全文获取类型
收费全文 | 13232篇 |
免费 | 412篇 |
国内免费 | 24篇 |
专业分类
化学 | 7207篇 |
晶体学 | 152篇 |
力学 | 244篇 |
数学 | 2617篇 |
物理学 | 3448篇 |
出版年
2022年 | 109篇 |
2021年 | 213篇 |
2020年 | 204篇 |
2019年 | 206篇 |
2018年 | 263篇 |
2017年 | 280篇 |
2016年 | 575篇 |
2015年 | 407篇 |
2014年 | 473篇 |
2013年 | 1007篇 |
2012年 | 665篇 |
2011年 | 809篇 |
2010年 | 537篇 |
2009年 | 484篇 |
2008年 | 490篇 |
2007年 | 440篇 |
2006年 | 335篇 |
2005年 | 275篇 |
2004年 | 248篇 |
2003年 | 226篇 |
2002年 | 242篇 |
2001年 | 166篇 |
2000年 | 165篇 |
1999年 | 164篇 |
1998年 | 144篇 |
1997年 | 145篇 |
1996年 | 166篇 |
1995年 | 144篇 |
1994年 | 133篇 |
1993年 | 139篇 |
1992年 | 141篇 |
1991年 | 115篇 |
1990年 | 125篇 |
1989年 | 113篇 |
1988年 | 116篇 |
1987年 | 133篇 |
1986年 | 96篇 |
1985年 | 142篇 |
1984年 | 152篇 |
1983年 | 136篇 |
1982年 | 132篇 |
1981年 | 126篇 |
1980年 | 130篇 |
1979年 | 134篇 |
1978年 | 140篇 |
1977年 | 133篇 |
1976年 | 123篇 |
1975年 | 103篇 |
1974年 | 106篇 |
1973年 | 105篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
51.
In this paper we deal with nonlinear second-order boundary value problems with impulses. The impulsive functions depend implicitly on the different considered variables and the boundary value conditions are nonlinear. In both cases functional dependence on the solution is allowed. The existence results follow from the existence of a pair of well-ordered lower and upper solutions. 相似文献
52.
T. Roubíček 《Journal of Optimization Theory and Applications》2007,132(1):41-50
Existence of a Nash equilibrium in a noncooperative game governed by the one-dimensional Burgers equation, proposed in the
case of pointwise controls in Ref. 1, is proved under data qualifications that guarantee the diffusion term in the Burgers’
equation to be dominant enough with respect to the uniform convexity of the payoffs.
This work was partly supported by Grants 201/03/0934 (GA čR) and MSM 0021620839 (MšMT čR). Inspiring discussions with Angel
M. Ramos are acknowledged. 相似文献
53.
A. Odrzywołek 《The European Physical Journal C - Particles and Fields》2007,52(2):425-434
The spectrum of the neutrinos produced in the massive photon and longitudinal plasmon decay process has been computed with
four levels of approximation for the dispersion relations. Some analytical formulae in the limit cases are derived. Interesting
conclusions related to previous calculations of the energy loss in stars are presented. The high energy tail of the neutrino
spectrum is shown to be proportional to exp(-E/kT), where E is the neutrino energy and kT is the temperature of the plasma.
PACS 97.90.+j; 97.60.-s; 95.55.Vj; 52.27.Ep 相似文献
54.
V. V. Panić A. B. Dekanski S. K. Milonjić V. B. Mišković-Stanković B. Ž. Nikolić 《Russian Journal of Electrochemistry》2006,42(10):1055-1060
Electrocatalytic properties of RuO2/Ti anode with different coating masses, which are prepared by the alkoxide sol-gel procedure, are investigated in chlorine
and oxygen evolution reactions by polarization measurements and electrochemical impedance spectroscopy in H2SO4 and NaCl electrolytes. According to polarization measurements, the activity of anodes at overpotentials below 100 mV is independent
of coating mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine evolution
reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered in low-frequency
domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V (SCE). The observed impedance behavior is
discussed with respect to the activity model for activated titanium anodes in chlorine evolution reaction involving formation
of gas channels within porous coating structure. Gas channels enhance the mass transfer rate similarly to the forced convection,
which also increases the activity of anode. This is more pronounced for the anode of greater coating mass due to its more
compact surface structure. The more compact structure appears to be beneficial for gas channels formation.
Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 10, pp. 1173–1179.
The text was submitted by the authors in English. 相似文献
55.
Orotic acid (vitamin B13) is a key intermediate in biosynthesis of the pyrimidine nucleotides in living organisms, moreover, it may serve as the biological carrier for some metal ions. cis-Diammine(orotato)platinum(II), cis-[Pt(C5H2N2O4)(NH3)2] can be considered as a new potential cisplatin analogue. The FT-Raman and FT-IR spectra of the title complex are reported, for the first time. The molecular structure, vibrational frequencies, and the theoretical infrared and Raman intensities have been calculated by the density functional mPW1PW91 method. The detailed vibrational assignment has been made on the basis of the calculated potential energy distribution. The theoretically predicted IR and Raman spectra show very good agreement with experiment. Natural bond orbital (NBO) analyses were performed for cisplatin, carboplatin and the title complex. The results provided new data on the nature of platinum–ligand bonding in these compounds. Strong intramolecular hydrogen bond between the orotate ligand and the coordinated ammonia group stabilizes the structure of the platinum(II) complex. Thus, it is suggested that the orotate ligand in the title complex is more inert to the substitution reactions than the chloride ligands in cisplatin. 相似文献
56.
K. Prokeš 《Czechoslovak Journal of Physics》2002,52(2):253-258
Many materials exhibit various magnetic phenomena as a function of magnetic field, temperature and/or pressure. Usually, bulk magnetic measurements provide first information on the magnetic state of the material by measuring their response on the applied magnetic field. However, it is necessary to investigate materials also on a microscopic scale. This is often done by means of neutron scattering. In this contribution we discuss basic ideas of this method and we report on few experimental results obtained with a split-pair coil 14.5 T superconducting magnet which can be combined with dilution stick offering temperatures as low as 30 mK and/or with a small clamped-type pressure cell which offers pressure up to 1.0 GPa. 相似文献
57.
We have investigated the structure of spider dragline silk by X-ray diffraction over a broad temperature range from room temperature
up to thermal denaturation conditions. The dominating signal from the β-sheet crystallites is analyzed. Pronounced changes
of scattering intensity starting at temperatures around 150 °C are observed. These changes are discussed in view of the respective
lattice constants, crystal size, size distribution, crystallite number density and amino acid composition.
PACS 87.68.+z; 87.15.-v; 87.64.Bx 相似文献
58.
G. Michałek B.R. Bułka 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(1):121-128
The currents and their fluctuations in two capacitively coupled single electron transistors are determined in the limit of
sequential tunnelling. Our considerations are restricted to the case when the islands (dots) of the transistors are atomic-sized,
which means each of them has only one single electronic level available for the tunnelling processes. The Coulomb interactions
of accumulated charges on the both single electron transistors lead to the effect of the negative differential resistance.
An enhancement of the current shot-noise was also found. Spectral decomposition analysis indicated the two main contributions
to the shot-noise: low- and high-frequency fluctuations. It was found that the low frequency fluctuations (polarization noise)
are responsible for a strong enhancement of the current noise.
Received 9 October 2001 / Received in final form 8 March 2002 Published online 9 July 2002 相似文献
59.
60.
The validity of local parton-hadron duality within the framework of HERWIG and JETSET event generators is investigated. We concentrate one
+
e
– annihilations in LEP 2 energy range as these interactions provide theoretically the cleanest condition for the discussion of this concept. We conclude that the concept of local parton-hadron duality is not valid in either of the two generators considered. 相似文献