Fluorescence spectrometer-on-a-fluidic-chip

A chip-size spectrometer is realized by combining a linear variable band-pass filter with a CMOS camera. The filter converts the spectral information of the incident light into a spatially dependent signal that is analyzed by the camera. A fluidic platform is integrated onto the spectrometer for analyzing the fluorescence from moving objects. The target is continuously excited within an anti-resonant waveguide, and its fluorescence spectrum is recorded as the object traverses the detection area.     

Experimental observation of four-photon entangled Dicke state with high fidelity

We present the experimental observation of the symmetric four-photon entangled Dicke state with two excitations |D_{4};{(2)}. A simple experimental setup allowed quantum state tomography yielding a fidelity as high as 0.844+/-0.008. We study the entanglement persistency of the state using novel witness operators and focus on the demonstration of a remarkable property: depending on the orientation of a measurement on one photon, the remaining three photons are projected into both inequivalent classes of genuine tripartite entanglement, the Greenberger-Horne-Zeilinger and W class. Furthermore, we discuss possible applications of |D_{4};{(2)} in quantum communication.     

Experimental observation of an entire family of four-photon entangled states

A single linear-optical setup is used to observe an entire family of four-photon entangled states. This approach breaks with the inflexibility of present linear-optical setups usually designed for the observation of a particular multipartite entangled state only. The family includes several prominent entangled states that are known to be highly relevant for quantum information applications.     

Determination of angular momenta in the incomplete-fusion channels of the reactions Ta+22Ne and Ir+12C

By using the γ-ray-multiplicity technique, experiments were carried out to determine the input angular momenta lⁱⁿ corresponding to the heavy-ion induced incomplete-fusion reactions involving the emission of fast charged particles. The α-particle and Li-nuclei emission channels were investigated in the reaction ¹⁸¹Ta + ²²Ne at the average Ne-ion energy of 155 MeV and for the α-particle emission channel in the reaction ^natIr+¹²C at E = 100 MeV. The separation of the reaction channels was carried out using an X-ray spectrometer. The angular distributions of the fission fragments were measured in the reaction ¹⁸¹Ta(²²Ne, αf). The data obtained indicate that input angular momenta are equal to about 60 ? and 50 ? for the channels of Li emission and α-emission, respectively, being practically independent of the particle energy. For the α-emission channel the lⁱⁿ values are the same for both reactions within experimental errors. The lifetime of the system of interacting target and projectile nuclei, prior to the emission of an α-particle, has been estimated to be equal to 10^?20s.     

Experimental realization of a three-qubit entangled W state

We report on the experimental observation of the three-photon polarization-entangled W state using spontaneous parametric down-conversion. This state is inequivalent to the Greenberger-Horne-Zeilinger state under stochastic local operations and classical communications and thus is the representative of the second class of genuine tripartite entanglement. We study the characteristic features of entanglement and demonstrate the high degree of two-photon entanglement in the W state.     

The use of complexation induced proton NMR chemical shifts for structural analysis of host-guest complexes in solution

Proton shielding variations in supramolecular complexes contain a wealth of information on complex geometries in solution that has been until now mostly neglected. We describe herein ways for such analyses with five cyclophane and two cyclodextrin complexes in water, by using a program SHIFT which is based on and parametrized with the analyses of over 300 intramolecular proton shift variations in well defined molecular frameworks such as steroids or cyclophanes. The intermolecular shift changes in the host-guest complexes at 100% complexation (CIS values) are calculated as sum of anisotropy effects deltachi from aromatic ring currents and linear electric field effects LEF, based on force field generated geometries. The conformations with the best agreement between calculated and observed CIS values are at least for noncharged guest compounds close to those obtained from molecular mechanics and/or MD calculations and intermolecular NOEs (where available), noticeably without adjusting the complex geometries to the experimental CIS. Through-space electrostatic field effects LEF, which have been until now often neglected, can be sizeable also for noncharged systems; best agreement between experiment and calculation is observed with Gasteiger atomic charges.     

Characterizing nonclassicality and entanglement

In Quantum Optics, the widely accepted definition of nonclassicality is based on the P function of Glauber and Sudarshan. When it fails to be interpreted as a classical probability density, the corresponding quantum state is said to be a nonclassical one. Here we present the first reconstruction of a nonclassical P function of a single-photon added thermal state. We also consider the nonclassical properties of general spacegtime dependent correlation functions of radiation fields. For the detection of these correlation functions, a balanced homodyne correlation technique was proposed. It is shown that the measurable correlation functions also allow one to completely characterize bipartite entangled quantum states with a negative partial transposition. Finally, we present a method for identifying general bipartite entanglement for continuous variables.     

Structural Electricity Models and Asymptotically Normal Estimators to Quantify Parameter Risk

ABSTRACT

We estimate a structural electricity (multi-commodity) model based on historical spot and futures data (fuels and power prices, respectively) and quantify the inherent parameter risk using an average value at risk approach (‘expected shortfall’). The mathematical proofs use the theory of asymptotic statistics to derive a parameter risk measure. We use far in-the-money options to derive a confidence level and use it as a prudent present value adjustment when pricing a virtual power plant. Finally, we conduct a present value benchmarking to compare the approach of temperature-driven demand (based on load data) to an ‘implied demand approach’ (demand implied from observable power futures prices). We observe that the implied demand approach can easily capture observed electricity price volatility whereas the estimation against observable load data will lead to a gap, because – amongst others – the interplay of demand and supply is not captured in the data (i.e., unexpected mismatches).     

On optimal allocation of risk vectors

In this paper we extend results on optimal risk allocations for portfolios of real risks w.r.t. convex risk functionals to portfolios of risk vectors. In particular we characterize optimal allocations minimizing the total risk as well as Pareto optimal allocations. Optimal risk allocations are shown to exhibit a worst case dependence structure w.r.t. some specific max-correlation risk measure and they are comonotone w.r.t. a common worst case scenario measure. We also derive a new existence criterion for optimal risk allocations and discuss some examples.     

Experimental analysis of a four-qubit photon cluster state

Linear-optics quantum logic operations enabled the observation of a four-photon cluster state. We prove genuine four-partite entanglement and study its persistency, demonstrating remarkable differences from the usual Greenberger-Horne-Zeilinger (GHZ) state. Efficient analysis tools are introduced in the experiment, which will be of great importance in further studies on multiparticle entangled states.