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81.
A cross-linked polyethyleneimine polymer containing the [ZnWZn2(H2O)2(ZnW9O34)2]12- polyoxometalate was prepared from branched polyethyleneimine (Mw = 600), the polyoxometalate, and a n-octylamine-epichlorohydrin cross-linking reagent. This catalytic assembly was active for the selective oxidation of 2-alkanols to 2-alkanones with aqueous H2O2 with reactions presumably occurring at a hydrophobic domain. Most importantly, the catalyst showed distinctive lipophiloselectivity, that is selectivity as a function of the lipophilic nature of a reaction substrate. The lipophiloselectivity was proportional to the relative partition coefficient (1-octanol/water) of the substrates. 相似文献
82.
Kruhlak RJ Wong GK Chen JS Murdoch SG Leonhardt R Harvey JD Joly NY Knight JC 《Optics letters》2006,31(10):1379-1381
Polarization modulation instability (PMI) in birefringent photonic crystal fibers has been observed in the normal dispersion regime with a frequency shift of 64 THz between the generated frequencies and the pump frequency. The generated sidebands are orthogonally polarized to the pump. From the observed PMI frequency shift and the measured dispersion, we determined the phase birefringence to be 5.3 x 10(-5) at a pump wavelength of 647.1 nm. This birefringence was used to estimate the PMI gain as a function of pump wavelength. Four-wave mixing experiments in both the normal and the anomalous dispersion regimes generated PMI frequency shifts that show good agreement with the predicted values over a 70 THz range. These results could lead to amplifiers and oscillators based on PMI. 相似文献
83.
84.
Hauptvogel IM Bon V Grünker R Baburin IA Senkovska I Mueller U Kaskel S 《Dalton transactions (Cambridge, England : 2003)》2012,41(14):4172-4179
Five new coordination polymers, namely, [Zn(2)(H(2)O)(2)(BBC)](NO(3))(DEF)(6) (DUT-40), [Zn(3)(H(2)O)(3)(BBC)(2)] (DUT-41), [(C(2)H(5))(2)NH(2)][Zn(2)(BBC)(TDC)](DEF)(6)(H(2)O)(7) (DUT-42), [Zn(10)(BBC)(5)(BPDC)(2)(H(2)O)(10)](NO(3))(DEF)(28)(H(2)O)(8) (DUT-43), and [Co(2)(BBC)(NO(3))(DEF)(2)(H(2)O)](DEF)(6)(H(2)O) (DUT-44), where BBC--4,4',4'-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate, TDC--2,5-thiophenedicarboxylate, BPDC--4,4'-biphenyldicarboxylate, DEF--,N-diethylformamide, were obtained under solvothermal conditions and structurally characterized. It has been shown that compounds DUT-40, DUT-41 and DUT-44 exhibit 2D layered structures with large hexagonal channels. Utilization of additional angular dicarboxylic TDC linker led to the formation of the DUT-42 compound with the structure consisting of three interpenetrated 3D networks. Using the linear co-linker dicarboxylic BPDC, DUT-43 was obtained which forms a complicated 3D architecture arising from the polycatenation of triple-layered 2D building units and 2D single layer units. The pore accessibility of the synthesized compounds in the liquid phase was proved by the adsorption of dye molecules. 相似文献
85.
Schuhmann K Almeida R Baumert M Herzog R Bornstein SR Shevchenko A 《Journal of mass spectrometry : JMS》2012,47(1):96-104
Top-down shotgun lipidomics relies on direct infusion of total lipid extracts into a high-resolution tandem mass spectrometer and implies that individual lipids are recognized by their accurately determined m/z. Lipid ionization efficiency and detection specificity strongly depend on the acquisition polarity, and therefore it is beneficial to analyze lipid mixtures in both positive and negative modes. Hybrid LTQ Orbitrap mass spectrometers are widely applied in top-down lipidomics; however, rapid polarity switching was previously unfeasible because of the severe and immediate degradation of mass accuracy. Here, we report on a method to rapidly acquire high-resolution spectra in both polarity modes with sub-ppm mass accuracy and demonstrate that it not only simplifies and accelerates shotgun lipidomics analyses but also improves the lipidome coverage because more lipid classes and more individual species within each class are recognized. In this way, shotgun analysis of total lipid extracts of human blood plasma enabled to quantify 222 species from 15 major lipid classes within 7?min acquisition cycle. 相似文献
86.
Laurine R. ZuppVeronica L. Campanella DiAndra M. RudzinskiFrançois Beland Ronny Priefer 《Tetrahedron letters》2012,53(39):5343-5346
Microwave irradiation is a popular method in organic synthesis to achieve high yields in shorter reaction times. This decreases total ‘man-hours’ in a synthetic setting. Another technique used in organic chemistry to decrease manual manipulations, is solid support reagents. The benefits of this approach is that upon completion of a reaction, a simple filtration can be performed which expedites the work-up and also produces less organic waste. Friedel-Crafts alkylation has been explored using microwave chemistry as well as with solid-supported reagents. In comparison with traditional heating, as well as with AlCl3, superior yields were observed with silica-gel bound aluminum chloride (Si-AlClx) when microwave irradiated for only 5 min. 相似文献
87.
