Probing the Pore Size of Porous Ceramics with Controlled Amount of Magnetic Impurities via Diffusion Effects on the CPMG Technique

In our work, we will explore the possibility of implementing the well-known Carr–Purcell–Meiboom–Gill pulse sequence to determine the pore size of porous ceramics with magnetic impurities. The proposed approach exploits the diffusion dependence of the spin-echo signal in the presence of internal gradients occurring as a result of susceptibility contrast between the porous matrix and the confined liquid. For calibrating the technique, a comparison of the pore size data with those extracted from the so-called DDIF technique (DDIF, decay due to diffusion in the internal fields) is performed. This approach can be applied for nondestructive in situ characterization of soils, concrete, biological tissues or other structures with micrometer pore size.     

Spectroscopic study on nystatin conformational modifications generated by its interaction with the solvent

Conformational transformations of the tetraenic nystatin chromophore under the influence of solvents and UV irradiation have been studied by absorption, fluorescence and wide-line NMR spectroscopy.     

Study of the Acid-Base Properties of sio2-Supported Nimoo4 Catalysts by Temperature-Programmeddesorption. Effect of the Active Phase Content

The acid-base properties of a series of SiO₂-supported NiMoO₄ catalysts were investigated by temperature-programmed desorption of NH₃ and CO₂. Results show that supported catalysts with ca. one monolayer of the active phase are less acidic than the unsupported stoichiometric NiMoO₄.     

Amide,urea and thiourea‐containing triphenylene derivatives: influence of H‐bonding on mesomorphic properties

The synthesis and thermotropic properties are reported for a series of hexaalkoxytriphenylenes that contain an amide, urea or thiourea group in one of their alkoxy tails. The intermolecular hydrogen bonding abilities of these molecules have a disturbing influence on the formation and stability of the columnar liquid crystalline phases. The stronger the hydrogen bonding the more the liquid crystallinity is suppressed, probably due to disturbance of the π–π stacking of the triphenylene discs. As a direct result, urea‐ and amide‐containing triphenylene derivatives are not liquid crystalline, but several thiourea derivatives show hexagonal columnar mesophases.     

Formation of Iron Macro-Spheres in Plasma

In this paper the formation mechanism of iron macro-spheres in a plasma medium is dealt with, including the conditions under which such spheres are formed. The geometry of the spheres referred to above depends on the main technological parameters involved in the production of pores. Conditions under which pores occur within macro-spheres are also established. The radii of these pores are sensitive to the velocity distribution within the plasma jet section     

Cracking in polylactide spherulites

A polylactide of high optical purity was crystallized between 100 and 140 °C, in‐between two glass slides, and its morphology was investigated by polarizing optical microscopy, scanning electron microscopy, and atomic force microscopy, during subsequent heating and cooling cycles between ?15 °C and the crystallization temperature. It was found that dark circular rings show up on cooling on top of the spherulites and represent cracks of about 300 nm in width. This phenomenon is completely reversible, and the heating–cooling curves are centered at about 56 °C, which coincide with the T_g of polylactide. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3308–3315, 2005     

The lattice automorphisms of the dominance ordering

In this paper it is shown that the lattice L_n of partitions of n under the dominance ordering is totally asymmetric, except for the cases n = 6 and 7 where the automorphism group is $\text{Z}$₂ × $\text{Z}$₂. As a consequence, partition conjugation is the only antiautomorphism of L_n if n ≠ 6, 7.     

Unbounded divergence of simple quadrature formulas

Given a sequence of real or complex coefficients c_i and a sequence of distinct nodes t_i in a compact interval T, we prove the divergence and the unbounded divergence on superdense sets in the space C(T) of the simple quadrature formulas ∝_Tx(t)du(t) = Q_n(x) + R_n(x) and ∝_Tw(t)x(t)dt = Q_n(x) + R_n(x), where Q_n(x)=∑_i=1^m_n c_ix(t_i), ε C(T).The divergence (not certainly unbounded) for at most one continuous function of the first simple quadrature formula, with m_n = n and u(t) = t, was established by P. J. Davis in 1953.