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971.
Frank Würthner Carsten Tschierske Anke Krüger Klaus Ditrich Roland Pfau Henning Priepke Rolf Breinbauer Hans‐Achim Wagenknecht Gerald Drger Andreas Kirschning Norbert Sewald Uwe Beifuss Mathias O. Senge Thomas J. J. Müller Peter R. Schreiner Ruth Gschwind Bernd F. Straub Kilian Muiz Martin Oestreich Jrg Pietruszka Thomas Lindel Roderich Süßmuth Philippe Bisel Michael Müller Elmar Weinhold Andres Jschke Markus Albrecht Thorsten Bach Gtz Bucher Heinrich Heydt Jens Hartung 《Nachrichten aus der Chemie》2006,54(3):241-264
972.
973.
The strong coupling of thermal and mechanical properties and the highly inhomogeneous strain distribution in tensiontests motivate for thorough investigations on NiTi shape memory alloys. For these tests a complex experimental set-up has been developed which allows for the simultaneous measurement of stress, strain, and temperature with high spatial and temporal resolution. The experimental results show the influence of strain rate, number of cycles, and deformation level on the progress of stress induced phase transformation in the specimens. A critical evaluation of the experimental results in view of a potential constitutive modeling is given. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
974.
Polycarbonate is an amorphous polymer which exhibits nonlinear deformation before failure. It shows a pronounced strength-differential effect between compression and tension. Strain rate influences the mechanical response of the polycarbonate. In particular, the yield stress is increased with increasing strain rate. The concept of stress mode dependent weighting function is used in the proposed model to simulate the asymmetric effects for different loading speeds. In this concept, an additive decomposition of the flow rule is assumed into a sum of weighted stress mode related quantities. The characterization of the stress modes is obtained in the octahedral plane of the deviatoric stress space in terms of the mode angle, such that stress mode dependent scalar weighting functions can be constructed. The resulting evolution equations are updated using a backward Euler scheme and the algorithmic tangent operator is derived for the finite element equilibrium iteration. The numerical implementation of the resulting set of constitutive equations is used in a finite element program for parameter identification. The proposed model is verified by showing a good agreement with the experimental data. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
975.
Experimental results of shape memory alloys show a pronounced asymmetric behaviour between tension, compression and shear. For simulation of these effects in the constitutive equations different transformation strain tensors are introduced. These are related to the different variants for the multi-variant- and detwinned-martensite as a consequence of different stress states. In the framework of plasticity the concept of stress mode dependent weighting functions is applied in order to characterize the different stress states. Verification of the proposed methodology is succeeded for simulation of the pseudoelastic behaviour of shape memory alloys with different hardening characteristics in tension, compression and shear. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
976.
The wake vortex hazard and the required separation distances between aircraft at airports constitute an impediment to the growth of air traffic at major hubs. One approach to reduce separation distances is the exploitation of the inherent instability in vortex systems, leading to an accelerated breakdown. In this paper we show the impact of excitation by different control surfaces on the stability behavior of the wake of a rectangular wing with winglets. The experiment shows that the excitation through winglet rudders and ailerons yields the best results. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
977.
Biphasic materials are widely used for the modelling and the numerical simulation of articular cartilage within joints. In combination with contact, the numerical solution of the arising discrete systems is a demanding task, in particular for realistic geometries. We consider the stability and efficiency of different multilevel approaches for the numerical solution of the resulting non–smooth systems. Moreover, multilevel methods are derived which allow for the efficient numerical simulation of biphasic materials in contact. Numerical examples on problem specific geometries in three space dimensions are given. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
978.
Metal forming processes are important technologies for the production of engineering structures. In order to optimize the resulting material properties, it becomes necessary to simulate the entire forming process by taking into account physical effects such as phase transformations. In this work, we concentrate on the phase change from austenite to martensite and present a macroscopic material model, which combines the effect of classical plasticity with the effect of transformation induced plasticity (TRIP). An extensive experimental database for a low-alloy steel is used for parameter identification, thus taking into account the effects of uniaxial compressive and tensile stress on the kinetics of phase transformation at different temperatures. For temperatures below the martensite start temperature with simultaneous stresses above the yield limit, it is difficult to obtain experimental data. Consequently, a numerical homogenization technique is employed for this case. In a further part of this paper, an effective integration scheme is provided, which is implemented into a commercial finite element program. In a finite element simulation, the austenite to martensite phase transformation in a shaft subjected to thermal loading is investigated. 相似文献
979.
Dr. Duy-Khiet Ho Dr. Xabier Murgia Dr. Chiara De Rossi Rebekka Christmann Dr. Antonio G. Hüfner de Mello Martins Dr. Marcus Koch Anastasia Andreas Dr. Jennifer Herrmann Prof. Dr. Rolf Müller Dr. Martin Empting Prof. Dr. Rolf W. Hartmann Dr. Didier Desmaele Dr. Brigitta Loretz Prof. Dr. Patrick Couvreur Prof. Dr. Claus-Michael Lehr 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(26):10378-10382
Elimination of pulmonary Pseudomonas aeruginosa (PA) infections is challenging to accomplish with antibiotic therapies, mainly due to resistance mechanisms. Quorum sensing inhibitors (QSIs) interfering with biofilm formation can thus complement antibiotics. For simultaneous and improved delivery of both active agents to the infection sites, self-assembling nanoparticles of a newly synthesized squalenyl hydrogen sulfate (SqNPs) were prepared. These nanocarriers allowed for remarkably high loading capacities of hydrophilic antibiotic tobramycin (Tob) and a novel lipophilic QSI at 30 % and circa 10 %, respectively. The drug-loaded SqNPs showed improved biofilm penetration and enhanced efficacy in relevant biological barriers (mucin/human tracheal mucus, biofilm), leading to complete eradication of PA biofilms at circa 16-fold lower Tob concentration than Tob alone. This study offers a viable therapy optimization and invigorates the research and development of QSIs for clinical use. 相似文献
980.