Kai Schuhmann Reinaldo Almeida Mark Baumert Ronny Herzog Stefan R. Bornstein Andrej Shevchenko 《Journal of mass spectrometry : JMS》2012,47(1):96-104
Top–down shotgun lipidomics relies on direct infusion of total lipid extracts into a high‐resolution tandem mass spectrometer and implies that individual lipids are recognized by their accurately determined m/z. Lipid ionization efficiency and detection specificity strongly depend on the acquisition polarity, and therefore it is beneficial to analyze lipid mixtures in both positive and negative modes. Hybrid LTQ Orbitrap mass spectrometers are widely applied in top–down lipidomics; however, rapid polarity switching was previously unfeasible because of the severe and immediate degradation of mass accuracy. Here, we report on a method to rapidly acquire high‐resolution spectra in both polarity modes with sub‐ppm mass accuracy and demonstrate that it not only simplifies and accelerates shotgun lipidomics analyses but also improves the lipidome coverage because more lipid classes and more individual species within each class are recognized. In this way, shotgun analysis of total lipid extracts of human blood plasma enabled to quantify 222 species from 15 major lipid classes within 7 min acquisition cycle. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
88.
Detlef Günther Albrecht v. Quadt Ronny Wirz Herve Cousin Volker J. Dietrich 《Mikrochimica acta》2001,136(3-4):101-107
Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) was used as a complementary technique to X-ray fluorescence
(XRF), for multi-element analysis of geological samples fused with lithium-tetraborate Li2B4O7). Different calibration strategies using external non-matrix matched reference materials were investigated. Various internal
standards were tested, including the use of Li from the flux, and the use of the naturally occurring internal standards, Si
or Ca. The use of a naturally occurring standard is not as efficient as this required a prior analysis of the samples using
XRF. The obtained values for the analysis of geological reference materials were compared with consensus literature values,
and satisfactory agreement was found. Laser pits, which were formed, had a diameter of 80 μm and 3–5 replicates on each fused
disc were measured. The reproducibility of the method was better than 10% for concentrations above 1 μg/g and better than
15% for lower concentrations. The use of Li as the internal standard offers the possibility of multi-element determinations
in geological samples, which have an unknown composition when the laser ablation analysis is carried out. However, using the
calculated stoichiometric composition of the lithium-tetraborate for the calculation of the Li concentration leads to a constant
deviation from the recommended values. Therefore, it was necessary to determine the Li concentration within each sample batch
using at least one lithium tetraborate fused geological reference material. This resulting Li concentration in the beads was
then used for all subsequent samples in a run. Limits of detection, reproducibility, deviation from reference values indicate
the potential of LA-ICP-MS for such bulk analysis without matrix matched calibration standards. 相似文献
89.
Ronny Pieters Hans E. Miltner Guy Van Assche Bruno Van Mele 《Macromolecular Symposia》2006,233(1):36-41
Temperature-induced phase separation of P(EO75-ran-PO25)/PES and reaction-induced phase separation of DGEBA/MDA modified with PVME are studied using MTDSC as an in-situ tool. Phase separation can be probed by the onset of an ‘excess’ contribution in the MTDSC heat capacity signal, in good correspondence with the cloud point temperature. This feature enables the complete construction of the state diagram of P(EO75-ran-PO25)/PES. The detection of phase separation-induced partial vitrification of the high-Tg phase (PES-rich phase) enables to sub-divide the LCST-type heterogeneous region in a zone 1 (no interference of partial vitrification) and a zone 2 (interference of partial vitrification of the PES-rich phase). This sub-division of the heterogeneous region has drastic implications on the remixing behavior of demixed blends. In DGEBA/MDA modified with PVME, reaction-induced phase separation accompanied by an increase in reaction rate, followed by a vitrification step of the epoxy-amine phase can be detected in-situ. In non-isothermal conditions, a diffusion-controlled reaction after vitrification and a final devitrification of the system is also observed. 相似文献
90.
Ronny Pini Giuseppe Storti Marco Mazzotti Hongyun Tai Kevin M. Shakesheff Steven M. Howdle 《Macromolecular Symposia》2007,259(1):197-202
Summary: The equilibrium sorption and swelling behavior in supercritical CO2 of poly(D,L-lactic acid) and poly(lactic-co-glycolic acid) has been studied at a temperature of 35 °C and at pressures up to 200 bar. Sorption was measured through a gravimetric technique and swelling by visualization. From these data, the behavior of the different polymers can be compared. In terms of partial molar volume of CO2 in the polymer matrix, all the polymers exhibit a behavior typical of rubbery systems. The experimental results have been modeled using the Sanchez-Lacombe equation of state, which is able to represent the actual behavior of the polymer-CO2 systems with reasonable accuracy. 相似文献