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61.
John A. Powell Jong J. Whang Frederick H. Owens Roger K. Graham 《Journal of polymer science. Part A, Polymer chemistry》1967,5(10):2655-2664
Copolymers of methyl methacrylate with methyl and ethyl α-hydroxymethylacrylate and with α-hydroxymethylstyrene have been prepared with free-radical initiators at temperatures below 80°C. At higher reaction temperatures or under extrusion conditions, alcohol was eliminated and the free hydroxyl content was greatly decreased. All evidence indicates the formation of six-membered lactone groups in this post-polymerization reaction: direct evidence for their formation is lacking, however, since neither infrared nor nuclear magnetic resonance spectra could be used to detect lactonization in this system. The loss of activity from 14C ester-labeled methyl methacrylate copolymer on heating could be correlated with the extent of lactonization. The degree of lactonization is relatively less with copolymers containing higher amounts of hydroxymethyl groups. The resulting polymers exhibit higher heat distortion temperatures and decreased impact resistance when compared to poly(methyl methacrylate). Attempts were made to incorporate similar lactone structures by cyclocopolymerization with methyl methacrylate of α-methacryloxymethylstyrene or ethyl α-methacryloxymethylacrylate, but only crosslinked polymers or polymers with pendent unsaturation were found. 相似文献
62.
Quantum theory accepts the point-like indivisible (classical) character of a particle as a mere product of a measuring process, or what has become known as a collapse. Following the notion of empty waves, which accepts the particle as a real existent entity without regard to the measurement process, we propose an experiment that may shed some light on the reality of the particle and the consequences of that reality. 相似文献
63.
64.
Given an expansive action α of ?2 by automorphisms of a compact connected metrizable abelian groupX, we show how the entropy of the action may be decomposed into local contributions, 1 $$h(\alpha ) = \sum\limits_{p \leqslant \infty } {h_p^{(a,b)} } (\alpha )$$ in which the summandh p (a,b) (α) represents thep-adic entropy due to arithmetic or geometric hyperbolicity in the direction (a, b). We recognize thep-adic contribution as an integral over thep-adic unit circle, in analogy with the global counterpart. As (a, b) changes, the decomposition (1) changes only when the line through (a, b) passes through one of a finite collection of critical directions, which are explicitly identified. 相似文献
65.
Cellular algebras 总被引:4,自引:0,他引:4
66.
Ron M. Roth 《Designs, Codes and Cryptography》1996,9(2):177-191
Codes
of length 2
m
over {1, -1} are defined as null spaces of certain submatrices of Hadamard matrices. It is shown that the codewords of
all have an rth order spectral null at zero frequency. Establishing the connection between
and the parity-check matrix of Reed-Muller codes, the minimum distance of
is obtained along with upper bounds on the redundancy of
. An efficient algorithm is presented for encoding unconstrained binary sequences into
. 相似文献
67.
68.
69.
Ron S. Dickson Gary S. Evans Gary D. Fallon 《Journal of organometallic chemistry》1982,236(2):C49-C52
The complexes (η-C5Me5)2Rh2(μ-CO) {μ-η2,η2-C(O)CRCR} are obtained from reactions between (η-C5Me5)2Rh2(CO)2 and the alkynes RCCR (R CF3, CO2Me, or Ph) at 25°C. The molecular geometry of the complex with R CF3 has been established by X-ray diffraction; the bridging 'ene-one' unit adopts a μ-η2,η2 conformation. Other complexes isolated from these reactions include (η-C5Me5)Rh(C6R6) (R CF3, CO2Me), (η-C5Me)2Rh2(C4R4) (R CO2Me) and (η-C5Me5)2Rh2(CO2C2R2) (R Ph). The reaction between (η-C5Me5)2Rh2(CO)2 and C6F5CCC6F5 gives (η-C5Me5)2Rh2(CO)2(C6F5C2C6F5). Mononuclear complexes such as (η-C5Me5)Co(C4R4CO) are the major products isolated from reactions between (η-C5Me5)2CO2(CO)2 and alkynes at 25°C. 相似文献
70.
The thermally stable, terminal phosphinidene complexes [CpM(CO)2(eta1-PNiPr2)]AlCl4(Cp= Cp, Cp*; M = Fe) and [Cp*M(CO)3(eta1-PNiPr2)]AlCl4 (M = Cr, Mo, W) react with Ph2C=N=N to form terminal P-coordinated eta1-phosphaazine and eta3-diazaphosphaallene ligands, respectively, whereas [CpFe(CO)2(eta1-PNiPr2)]AlCl4 reacts with Me3SiCHN2 affording a terminal phosphorus bound eta1-phosphaalkene complex. 相似文献