficients. Compared with image compression algorithms do not use CVM and methods based on wavelet transform, experimental results show that the compression performance of our method gains much improvement in peak-signal-to-noise-ratio (PSNR) and CPU time. Moreover, the algorithm works fairly well for declining block effect at higher compression ratios. 相似文献
996.
In this paper, a highly birefringent index-guiding photonic crystal fiber with low confinement loss is proposed by enlarging the central row of air holes in the structure. By employing the multipole method, properties of this structure, including the effective index, birefringence and confinement loss, are investigated. Simulation results indicate that high birefringence of 1.65 × 10−3 can be reached at the wavelength of 1.55 μm, and a low confinement loss on the order of 10−6 dB/km can be achieved at the same wavelength. Moreover, the impacts of air hole sizes on birefringence and confinement loss are also analyzed in detail. 相似文献
997.
Yoshihiro Fukumoto Koji Ohata Rui Tsukagoshi Keiich Kawanabe Haruhiko Akiyama Toshihiro Mata Misaka Kimura Noriaki Ichihashi 《Physical Therapy Research》2013,16(1):22-27
Objective: To investigate changes in hip and knee muscle strength in patients before and after total hip arthroplasty (THA) in comparison with that in healthy adults. Methods: The study included 21 women who underwent unilateral THA (THA group) and 21 age-matched healthy women (healthy group). Maximal isometric strengths of hip flexors, extensors, and abductors, and knee extensors and flexors were measured before surgery and at 4 weeks and 6 months after surgery. Results: Before surgery, muscle strength on both sides, except for hip flexors on the uninvolved side, was significantly lower in the THA group than the corresponding muscle strength in the healthy group. Up to 6 months after THA, strength of all muscle groups on both sides was significantly improved compared with their preoperative status, although the knee extensor strength on the involved side temporarily worsened at 4 weeks. However, the strength of hip extensors and knee extensors on the involved side, and hip abductors on both sides in the THA group remained below that in the healthy group. Conclusions: Our results suggest that rehabilitation specialists should consider increasing the focus on the uninvolved side and encourage patients to continue strength training beyond 6 months after surgery. 相似文献
998.
Mauro D. Santos Pedro Cunha Rui P. Queirós Liliana G. Fidalgo Ivonne Delgadillo 《高压研究》2013,33(4):452-459
Pressure treatments of 300 and 500?MPa during 15?min were found to change starch–water sorption (adsorption and desorption) isotherms and the hysteresis effect, particularly the 500?MPa. This last treatment shifted the adsorption/desorption isotherms downward, compared with non-treated starch and starch treated at 300?MPa. The observed hysteresis effect decreased with the increase in pressure level in the whole aw range, indicating that adsorption and desorption isotherms became closer. Guggenheim–Anderson–De Boer and Brunauer–Emmett–Teller model parameters Cb, Cg, K and Mm also showed changes caused by pressure, the latter being lower in the pressure-processed samples, thus indicating possible changes on microbial and (bio)chemical stabilities of pressure-processed food products containing starch. 相似文献
999.
Cun Zhu Rui Deng Jie Zeng Gamal E. Khalil Dana Dabiri Zhongze Gu Younan Xia 《Particle & Particle Systems Characterization》2013,30(6):542-548
A facile approach to the synthesis of pressure and temperature dual‐responsive polystyrene (PS) microbeads with controlled sizes via dispersion polymerization is described. Three different luminophors are selected and directly introduced into the reaction system and thus incorporated into the resultant PS microbeads during polymerization. By manipulating the reaction conditions, including concentrations of the initiator and monomer, polarity of the reaction medium, and injection rate for the monomer, uniform PS microbeads with sizes ranging from 1 to 5 μm are obtained. When a light source centered at 365 nm is used to excite all the luminophors in the PS beads, three distinct and resolvable emission peaks corresponding well with the luminophors are observed. By taking advantage of their sensitive responses to both pressure and temperature, the PS beads can be utilized for quantitative measurements of these two stimulations simultaneously. The PS beads loaded with multiple luminophors have the ability to serve as building blocks for the fabrication of novel sensing and imaging devices and therefore provide a promising strategy for the study of aerodynamics. 相似文献
1000.
The LiVPO4F as cathode material for lithium-ion batteries was synthesized through two steps of solid-state reactions and investigated by ex situ Fourier transform infrared (FTIR) spectroscopy for the initial charge and discharge cycle. The characterization of the effect on the structure of the LiVPO4F in the process of lithium-ion insertion/extraction at a molecular level by ex situ FTIR spectroscopy is helpful for the mechanism research for lithium-ion insertion/extraction and the improvement of the performance of lithium-ion batteries. In the process of the initial cycle, new bands of VPO4F appear in the charge and the featured bands of LiVPO4F reappear in the discharge. In this paper, ex situ FTIR spectra indicates that the structure of the LiVPO4F in the process of lithium-ion insertion/extraction is almost not affected, which clearly states that the LiVPO4F possesses stable structure as cathode material. Consequently, the LiVPO4F might be expected as a potential cathode replacement for commercial lithium-ion batteries. 相似文献