Matrix-isolation FT-IR spectra and theoretical study of dimethyl sulfate

The preferred conformations of dimethyl sulfate and their vibrational spectra were studied by matrix-isolation FT-IR spectroscopy and theoretical methods (DFT and MP2, with basis sets of different sizes, including the quadruple-zeta, aug-cc-pVQZ basis). Conformer GG (of C2 symmetry and exhibiting OSOC dihedral angles of 74.3 degrees ) was found to be the most stable conformer in both the gaseous phase and isolated in argon. Upon annealing of the matrix, the less stable observed conformer (GT; with C1 symmetry) quickly converts to the GG conformer, with the resulting species being embedded in a matrix-cage which corresponds to the most stable matrix-site for GG form. The highest energy TT conformer, which was assumed to be the most stable conformer in previous studies, is predicted by the calculations to have a relative energy of ca. 10 kJ mol-1 and was not observed in the spectra of the matrix-isolated compound.     

光催化降解染料ZnO催化剂的性能

光催化法是20世纪70年代发展起来的新型水处理技术，即以某些半导体材料为催化剂，利用光催化法来降解环境污染物。该方法工艺简单，成本较低，在常温下能使大多数不能或难于生物降解的有毒有机物彻底氧化分解。近年来研究最多的是TiO2，由于其带隙较宽(3．2eV)，只能吸收波长λ≤387nm的紫外光，因此研制新型光催化剂仍是重要课题。     

Efficient asymmetric synthesis of an azasugar in water

An extremely efficient asymmetric synthesis of a pyrrolidine azasugar was completed in only four steps in water, without the use of protecting groups and in 60% overall yield from a simple, achiral bis-electrophile.     

吸热型碳氢燃料在银、镧改性混合分子筛上的裂解研究

为进一步提高吸热型碳氢燃料的吸热能效，考察了吸热型碳氢燃料NNJ－150在USHY和HZSM－5混合分子筛以及银、镧改性混合分子筛催化剂上的催化裂解。结果表明，在Ag-LaUSY Ag-LaZSM-5(75:25)混合分子筛催化NNJ－150裂解反应中，低碳烯烃选择性较高，催化剂寿命较长。采用此催化剂，能较好满足吸热型碳氢燃料裂解的需要。     

我国化学纤维新品种的发展

本文紧紧围绕发展我国化纤新品种的现状和展望,提出由“产品先导型”向“技术先导型”、由“市场开发型”向“发展型”过渡的发展展望。按化纤新品种几种主要发展途径,侧重就我国化纤新品种的成就,如:合成新的高聚物,化学、物理(包括结构)改性和纱线、织物后整理等,特别对共聚、共混、多种复合技术改性等,进行了重点讨论。     

热致液晶聚合物分散相的形态及其与树脂连续相之间的相互作用

用动态力学谱仪和扫描电子显微镜测试观察了六个含热致液晶聚合物（ＴＬＣＰ）共混体系中的相间相互作用与微结构．组份损耗峰向内或大或小的移动表明在这些共混物中存在着强弱不同的相间相互作用．在各个共混物中所含ＴＬＣＰ公相的形态有圆球状、椭球状、条状和微纤状的．结果表明，在含ＴＬＣＰ的不相容聚合物共混体系中，相间相互作用与微纤形成之间没有直接的相关性．     

Palladium catalyzed synthesis of tertiary allylamines. Utilization of α-nitro olefins as allylic nitro compounds

Reaction of α-nitro olefins with secondary amines in the presence of palladium(O) catalyst affords allylic amines.     

Amidomethylation of amodiaquine: antimalarial N-Mannich base derivatives

Novel N-Mannich base-type derivatives of the antimalarial drug amodiaquine were synthesised by reaction with tertiary N-chloromethylamides. With the exception of the derivative of ethyl hippurate, all the so-formed (1-amidomethyl-1H-quinolin-4-ylidene)arylamines displayed high chemical and enzymatic stability. These compounds displayed antimalarial activity against the multi-drug resistant Plasmodium falciparum strain Dd2 (IC₅₀ values 15-31 nM) and demonstrated no significant loss in activity compared to amodiaquine (IC₅₀ 30 nM).     

一种分离抗凝血酶Ⅲ的高效亲和色谱填料的制备及表征

以聚甲基丙烯酸环氧丙酯微球 ( PGMA)为基质 ,利用还原氨化方法将肝素键合在其表面上 ,得到一种以肝素为配基的高效亲和色谱填料 ,该填料对抗凝血酶 的亲和容量为 1 .2 mg/g,对抗凝血酶 和人血清白蛋白的回收率分别为 96.9%和 94 .4 % .利用前沿色谱法测定了肝素与抗凝血酶 之间的表观解离常数为 1 .96× 1 0 - 5mol/L.利用该填料可直接从人血浆中分离出抗凝血酶     

Gas-phase generation of highly reactive hexatriyne-bridged [6n]paracyclophynes

[6n]Paracyclophenediynes 2a-d (n = 3-6) having [4.3.2]propellatriene units were prepared as precursors of the corresponding [6n]paracyclophynes. Laser irradiation of 2a-d produced the negative ions of [6n]paracyclophynes 1a-d (n = 3-6) by extrusion of the indan fragments, which were detected by time-of-flight mass spectrometry.