非线性生态系统的复杂动力学行为研究(Ⅲ)

本文继续文献[1～2]的研究,首先引进了生态系统的系综概念,在此基础上比较详细地讨论了生态协同学的微观方法和宏观方法.将这二者结合起来,利用生态系统输出(或可以测得)的宏观数据,建立广义金兹堡-朗道方程(GGLE),把握广义相变(群落演替)前后的信息变化,找出其微观对客观结果的作用机制,这也许是对复杂生态系统作用机制研究的一条新途径.     

[Hg8(μ‐n‐C3H7Te)12(μ‐Br)Br3] — Synthesis and Structure

The novel mercury‐tellurium cluster [Hg₈(μ‐n‐C₃H₇Te)₁₂(μ₂‐Br)Br₃] is formed during the reaction of HgBr₂ and (n‐C₃H₇Te)₂Hg in DMSO. Its crystal structure has been elucidated showing [Hg₈(μ‐n‐C₃H₇Te)₁₂(μ₂‐Br)]³⁺ units with a bromine‐centered distorted Hg₈ cube. The mercury atoms are bridged by n‐C₃H₇Te^— ligands and the resulting clusters are linked to a three‐dimensional network by bromine atoms. The close packing of the cluster is mainly determined by the flexible n‐propyl residues of the telluride building blocks.     

一种自适应的自动聚焦算法

自动聚焦是图像测量和计算机视觉中的重要技术。研究发现,以前的一些自动聚焦算法,在没有噪声的影响下,效果较好,但一旦有噪声的影响,算法可能会失效,因此,提出了一种自适应的自动聚焦方法。首先通过一个基于局部小窗口的自适应门限将边缘像素和非边缘像素区别开来,然后再加上一个全局门限来进一步滤除噪声的影响,最后用一些自动聚焦算法来计算经过自适应处理后的图像,画出它们的聚焦曲线。经过大量的实验,结果表明,该算法不仅具有单峰性强,无偏性好,灵敏度高等特点,而且还具有很好的抗噪声性能。     

Impact of Zn(Ⅱ) Ions on Crystallization and Thermal Properties of Poly(lactic acid)

The issues of low crystallinity and slow crystallization rate of poly(lactic acid) (PLA) have been widely addressed. In this work, we find that doping PLA with Zn(Ⅱ) ions can speed up the process of crystallization of PLA. Three kinds of Zn(Ⅱ) salts (ZnCl\begin{document}$ _2 $\end{document}, ZnSt and ZnOAc) were tested in comparison with some other ions such as Mg(Ⅱ) and Ca(Ⅱ). The increased crystallinity and crystallization rate of PLA doping with Zn(Ⅱ) are reflected in FT-IR and variable temperature Raman spectroscopy. The crystallinity is further confirmed or measured with differential scanning calorimetry and X-ray diffraction. The crystallinity rate of the PLA/ZnSt-0.4 wt% material can reach 22.46% and the crystallinity rate of the PLA/ZnOAc-0.4 wt% material can reach 24.83%, as measured with differential scanning calorimetry.     

邻香草醛缩氨基酸钾Schiff碱及其三苄基锡(IV)配合物的合成与表征

Six schiff bases derived from o－vanillin and amino acids and their tribenzyltin(IV) complexes have been synthesezed. The ligands and complexes were characterized by elemental analysis, IR ,UV and 1H NMR. The tin atom is five－coordinated in tribenzyltin(IV) complexes. There is intramolecular Sn←N of imine N atom.     

4,6,7-三氯喹啉的合成

以3,4-二氯苯胺和乙氧基亚甲基丙二酸二乙酯为起始原料,经缩合、Gould-Jacobs环合、水解、脱羧及氯化反应合成了含4-氨基喹啉结构抗肿瘤化合物的关键中间体——4,6,7-三氯喹啉,总收率54.21%,其结构经1H NMR,IR和ESI-MS确证。     

双周期平行四边形排列裂纹反平面问题的有限元分析

提出了双周期平行四边形排列裂纹反平面问题的有限元方法,通过对单位胞元引入周期边界条件,在裂纹尖端采用奇异单元,解决了有限元分析这类问题的效率和精度问题.利用Ansys软件计算,在各种有解析解对照的情形下,应力强度因子的相对误差都在0.2%以内.与现有通常限于对称阵列的双周期裂纹的研究相比,本文发展的方法适用于一般的非对称平行四边形裂纹阵列.算例揭示了行向裂纹间的相互干涉放大应力强度因子,而叠向裂纹间的作用相互屏蔽.对于平行四边形阵列的情形,这两种相反的干涉效应使应力强度因子与裂纹错动参数间呈现非单调依赖关系.     

"蹦环"现象理论分析

对“蹦环”现象进行了理论分析,给出了金属环蹦起初速度的表达式,同时指出了文献[1]存在的不足。     

邻香草醛缩氨基酸钾Schiff碱及其三苄基锡(Ⅳ)配合物的合成与表征

Six schiff bases derived from o-vanillin and amino acids and their trihenzyltin (Ⅳ) complexes have been synthesezed.The ligands and complexes were characterized by elemental analysis, IR, UV and ¹H NMR.The tin atom is five-coordinated in tribenzyltin (Ⅳ) complexes.There is intramolecular Sn←N of imine Natom.