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21.
Jeon IeR Ababei R Lecren L Li YG Wernsdorfer W Roubeau O Mathonière C Clérac R 《Dalton transactions (Cambridge, England : 2003)》2010,39(20):4744-4746
In an attempt to develop novel coordination networks of SMMs, a Cu(II) picolinate complex has been used to coordinate S(T) = 9 tetranuclear Mn-based SMMs resulting in an intriguing 2D framework exhibiting a magnet-like behavior at low temperature. 相似文献
22.
The microstructure of water soluble nanoaggregates based on polyelectrolyte complex formed by the cationic comb-type copolymer
poly(acrylamide -co-[3- (methacryloyl-amino)propyl] trimethylammonium chloride)-graft- polyacrylamide [P(AM-co-MAPTAC)-g-PAM]
and the anionic linear polyelectrolyte sodium polyacrylate (NaPA) was investigated using the fluorescence probe technique.
The fluorescence probe were 1-anilinonaphthalene-8-sulfonic acid (ANS), pyrene (Py) and 1,10-bis(1-pyrene) decane (PD). The
fluorescence properties in polyelectrolyte complex solutions, which are sensitive to either micropolarity (ANS, Py) or microviscosity
(PD), were related to the quantities obtained in different pure or mixed solvents. Micropolarities were quantified utilizing
the polarity common index (Reichardt) E
T(30). ANS and Py showed a variation of the micropolarity with the charge ratio of the two polymers, with the lowest polarity
reached at the complex neutralization. The PD probe, by its excimer-to-monomer fluorescence intensities ratio, enabled us
to evidence the effect of the composition and the comb-type copolymer grafting density on the microviscosity of the interpolyelectrolytes
aggregates. It has been found that the microviscosity increased with the density of the grafting PAM chains. 相似文献
23.
This paper deals with a constrained egalitarian solution for convex multi-choice games named the d value. It is proved that the d value of a convex multi-choice game belongs to the precore, Lorenz dominates each other element of the precore and possesses a population monotonicity property regarding players’ participation levels. Furthermore, an axiomatic characterization is given where a specific consistency property plays an important role. 相似文献
24.
The paper analyses the effect of normal contact with friction on the generation of full band-gaps in sonic composites. The behavior of contact interfaces are computed by using LISA (local interaction simulation approach). LISA is an efficient tool for numerical simulation of the acoustic wave propagation in heterogeneous material specimens, in particular those with contact interfaces between different materials, like in sonic composites. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
25.
Calu Larisa Badea Mihaela Čelan Korošin Nataša Chifiriuc Mariana Carmen Bleotu Coralia Stanică Nicolae Silvestro Luigi Maurer Martin Olar Rodica 《Journal of Thermal Analysis and Calorimetry》2018,134(3):1839-1850
Journal of Thermal Analysis and Calorimetry - A novel series of complexes ML(ClO4)·nH2O (M: Co, Ni, Cu, Zn; HL: 2-[(E)-(1H-1,2,4-triazol-3-ylimino)methyl]phenol) have been synthesized and... 相似文献
26.
Ionel Haiduc Gellert Mezei Rodica Micu‐Semeniuc Frank T. Edelmann Axel Fischer 《无机化学与普通化学杂志》2006,632(2):295-300
The three (O‐methyl)‐p‐ethoxyphenyldithiophosphonato triphenylphosphine complexes of copper, silver and gold, [(Ph3P)nM{S2P(OMe)C6H4OEt‐p}] (M = Cu, n = 2; M = Ag, Au, n = 1) investigated structurally by X‐ray diffraction exhibit remarkable structural differences. The copper compound is a four‐coordinate chelate monomer with Cu–S 2.4417(6) and 2.5048(6) Å; P–Cu–S 104.24(2)–114.01(2)°; Cu–S–P 82.49(3)° and 80.85(2)°. The silver compound is a cyclic dimer with bridging dithiophosphonato ligands and three‐coordinate silver atoms [Ag–S 2.5371(5) and 2.6867(5) Å; P–Ag–S 122.88(2)° and 122.17(2)°; Ag–S–P 89.32(2)° and 103.56(2)°]. The gold compound is monomeric with linear dicoordinate gold [Au–S 2.3218(6) Å; P–Au–S 177.72(2)°, Au–S–P 100.97(3)°]. 相似文献
27.
Conformational transformations of the tetraenic nystatin chromophore under the influence of solvents and UV irradiation have been studied by absorption, fluorescence and wide-line NMR spectroscopy. 相似文献
28.
Mihaela?BadeaEmail author Rodica?Olar Valentina?Uivarosi Dana?Marinescu Victoria?Aldea 《Journal of Thermal Analysis and Calorimetry》2012,107(1):279-285
Two new complexes with formula VOL2·nH2O ((1) L: 4′,5,7-trihydroxyflavone-7-rhamnoglucoside (naringin), n = 8; (2) L: 3′,4′,7-tris[O-(2-hydroxyethyl)]rutin (troxerutin), n = 0) were synthesised and characterised. The IR and UV–Vis spectral data indicate that these flavones act as bidentate chelating
ligands and generate VO(II) complexes with a square-pyramidal stereochemistry. The thermal analysis (TG, DTA) elucidated the
composition and also the number and nature of the water molecules. The thermal behavior indicates also a strong interaction
between oxovanadium (IV) and these oxygen donor ligands. 相似文献
29.
Experimental results for the temperature dependence of density at normal pressure for two compositions of sodium lauryl sulphate/decanol/water solutions, exhibiting either a calamitic or a discotic lyotropic nematic phase at room temperature, are presented. Within the limits of experimental precision (±1 ×10-5 g cm-3), the systems show no jump in density at the nematic to isotropic phase transition. Over the studied temperature range, the mean thermal expansion coefficients were also evaluated. 相似文献
30.
Tree-connected peer group situations and peer group games 总被引:2,自引:0,他引:2