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31.
Romain Heck 《Tetrahedron letters》2004,45(2):281-284
A new tripodal α-cyclodextrin having three ureido-bipyridyl tethers symmetrically distributed on its upper rim was prepared in one step by the polymer supported ‘phosphine imide’ reaction in a medium yield. As expected, the highly selective complexation properties towards ‘hard’ and ‘soft’ cations were maintained with regards to the URFT-Cd (upper rim fully tethered) family previously investigated. Its EuIII and TbIII lanthanide complex fluorescence behaviour clearly indicates that a limited number of tethers allow a better bis-heterocyclic antenna self-organisation around the cation leading to enhanced fluorescence properties. 相似文献
32.
ortho‐, meta‐, and para‐Dihydroindenofluorene Derivatives as Host Materials for Phosphorescent OLEDs
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Maxime Romain Sébastien Thiery Anna Shirinskaya Dr. Céline Declairieux Dr. Denis Tondelier Bernard Geffroy Dr. Olivier Jeannin Dr. Joëlle Rault‐Berthelot Dr. Rémi Métivier Dr. Cyril Poriel 《Angewandte Chemie (International ed. in English)》2015,54(4):1176-1180
This work reports the first structure–properties relationship study of ortho [2,1‐c]‐, meta [1,2‐a]‐, and para [1,2‐b]dihydroindenofluorenes, highlighting the influence of bridge rigidification on the electronic properties. This study has made it possible to devise an extended π‐conjugated molecule with both a high triplet state energy level and excellent thermal and morphological stability. As a proof of concept, dihydroindenofluorenes were used as the host in sky‐blue phosphorescent organic light‐emitting diodes (PhOLEDs) w ith high performance. 相似文献
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34.
Synthesis of Functionalized Mono‐, Bis‐, and Trisethynyltriptycenes for One‐Dimensional Self‐Assembly on Surfaces
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Agnès M. Sirven Romain Garbage Yun Qiao Dr. Claire Kammerer Prof. Dr. Gwénaël Rapenne 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(42):15013-15019
This paper describes the synthesis of triptycene‐based building blocks that are able to interact through hydrogen bonds to form one‐dimensional self‐assembled motifs on surfaces. We designed 9,10‐diethynyltriptycene derivatives functionalized at the ethynyl end groups by a variety of hydrogen‐bonding groups for homomolecular recognition and complementary building blocks for heteromolecular recognition. We also present the synthesis of bis‐ and trisethynyltriptycenes with terminal alkyne functional groups available for on‐surface azide–alkyne cycloaddition reaction to expand the potential of the triptycene building block. 相似文献
35.
Bulard E Guo Z Zheng W Dubost H Fontaine-Aupart MP Bellon-Fontaine MN Herry JM Briandet R Bourguignon B 《Langmuir : the ACS journal of surfaces and colloids》2011,27(8):4928-4935
Understanding bacterial adhesion on a surface is a crucial step to design new materials with improved properties or to control biofilm formation and eradication. Sum Frequency Generation (SFG) vibrational spectroscopy has been employed to study in situ the conformational response of a self-assembled monolayer (SAM) of octadecanethiol (ODT) on a gold film to the adhesion of hydrophilic and hydrophobic ovococcoid model bacteria. The present work highlights vibrational SFG spectroscopy as a powerful and unique non-invasive biophysical technique to probe and control bacteria interaction with ordered surfaces. Indeed, the SFG vibrational spectral changes reveal different ODT SAM conformations in air and upon exposure to aqueous solution or bacterial adhesion. Furthermore, this effect depends on the bacterial cell surface properties. The SFG spectral modeling demonstrates that hydrophobic bacteria flatten the ODT SAM alkyl chain terminal part, whereas the hydrophilic ones raise this ODT SAM terminal part. Microorganism-induced alteration of grafted chains can thus affect the desired interfacial functionality, a result that should be considered for the design of new reactive materials. 相似文献
36.
Dabre R Azad N Schwämmle A Lämmerhofer M Lindner W 《Journal of separation science》2011,34(7):761-772
Several methods for the separation of vitamins on HPLC columns were already validated in the last 20 years. However, most of the techniques focus on separating either fat- or water-soluble vitamins and only few methods are intended to separate lipophilic and hydrophilic vitamins simultaneously. A mixed-mode reversed-phase weak anion exchange (RP-WAX) stationary phase was developed in our laboratory in order to address such mixture of analytes with different chemical characteristics, which are difficult to separate on standard columns. The high versatility in usage of the RP-WAX chromatographic material allowed a baseline separation of ten vitamins within a single run, seven water-soluble and three fat-soluble, using three different chromatographic modes: some positively charged vitamins are eluted in ion exclusion and ion repulsion modes whereas the negatively charged molecules are eluted in the ion exchange mechanism. The non-charged molecules are eluted in a classical reversed-phase mode, regarding their polarities. The method was validated for the vitamin analysis in tablets, evaluating selectivity, robustness, linearity, accuracy, and precision. The validated method was finally employed for the analysis of the vitamin content of some commercially available supplement tablets. 相似文献
37.
Canioni R Marchal-Roch C Leclerc-Laronze N Haouas M Taulèlle F Marrot J Paul S Lamonier C Paul JF Loridant S Millet JM Cadot E 《Chemical communications (Cambridge, England)》2011,47(22):6413-6415
{Mo(132)} Keplerate anion reacts with tellurites to give a soluble precursor to produce in hydrothermal conditions single-phase M1 MoVTeO light-alkanes oxidation catalyst. Characterization of this Te-containing intermediate by single-crystal X-ray diffraction, (125)Te NMR, UV-visible and redox titration reveals a molybdotellurite anion as a crown-capped Keggin derivative. 相似文献
38.
39.
Using [Cp(Me)5Rh(bipy)C1]C1 (1) as redox catalyst for the continous NADH regeneration it was possible to perform an electrochemically driven enzymatic reduction of pyruvate to D-lactate catalyzed by D-LDH at a rate of 5 turnovers per hour. This is by a factor of 20 faster than the best results obtained until now. Current yields of 50 to 70 % may be obtained. 相似文献
40.
We consider a multidimensional diffusion X with drift coefficient b(α,Xt) and diffusion coefficient ?σ(β,Xt). The diffusion sample path is discretely observed at times tk=kΔ for k=1…n on a fixed interval [0,T]. We study minimum contrast estimators derived from the Gaussian process approximating X for small ?. We obtain consistent and asymptotically normal estimators of α for fixed Δ and ?→0 and of (α,β) for Δ→0 and ?→0 without any condition linking ? and Δ. We compare the estimators obtained with various methods and for various magnitudes of Δ and ? based on simulation studies. Finally, we investigate the interest of using such methods in an epidemiological framework. 相似文献