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101.
Giovanelli E Leroux S Moisan L Carreyre H Thuéry P Buisson DA Meddour A Coustard JM Thibaudeau S Rousseau B Nicolas M Hellier P Doris E 《Organic letters》2011,13(15):4116-4119
Detailed investigations on one of the key steps of the superacidic fluorination of Vinca alkaloids that is the origin of C20' activation are reported. While two different pathways can be envisioned for the emergence of the transient secondary carbocationic intermediate, isotopic labeling experiments unambiguously revealed the involvement of a 1,2-hydride shift mechanism. 相似文献
102.
A highly efficient synthesis of L-ristosamine and L-epi-daunosamine glycosides via BF(3)·OEt(2) promoted tandem hydroamination/glycosylation of 3,4-di-O-acetyl-6-deoxy-L-glucal and L-galactal has been developed. The new method proceeds in a completely stereocontrolled manner within a short reaction time. Preparation of a library of L-ristosamine and L-epi-daunosamine glycosides with potential biochemical applications, by varying each component, exemplified the generality of the reaction. 相似文献
103.
Assia Benabdallah Yves Dermenjian Jrme Le Rousseau 《Journal of Functional Analysis》2011,260(12):357-3677
We consider anisotropic elliptic and parabolic operators in a bounded stratified media in Rn characterized by discontinuities of the coefficients in one direction. The surfaces of discontinuities cross the boundary of the domain. We prove Carleman estimates for these operators with an arbitrary observation region. 相似文献
104.
Livanov K Madhu V Balaraman E Shimon LJ Diskin-Posner Y Neumann R 《Inorganic chemistry》2011,50(22):11273-11275
The catalytic photocleavage of CS(2) to S(8) and a (C(x)S(y))(n) polymer with visible light using a dinuclear ruthenium(II) compound with a bipyridine units for photoactivity and a vicinal tertiary amine binding site for CS(2) activation was studied. The catalyst was characterized by X-ray diffraction, (1)H NMR, and (13)C NMR, ESI-MS and elemental analysis. CS(2) photocleavage was significant (240 turnovers, 20 h) to yield isolable S(8) and a (C(x)S(y))(n) polymer. A mononuclear catalyst or one without an amine binding site showed significantly less activity. XPS of the (C(x)S(y))(n) polymer showed a carbon/sulfur ratio ~1.5-1.6 indicating that in part both C-S bonds of CS(2) had been cleaved. Catalyst was also included within the polymer. The absence of peaks in the (1)H NMR verified the (C(x)S(y))(n) nature of the polymer, while (13)C NMR and IR indicated that the polymer had multiple types of C-S and C-C bonds. 相似文献
105.
Products such as cosmetics, pharmaceuticals, and crude oil often exist as water-in-oil (W/O) emulsions during their processing or in final form. In many cases, their dispersed aqueous phase is encased in a crystal network and/or by interfacially-adsorbed (‘Pickering’) particles [paraffins, triacylglycerols, polymers, etc.] that promote emulsion kinetic stability by hindering droplet–droplet contact, coalescence and macroscopic phase separation. In processed foods, important questions remain regarding whether a continuous phase fat crystal network or Pickering crystal provides better stabilization. This review explores the following factors related to crystal-stabilized W/O emulsions: i) the key properties dictating fat crystal spatial distribution (at the interface or in the continuous phase); ii) how temperature and freeze–thaw emulsion destabilization are intimately linked with fat crystal spatial distribution, and; iii) why oil-soluble surfactant interactions with the continuous oil phase influence fat crystal wettability and emulsifier efficacy. It is shown that these parameters strongly govern W/O emulsion formation and stability. 相似文献
106.
Padmanaban M Müller P Lieder C Gedrich K Grünker R Bon V Senkovska I Baumgärtner S Opelt S Paasch S Brunner E Glorius F Klemm E Kaskel S 《Chemical communications (Cambridge, England)》2011,47(44):12089-12091
A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal-organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported. 相似文献
107.
Grünker R Senkovska I Biedermann R Klein N Lohe MR Müller P Kaskel S 《Chemical communications (Cambridge, England)》2011,47(1):490-492
A flexible Metal-Organic Framework Zn(4)O(BenzTB)(3/2) (DUT-13) was obtained by combination of a tetratopic linker and Zn(4)O(6+) as connector. The material has a corundum topology and shows the highest pore volume among flexible MOFs. 相似文献
108.
Jakes P Erdem E Ozarowski A van Tol J Buckan R Mikhailova D Ehrenberg H Eichel RA 《Physical chemistry chemical physics : PCCP》2011,13(20):9344-9352
The local coordination of the Fe(3+)-centers in Li[Co(0.98)Fe(0.02)]O(2) cathode materials for lithium-ion batteries has been investigated by means of XRD and multi-frequency EPR spectroscopy. EPR clearly showed the Fe(3+) being in a high-spin state with S = 5/2. The set of spin-Hamiltonian parameters obtained from multi-frequency EPR experiments with Larmor frequencies ranging between 9.8 and 406 GHz was transformed into structural information by means of an expansion to standard Newton-superposition modeling, termed as Monte-Carlo Newman superposition modeling. Based on this analysis, an isovalent incorporation of the Fe(3+)-ions on the Co(3+)-sites, i.e. Fe(x)(Co), has been shown. With that respect, the positive sign of the axial second-order fine-structure interaction parameter B(0)(2) is indicative of an elongated oxygen octahedron, whereas B(0)(2) < 0 points to a compressed octahedron coordinated about the Fe(3+)-center. Furthermore, the results obtained here suggest that the oxygen octahedron about the Fe(3+)-ion is slightly distorted as compared to the CoO(6) octahedron, which in turn may impose mechanical strain to the cathode material. 相似文献
109.
Thomas Capelle Cristián E. Cortés Michel Gendreau Pablo A. Rey Louis-Martin Rousseau 《European Journal of Operational Research》2019,272(1):121-131
In this paper we formulate an integer programming model for the Location and Routing Problem with Pickup and Delivery. We propose a column generation scheme and implement, for the subproblem, a label-setting algorithm for the shortest path with pickup and delivery and time windows problem. We also propose a set of heuristics to speed up this process. To validate the model, we implement the column generation scheme and test it on different instances developed in this paper. We also provide an analysis of how the costs of opening depots and the fixed cost of routes affect the optimal solution. 相似文献
110.
Bergmann Ronny Herzog Roland Silva Louzeiro Maurcio Tenbrinck Daniel Vidal-Nez Jos 《Foundations of Computational Mathematics》2021,21(6):1465-1504
Foundations of Computational Mathematics - This paper introduces a new notion of a Fenchel conjugate, which generalizes the classical Fenchel conjugation to functions defined on Riemannian... 相似文献